Abstract
A systematic investigation of the intrinsic line widths of the C-O stretch vibration for different configurations of CO adsorbed on Cu (100) has been made, using infrared spectroscopy. The line width of 12C16O in the ordered c(2×2) structure was found to be 4.5 cm−1 and for 12C18O 4.0 cm−1. Disorder, structural or isotopic, increases the line width by about 1 cm−1, whereas there is no additional broadening for partial coverages. The results are correlated with existing theories for damping and molecular interactions.
Keywords
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
R. Ryberg, submitted to Phys. Rev. B.
B.N.J. Persson, M. Persson, Solid State Comm., in press.
B.N.J. Persson, M. Persson, Surf. Sci., in press.
M.A. Kozhushnev, V.G. Kustarev, B.R. Shub, Surf. Sci. 81, 261 (1979).
B.N.J. Persson, R. Ryberg, Solid State Comm., in press.
B.N.J. Persson, R. Ryberg, submitted to Phys. Rev. B.
J. Pritchard, Surf. Sci. 79, 231 (1979).
S. Andersson, Surf. Sci. 89, 477 (1979).
G.D. Mahan, A.A. Lucas, J. Chem. Phys. 68, 1344 (1978).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1982 Plenum Press, New York
About this chapter
Cite this chapter
Ryberg, R. (1982). Intrinsic Line Widths of CO Adsorbed on Cu(100). In: Caudano, R., Gilles, JM., Lucas, A.A. (eds) Vibrations at Surfaces. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4058-4_29
Download citation
DOI: https://doi.org/10.1007/978-1-4684-4058-4_29
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-4060-7
Online ISBN: 978-1-4684-4058-4
eBook Packages: Springer Book Archive