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Spreading and Reactions of Molten Metals on and with Cemented Carbides

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Book cover Surfaces and Interfaces in Ceramic and Ceramic — Metal Systems

Part of the book series: Materials Science Research ((MSR,volume 14))

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Abstract

The present paper deals with the interfacial phenomena of two-phase materials, more specifically, with the interaction between molten metals and cemented carbides. In spite of the technical importance in various fields, very little is known on the spreading and reaction of liquid on and with two-phase materials. Brazing of cemented carbides is one of the examples. It is shown in our early work1) that the structure of reaction zones obtained by heating cemented carbides in contact with molten copper is not explained simply by referring to the phase relationships in the system of interacting components, copper and cobalt, and that the reaction behavior depends on the nature of cobalt/carbide phase boundary as influenced by the parameters such cobalt and carbon content and carbide composition.

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References

  1. T. Yamaguchi and M. Okada, “High-Temperature Reaction Between cemented Tungsten Carbide and Copper:, J. Amer. Cer, Soc, 60 [7/8] 289 (1977).

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  2. Max Hansen, Constitution of Binary Alloys, 2nd ed; pp 469–71. McGraw-Hill, New York, 1958.

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  3. ibid., pp 16-17.

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  4. F. Bashforth and J. C. Adams, “The Theories of Capillary Action by Comparing the Theoretical and Measured Forms of Drops of Fluid”, Cambridge; AT THE UNIVERSITY PRESS., 1883.

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  5. S. K. Rhee, “Wetting of A1N and TiC by Liquid Ag and Liquid Cu”, J. Amer. Cer. Soc, 53[12] 639 (1970).

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  6. S. K. Rhee, “Wetting of TaC by Liquid Cu and Liquid Ag”, ibid., 55[3] 157 (1972).

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© 1981 Plenum Press, New York

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Yamaguchi, T., Harano, K., Yajima, K. (1981). Spreading and Reactions of Molten Metals on and with Cemented Carbides. In: Pask, J., Evans, A. (eds) Surfaces and Interfaces in Ceramic and Ceramic — Metal Systems. Materials Science Research, vol 14. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3947-2_44

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  • DOI: https://doi.org/10.1007/978-1-4684-3947-2_44

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-3949-6

  • Online ISBN: 978-1-4684-3947-2

  • eBook Packages: Springer Book Archive

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