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Metastable Phases Produced by Rapid Quenching from the Vapor and the Liquid

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Treatise on Solid State Chemistry

Abstract

Though some metastable phases are obtained readily, e.g., common inorganic oxide glasses or some phases present in many varieties of steels, the phases of interest here are those which can be obtained only through the use of high effective quenching rates from the vapor or liquid phase. This includes many thin-film phases obtained by evaporation or sputtering and not-so-thin film phases obtained by rapid cooling from the melt and by electrodeposition from a liquid electrolyte. In the case of evaporation or sputtering of a metal, the substrate is exposed to a gaseous ambient containing metal as well as nonmetal atoms, whereas in the case of rapid quenching from the melt and electrodeposition, the ambient of the substrate is made up of a crystallographically uncorrelated assembly of atoms in the liquid phase or in solution.

Communication No. 9.

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Authors and Affiliations

  1. Bell Laboratories, Murray Hill, New Jersey, USA

    A. K. Sinha

  2. Department of Chemistry and Institute of Chemical Analysis, Applications and Forensic Science, Northeastern University, Boston, Massachusetts, USA

    B. C. Giessen & D. E. Polk

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  1. Research and Patents, Bell Laboratories, Murray Hill, New Jersey, USA

    N. B. Hannay (Vice President) (Vice President)

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Sinha, A.K., Giessen, B.C., Polk, D.E. (1976). Metastable Phases Produced by Rapid Quenching from the Vapor and the Liquid. In: Hannay, N.B. (eds) Treatise on Solid State Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2664-9_1

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