Abstract
The electrical conductivity of geological liquids is usually studied for the purpose of gaining information about the composition of the system or the structure of the liquid. Three types of geological liquids will be referred to in this chapter: the sea, geothermal waters, and magmas or silicate melts.
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References
D. Goldberg, ed., The Sea, Vol. 5, Marine Chemistry, Wiley- Interscience, New York (1974).
F. J. Millero, in The Sea (D. Goldberg, ed.), Vol. 5, Wiley-Interscience, New York (1974).
Ninth report of the joint panel on oceanographic tables and standards. UNESCO Technical Papers in Marine Science, No. 30, Paris, 11–13 September 1978, UNESCO (1979).
M-S. Chen and L. Onsager, The generalized conductance equation, J. Phys. Chem. 81, 2017–2021 (1977).
R. A. Cox, in Chemical Oceanography ( J. P. Riley and G. Skinrow, eds.), Academic Press, London (1965), pp. 73–120.
C. T. Chen and F. J. Millero, The specific volume of sea water at high pressures, Deep-Sea Res. 23, 595–612 (1976).
D. N. Connors and P. K. Weyl, The partial equivalent conductance of salts in seawater and the density conductance relationship, Limnol. Oceanog. 13, 35–50 (1968).
D. A. Lown and H. R. Thirsk, Proton transfer conductance in aqueous solution; Part 1, Conductance of concentrated aqueous alkali metal hydroxide solutions at elevated temperatures and pressures, Trans. Faraday Soc. 67, 132–148 (1971).
S. K. Fellows, High temperature conductance of concentrated salt solutions, Ph.D. Thesis, Victoria University of Wellington, New Zealand (1971).
R. A. Home and R. P. Young, The electrical conductivity of aqueous 0.03 to 4.0 M potassium chloride solutions under hydrostatic pressure, J. Phys. Chem. 71, 3824–3832 (1967).
J. U. Hwang, H. D. Ludemann, and D. Hartmann, Die elektrische Leitfahigkeit konzentrierter wassriger Alkalihalogenidlosungen bei hohen Drucken und Temperaturen, High Temperatures-High Pressures 2, 651–669 (1970).
A. Bradshaw and K. E. Schleicher, The effect of pressure on the electrical conductance of sea water, Deep-Sea Res. 12, 151–162 (1965).
F. H. Fisher, Multistate dissociation and the effect of pressure on the equilibrium on magnesium sulfate, J. Phys. Chem. 69, 695–698 (1965).
F. H. Fisher, and A. P. Fox, KSO -4 , NaSO -4 , and MgCl>+ ion pairs in aqueous solutions up to 2000 atm, J. Solution Chem. 6, 641–650 (1977).
A. J. Ellis and W. A. J. Mahon, Chemistry and Geothermal Systems, Academic Press, New York (1977).
B. S. Smolyakov, Limiting Equivalent Ionic Conductance up to 200°C, International Conference on High Temperature and High Pressure Electrochemistry in Aqueous Solutions, University of Surrey (1973), pp. 177–181.
W. L. Marshall, Predictions of the geochemical behaviour of aqueous electrolytes at high temperatures and pressures, Chemical Geology 10, 56–58 (1972).
A. J. Ellis and D. W. Anderson, The effect of pressure on the first acid dissociation constants of “sulphurous” and phosphoric acids, J. Chem Soc. 342, 1765–1767 (1961).
A. J. Ellis and D. W. Anderson, The first acid dissociation constant of hydrogen sulphide at high pressures, J. Chem. Soc. 917, 4678–4680 (1961).
A. J. Ellis, The effect of pressure on the first dissociation constant of “carbonic acid,” J. Chem. Soc. 750, 3689–3699 (1959)
A. J. Read, The first ionization constant of carbonic acid from 25 to 250°C and to 2000 bar, J. Solution Chem. 4, 53–70 (1975).
S. D. Hamann, Physico-chemical Effects of Pressure, Butterworths, London (1957).
R. W. Henly and A. McNabb, Magmatic vapor plumes and ground water interaction in porphyry copper emplacement, Economic Geology 73, 1–19 (1978).
H. S. Waff, Theoretical consideration of electrical conductivity in a partially molten mantle and implications for geothermometry, J. Geophys. Res. 79, 4003–4010 (1974).
J. O’M. Bockris, J. A. Kitchener, S. Ignatowicz, and J. W. Tomlinson, The electrical conductivity of silicate melts: Systems containing Ca, Mn and Al, Discuss. Faraday Soc. 4, 265–281 (1948).
J. O’M. Bockris, J. A. Kitchener, S. Ignatowicz, and J. W. Tomlinson, Electric conductance in liquid silicates, Trans. Faraday Soc. 48, 75–91 (1952).
J. O’M. Bockris, J. A. Kitchener, and A. E. Davies, Electric transport in liquid silicates, Trans. Faraday Soc. 48, 536–548 (1951).
J. O’M. Bockris and G. W. Mellors, Electric conductance in liquid lead silicates and borates, J. Phys. Chem. 60, 1321–1328 (1956).
R. E. Tickle, The electrical conductance of molten alkali silicates, I, Experiments and results, Phys. Chem. Glasses 8, 101–112 (1967)
R. E. Tickle, The electrical conductance of molten alkali silicates, II, Theoretical discussion, Phys. Chem. Glasses 8, 113–124(1967).
H. S. Waff and D. F. Weill, Electrical conductivity of magmatic liquids, effects of temperature, oxygen fugacity and composition, Earth Planet. Sci. Lett. 28, 254–260 (1975).
H. Watanabe, Measurements of electrical conductivity of basalt at temperatures up to 1500°C and pressure to about 20 kilobars, Spec. Contr. Geophys. Inst. Kyoto Univ. 10, 159–170 (1970).
N. T. Khitarov and A. V. Slutsky, Influence de la temperature et de la pression sur la conductibilité electrique de l’albite et du basalte, J. Chim. Phys. et Phys. Chim. 64, 1085–1091 (1967).
I. Kushiro, Viscosity and structural changes of albite (NaA1Si3O8) melt at high pressures, Earth Planet Sci. Lett. 41, 87–90 (1978).
I. Kushiro, Changes in viscosity and structure of melt of NaA1Si2O6 composition at high pressures, J. Geophys. Res. 81, 6347–6350 (1976).
I. Kushiro, H. S. Yodder, and B. O. Mysen, Viscosities of basalt and andesite melts at high pressures, J. Geophys. Res. 81, 6351–6356 (1976).
E. B. Lebedev and N. I. Khitarov, Influence of water on the electrical conductivity of silicate melts at high pressures, High Temperature High Pressure Electrochemistry in Aqueous Solutions N.A.C.E. at University of Surrey, England (1973).
A. T. Kuhn, ed., Industrial Electrochemical Processes, Elsevier, Amsterdam (1971).
C. E. Bowen, Production of H2 and O2 by electrolysis of H20, Proc. Institution of Electrical Engineers 90, 474–485 (1943).
C. A. Angell, Electrical conductance of ionic liquids with water contents in the range 0–80 mol.%, Aust. J. Chem. 23, 929–937 (1970).
D. A. Lown and H. R. Thirsk, Proton transfer conductance in aqueous solution, Parts 1 and 2, Trans. Faraday Soc. 67, 132–152 (1971).
A. Reger, E. Peled, and E. Gileadi, Mechanism of high conductivity in a medium of low dielectric constant, J. Phys. Chem. 83, 873–879 (1979).
A. Reger, E. Peled, and E. Gileadi, Determination of the nature of the ionic species in a low dielectric constant solvent from Transference number measurements, J. Phys. Chem. 83, 869–873 (1979).
C. T. Moynihan, in Ionic Interactions (S. Petrucci, ed.), Vol. 1, Academic Press, New York (1971), Chapter 5.
C. T. Moynihan and R. W. Laity, Relative cation mobilities in potassium chloride- lithium chloride melts, J. Phys. Chem. 68, 3312–3317 (1964).
E. R. Van Artsdalen and I. S. Yaffe, Electrical conductance and density of molten salt systems: KCl-LiCl, KCl-NaCl and KCl-KI, J. Phys. Chem. 59, 118–127 (1955).
W. K. Behl and J. J. Egan, Transference numbers and ionic mobilities from electromotive force measurements on molten salt mixtures, J. Phys. Chem. 71, 1764–1769 (1967).
H. H. Emons and H. Vogt, On the structure of charge-unsymmetrical salt melts of alkaline earth and alkali metal chlorides, Z. Anorg. Allg. Chem. 394, 279–289 (1972).
D. S. Patterson and M. Chance, Production of sodium, British Patent No. 918, 809 (1963).
Jacques van Diest, Process for the manufacture of sodium by electrolysis of fused salt bath, U.S. Patent No. 3, 051, 635 (1960).
A. V. Tomashov, V. A. Nichkov, A. E. Mordovin, and R. S. Khailikov, Interaction of potassium chlorides and beryllium chloride in melts and their mixtures, Izv. Vyssh. Uchebn. Zaved. Tsvetn. Metall. 5, 81–85 (1975).
K. Grjotheim, C. Krohn, M. Malinovsky, K. Matiasovsky, and J. Thonstad, Aluminium Electrolysis, Aluminium-Verlag GmbH, Düsseldorf (1977).
E. W. Yim and M. Feinleib, Electrical conductivity of molten fluorides, J. Electrochem. Soc. 104, 626–630 (1957).
K. Gijotheim, M. Malinovsky, and K. Matiasovsky, The effect of different additives on the conductivity of cryolite-alumina melts, J. Metals 21, 28–33 (1969).
Chemistry Division, DSIR, Petone, New Zealand.
S. H. Wilson, Waiotapu Geothermal Field, New Zealand Department of Scientific and Industrial Research Bulletin 155 (1963a), pp. 87–118.
W. F. Giggenbach, The chemistry of Crater Lake, Mt. Ruapehu (New Zealand) during and after the 1971 active period, N.Z. J. Sci. 17, 33–45 (1974).
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© 1980 Plenum Press, New York
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Smedley, S.I. (1980). Electrical Conductivity in Liquids of Geological and Industrial Interest. In: The Interpretation of Ionic Conductivity in Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3818-5_6
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DOI: https://doi.org/10.1007/978-1-4684-3818-5_6
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