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Predictive Model for Interfacial Phenomena Between Molten Metals and Sapphire in Varying Oxygen Partial Pressures

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Surfaces and Interfaces in Ceramic and Ceramic — Metal Systems

Part of the book series: Materials Science Research ((MSR,volume 14))

Abstract

A model has been developed to predict the interfacial behaviour between a molten metal and an alumina substrate at different oxygen partial pressures. In developing the model, the existing sessile drop data on Cu-, Ag-, Fe- and Ni-A12O3 systems are used.

In the equation there are three empirical constants, which have been estimated from the thermodynamic considerations. The agreement between the predicted and the experimentally calculated value of γSL as a function of ln [O2−] is reasonably good. It has been shown that the model can be used to predict the interfacial behaviour of a molten metal — A12O3 system of which no sessile drop data exists.

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Authors and Affiliations

  1. Department of Metallurgical Engineering, The University of British Columbia, Vancouver, Canada, V6T 1W5

    A. C. D. Chaklader, W. W. Gill & S. P. Mehrotra

Authors
  1. A. C. D. Chaklader
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  2. W. W. Gill
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  3. S. P. Mehrotra
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Editor information

Editors and Affiliations

  1. The Lawrence Berkeley Laboratory, University of California, Berkeley, California, USA

    Joseph Pask  & Anthony Evans  & 

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© 1981 Plenum Press, New York

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Chaklader, A.C.D., Gill, W.W., Mehrotra, S.P. (1981). Predictive Model for Interfacial Phenomena Between Molten Metals and Sapphire in Varying Oxygen Partial Pressures. In: Pask, J., Evans, A. (eds) Surfaces and Interfaces in Ceramic and Ceramic — Metal Systems. Materials Science Research, vol 14. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3947-2_37

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  • DOI: https://doi.org/10.1007/978-1-4684-3947-2_37

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-3949-6

  • Online ISBN: 978-1-4684-3947-2

  • eBook Packages: Springer Book Archive

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