Abstract
A calcium ion-selective electrode based on a liquid membrane of calcium didecylphosphate sensor dissolved in dioctylphenylphosphonate solvent mediator(1) fulfilled a longstanding need for a reliable monitor of calcium ion activities in medicine and the life sciences. The wide interest in this ion-selective electrode was promoted by the commercial availability of a refined model although its general performance was matched by an electrode(2) with a sensing membrane comprising thenoyltrifluoroacetone sensor plus tributylphosphate plasticizer impregnated in poly(vinyl chloride) (PVC). The PVC matrix membrane was prepared by knife-coating a mixture of PVC with sensor and plasticizer components on a woven fabric and curing the applied coating at 140°C for 30 s.(2–5)
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Ross, J. W., Science 156, 1378 (1967).
Shatkay, A., Anal. Chem. 39, 1056 (1967).
Israel Patent 21,709 (1965).
British Patent 1090,096 (1967).
U.S. Patent 3450, 631 (1969).
Moody, G. J., Oke, R. B., and Thomas, J. D. R., Analyst 95, 910 (1970).
Davies, J. E. W., Moody, G. J., and Thomas, J. D. R., Analyst 97, 87 (1972).
Griffiths, G. H., Moody, G. J., and Thomas, J. D. R., Analyst 97, 420 (1972).
Davies, J. E. W., Moody, G. J., Price, W. M., and Thomas, J. D. R., Lab. Practice 22, 20 (1973).
Hiiro, K., Moody, G. J., and Thomas, J. D. R., Talanta 22, 918 (1975).
Craggs, A., Keil, L., Moody, G. J., and Thomas, J. D. R., Talanta 22, 907 (1975).
Craggs, A., Moody, G. J., and Thomas, J. D. R., J. Chem. Educ. 51, 541 (1974).
Simon, W., and Morf, W. E., in: Membranes-A Series of Advances (G. Eisenman, ed.), Vol. 2, Dekker, New York (1972).
Ryan, T. H. W., Ph.D. Thesis, University of London, 1974.
Dietrich, W. C., Tech. Progr. Rep. No. Y1174D, Y-12 Development Division, Aug.-Oct., 1971.
Ryba, O., Kniiabkovâ, E., and Petrânek, J., Coll. Czech. Chem. Commun. 38, 497 (1973).
Ryba, O., and Petrânek, J., Anal. Chim. Acta. 64, 425 (1973).
Petrânek, J., and Ryba, O., Anal. Chim. Acta. 72, 375 (1974).
Stejíânova, I., and Vadura, R., Chem. Listy 68, 853 (1974).
Morf, W. E., Ammann, D., and Simon, W., Chimia 28, 65 (1974).
Thoma, A. P., Cimerman, Z., Fiedler, U., Bedekovie, D., Güggi, M., Jordan, P., May, K., Pretsch, E., Prelog, V., and Simon, W., Chimia 29, 344 (1975).
Scholer, R., and Simon, W., Hell). Chico. Acta 55, 1801 (1972).
Hulanicki, A., and Lewandowski, R., Chemi. Anal. 19, 53 (1974).
Ishibashi, N., Jyo, A., and Matsumoto, K., Chem. Lett. 12, 97 (1973).
Rohm, T. J., and Guilbault, G. G., Anal. Chem. 46, 590 (1974).
Tanaka, T., Hiiro, K., and Kawahara, A., Anal. Lett. 7 (3), 173 (1974).
Manning, D. L., Stokely, J. R., and Magowyrk, D. W., Anal. Chem. 46, 1116 (1974).
Baum, G., and Lynn, M., Anal. Chim. Acta 65, 393 (1973).
Nikolskii, B. P., Materova, E. A., Grekovich, A. L., and Yurinskaya, V. E., Zh. Anal. Khim. 29, 205 (1974).
Keil, L., Moody, G. J., and Thomas, J. D. R., Analyst. 102, 274 (1977).
Cutler, S., Ph.D. Thesis, University of Aberdeen, 1975.
Cattrall, R. W., and Chin-Poh, P., Anal. Chem. 47, 93 (1975).
Ansaldi, A., and Epstein, S. I., Anal. Chem. 45, 595 (1973).
Cattrall, R. W., and Freiser, H., Anal. Chem. 43, 1905 (1971).
James, H., Garmack, G., and Freiser, H., Anal. Chem. 44, 586 (1972).
Smith, M. D., Genshaw, M. A., and Greyson, J., Anal. Chem. 45, 1782 (1973).
Cattrall, R. W., Tribuzio, S., and Freiser, H., Anal. Chem. 46, 2223 (1974).
Cattrall, R. W., Drew, D. M., and Hamilton, I. C., Anal. Chim. Acta 76, 269 (1975).
Cattrall, R. W., and Drew, D. M., Anal. Chim. Acta 77, 9 (1975).
Fujinaga, T., Okazaki, T. S., and Freiser, H., Anal. Chem. 46, 1842 (1974).
Hopirtean, E., Liteanu, C., and Stefaniga, E., Rev. Roum. Chim. 19, 1651 (1974).
Rúiicka, J., Hansen, E. H., and Tjell, J. C., Anal. Chim. Acta 67, 155 (1973).
Fiedler, U., and Rúzicka, J., Anal. Chim. Acta 67, 179 (1973).
Hussein, W. R., and Guilbault, G. G., Anal. Chim. Acta 76, 183 (1975).
Jaber, A. M. Y., Moody, G. J., and Thomas, J. D. R., Analyst 101, 179 (1976).
Durst, R. A., ed., Ion Selective Electrodes, National Bureau of Standards (U.S.) Spec. Publ. No. 314 (1969).
Moody, G. J., and Thomas, J. D. R., Selective Ion Sensitive Electrodes, Merrow, Watford (1971).
Ross, J. W., in reference 46.
Simon, W., Morf, W. E., and Meier, P. Ch., in Structure and Bonding (J. D. Dunitz, P. Hemmerich, J. A. Ibers, C. K. Jorgensen, J. B. Neilands, R. S. Nyholm, D. Reinen, and R. J. P. Williams, eds.), Vol. 16, p. 113, Springer-Verlag, Berlin and New York (1973).
Morf, W. E., Ammann, D., Pretsch, E., and Simon, W., Pure Appl. Chem. 36, 421 (1973).
Jaber, A. M. Y., Moody, G. J., and Thomas, J. D. R., unpublished results.
Liteanu, C., and Hopirtean, E., Chem. Anal. 17, 859 (1972).
Jaber, A. M. Y., Moody, G. J., and Thomas, J. D. R., in preparation.
Rúiicka, J., private communication.
Moody, G. J., and Thomas, J. D. R., Lab. Practice 23, 475 (1974).
International Union of Pure and Applied Chemistry, Recommendations for Nomenclature of Ion-Selective Electrodes, Pure Appl. Chem., 48, 127 (1976).
Fleet, B., Ryan, T. H., and Brand, M. J. D., Anal. Chem. 46, 12 (1974).
Moody, G. J., and Thomas, J. D. R., Chem. Ind. 6, 44 (1974).
Schill, G., Svensk Kem. Tids. 80, 323 (1968).
Back, S., and Sandblom, J., Anal. Chem. 45, 1680 (1973).
Craggs, A., Moody, G. J., and Thomas, J. D. R., and Willcox, A., Talanta, 23, 799 (1976).
McDowell, W. J., and Coleman, C. F., J. Inorg. Nucl. Chem. 28, 1083 (1966).
James, H. J., Carmack, G. P., and Freiser, H., Anal. Chem. 44, 853 (1972).
Eyal, E., and Rechnitz, G., Anal. Chem. 43, 1090 (1970).
Bailey, C. A. M., and Dalziel, J. A. W., IUPAC Int. Symp. Selective Ion-Sensitive Electrodes,UWIST, Cardiff, 1973, Abstract 25.
Carmack, G. D., and Freiser, H., Anal. Chem., 47, 2249 (1975).
Thomas, J. D. R., Proc. Soc. Anal. Chem. 11, 340 (1974).
Craggs, A., Moody, G. J., and Thomas, J. D. R., Proc. Anal. Div. Chem. Soc. 12, 64 (1975).
Moody, G. J., Thomas, J. D. R., and Willcox, A., unpublished results.
Pungor, E., and Toth, K., Pure Appl. Chem. 36, 441 (1973).
Mascini, M., and Liberti, A., Anal. Chim. Acta. 47, 339, (1969).
Mascini, M., and Liberti, A., Anal. Chico. Acta. 51, 231, (1970).
Mascini, M., and Liberti, A., Anal. Chim. Acta. 53, 202, (1971).
Mascini, M., and Liberti, A., Anal. Chim. Acta. 60, 405, (1972).
Kneebone, B. M., and Freiser, H., Anal. Chem. 45, 449, (1973).
Pick, J., Toth, K., Pungor, E., Vasek, M., and Simon, W., Anal. Chico. Acta 64, 477 (1973).
Schiffer, D. K., Hochhauser, A., Evans, D. F., and Cussler, E. L., Nature 250, 484 (1974).
Choy, E. M., Evans, D. F., and Cussler, E. L., J. Am. Chem. Soc. 96, 7085 (1975).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1978 Plenum Press, New York
About this chapter
Cite this chapter
Moody, G.J., Thomas, J.D.R. (1978). Poly(Vinyl Chloride) Matrix Membrane Ion-Selective Electrodes. In: Freiser, H. (eds) Ion-Selective Electrodes in Analytical Chemistry. Modern Analytical Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2592-5_4
Download citation
DOI: https://doi.org/10.1007/978-1-4684-2592-5_4
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-2594-9
Online ISBN: 978-1-4684-2592-5
eBook Packages: Springer Book Archive