Abstract
Sediments at DOMES Sites A, B and C are mixtures of pelagic clay, biogenic ooze, hydrogenous metals, and metalliferous sediment. The relative proportions of these components and the importance of local volcanic contributions can be estimated from bulk analyses of Si, A1, Fe, Ca, Mn, Ti and Na. Analyses of these and 20 additional elements for 118 samples indicate that average sediment at Sites A and B contains about 11% biogenic SiO2 and 70% pelagic clay, whereas that at Site C contains less than 2% biogenic SiO2, 87% pelagic clay and 1.8% metalliferous sediment.
A partitioning model based on element fractionation and inter-element correlation indicates that most of the Mn, Mo, Ni, and Pb is in the hydrogenous fraction of the sediment. The bulk composition of the hydrogenous fraction shows little variation from sample to sample and is comparable to the composition of the DOMES manganese nodules. The pelagic clay fraction is also remarkably homogeneous and is almost identical to average Pacific pelagic clay with respect to all major oxides except K2O.
Several cores at Site C have large components of metalliferous sediment. Fe2O3, SiO2, MgO, and P2O5 in excess of the amounts in pelagic clay are present in remarkably uniform proportions in the metalliferous fraction.
At Sites A and B, MgO in excess of the pelagic clay contribution has been taken up by very slowly deposited biogenic SiO2.
Factor analyses of the major oxides and partitioning by the Heath and Dymond (1977) model yield results in good agreement with the present partitioning model and provide additional insight into the distribution of minor elements not strongly confined to a single sediment fraction.
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References
Baker, E.T., Feeley, R.A. and Takahashi, K. (1979). Chemical composition, size distribution and particle morphology at DOMES Sites A, B, and C: Relationships with local sediment composition, In Bischoff, J.L. and Piper, D.Z. (eds.), Marine Geology and Oceanography of the Pacific Manganese Nodule Province, Plenum Publ. Corp., New York, (this volume).
Berner, R. (1973) Phosphate removal from sea water by absorption on volcanogenic ferric oxides. Earth and Planet. Sci. Lett. 18, 77–86.
Bischoff, J.L. and Sayles, F.L. (1972) Pore fluid and mineralogical studies of recent marine sediments: Bauer Depression region of the East Pacific Rise, Jour. Sed. Petrol. 42, 711–724.
Bischoff, J.L. (compiler) (1976) Deep Ocean Mining Environmental Study, N.E. Pacific Manganese Nodule Province, Site C, Geology and Geochemistry, U.S. Geol. Survey Open-file Report 76–548, 275 p.
Bischoff, J.L. and Rosenbauer, R.J. (1977) Recent metalliferous sediment in the North Pacific Manganese Nodule Area, Earth and Planet. Sci. Lett. 33, 379–388.
Bischoff, J.L., Piper, D.Z. and Quinterno, P. (1979) Nature and origin of metalliferous sediment in DOMES Site C, Pacific Manganese Nodule Province, In Lalou, C. (ed.) “International Colloquium on the Genesis of Manganese Nodules”, Colloques Internationaux du C.N.R.S., Paris, pp.
Calvert, S.E. and Price, N.B. (1977) Geochemical variation in ferromanganese nodules and associated sediments from the Pacific Ocean, Marine Chem. 5, 43–74.
Cook, H.E., Piper, D.Z. and Gardner, J.V. (1977) Geological and oceanographic framework of DOMES Sites A, B and C: Central Equatorial Pacific, In Piper, D.Z. (compiler), Deep Ocean Environmental Study: Geology and Geochemistry of DOMES Sites A, B, and C, Equatorial North Pacific, U.S. Geol. Survey Open-file Report 77–778, 15–81.
Cronan, D.S. (1969) Average abundances of Mn, Fe, Ni, Co, Cu, Pb, Mo, V, Cr, Ti and P in Pacific pelagic clays, Geochim. Cosmochim Acta 33, 1562–1565.
Cronan, D.S. and Tooms (1969) The Geochemistry of manganese nodules and associated pelagic deposits from the Pacific and Indian Oceans, Deep Sea Research 16, 335–339.
El Wakeel, S.K. and Riley, J.R. (1961) Chemical and mineralogical studies of deep sea sediments, Geochim. Cosmochim. Acta 25, no. 2, 110–146.
Engel, A.E., Engel, C.G. and Havens, R.G. (1965) Chemical characteristics of oceanic basalts and the upper mantle, Bull. Geol. Soc. Amer. 76, p. 719.
Froelich, P.N., Bender, M.L. and Heath, G.R. (1977) Phosphorus accumulation rates in metalliferous sediments on the East Pacific Rise, Earth and Planet. Sci. Lett. 34, 351–359.
Goldberg, E.D. and Arrhenius, G.O.S. (1958) Chemistry of Pacific pelagic sediments, Geochim. Cosmochim. Acta 13, 153–212.
Heath, G.R., Moore, T.C., Somayajulu, B.L.K. and Cronan, D.S. (1970) Sediment budget in a deep-sea core from the Central Equatorial Pacific, Jour. Mar. Res. 28, 225–234.
Heath, G.R. and Dymond, J. (1977) Genesis and transformation of metalliferous sediments from the East Pacific Rise, Bauer Deep and Central Basin, Northwest Nazca Plate, Bull. Geol. Soc. Amer. 88, 723–733.
Hein, J.R., Gutmacher, C., and Miller, J. (1976) DOMES Area C: General statement about mineralogy, diagenesis and sediment classification, in Bischoff, J.L. (compiler), Deep Ocean Mining Environmental Study, N.E. Pacific Nodule Province, Site C, Geology and Geochemistry, U.S. Geol. Survey Open-file Report 76–548, 275 pp (see 63–80 ).
Hein, J.R. and Jones, M.G. (1977) Mineralogy and diagenesis of DOMES Sites A and B, In Piper, D.Z. (compiler), Deep Ocean Mining Environmental Study: Geology and geochemistry of DOMES Sites A, B, and C, Equatorial North Pacific, U.S. Geol. Survey, Open-file Report 77–778, 527 pp. (see 146–178 ).
Imbrie, J. and van Andel, Tj. H. (1964) Vector analysis of heavy mineral data, Bull. Geol. Soc. Amer. 75, 1131–1156.
Klovan, J.E. and Imbrie, J. (1971) Algorithm and FORTRAN IV Program for largescale Q-mode factor analysis and calculations of factor scores, Mathematical Geol. 3, 61–77.
Krishnaswami, S. (1976) Authigenic transition elements in Pacific pelagic clays, Geochim. Cosmochim. Acta 40, 425–434.
Landergren, S. (1964) On the geochemistry of deep-sea sediments. Reports of the Swedish deep-sea expedition, v. X, Spec. Invest, no. 5, 61–148.
Piper, D.Z., Cannon, W.F., and Leong, K. (1977) Composition and abundances of ferromanganese nodules at DOMES Sites A, B, and C: Relationship with bathymetry and stratigraphy, In Piper, D.Z. (compiler), Deep Ocean Environmental Study: Geology and Geochemistry of DOMES Sites A, B, and C, Equatorial North Pacific, U.S. Geol. Survey Open-file Report 77–778, 217–266.
Piper, D.Z. (compiler) (1977) Deep Ocean Environmental Study: Geology and Geochemistry of DOMES Sites A, B, and C, Equatorial North Pacific, U.S. Geol. Survey Open-file Report 77–778, 527 pp.
Piper, D.Z., Cannon, W.F., and Leong, K. (this volume) Ferromanganese nodules at DOMES Sites A, B, and C: Relationship with bathymetry and stratigraphy, In Bischoff, J.L. and Piper, D.Z. (eds.), Oceanography of the Equatorial Pacific Manganese Nodule Province.
Piper, D.Z., Cook, H.E., and Gardner, J.V. (this volume). Acoustic and litho-stratigraphy of the Central Equatorial Pacific, Domes Sites A, B, and C.
Quinterno, P. and Theyer, F. (this volume). Biostratigraphy of the Equatorial North Pacific, DOMES Sites A, B, and C.
Sayles, F.L., and Bischoff, J.L. (1973) Ferromanganese sediments in the Equatorial East Pacific, Earth and Planet. Sci. Lett. 19, 330–336.
Sayles, F.L. and Mangelsdorf, P.C. (1977) The equilibrium of clay minerals with sea water: exchange reactions, Geochim. Cosmochim. Acta 41, 951–960.
Turekian, KX and Wedepohl K.H. (1961) Distribution of the elements in some major units of the earth’s crust, Bull. Geol. Soc. Amer. 72, 175–192.
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Bischoff, J.L., Heath, G.R., Leinen, M. (1979). Geochemistry of Deep-Sea Sediments from the Pacific Manganese Nodule Province: DOMES Sites A, B, and C. In: Bischoff, J.L., Piper, D.Z. (eds) Marine Geology and Oceanography of the Pacific Manganese Nodule Province. Marine Science, vol 9. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3518-4_12
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DOI: https://doi.org/10.1007/978-1-4684-3518-4_12
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