Abstract
Lattice imperfections have long been considered to be possible sites of catalytic activity in solids. Considerable research work has been undertaken with the aim of demonstrating such a relationship; but discrepant results have been reported in this field (1 – 4) Nevertheless, in some recent publications (5 – 7) a good correlation has been found between activity of deformed metal sheets and their lattice-defect content, mainly dislocations, as shown by structural investigations. Studies on metal powders are not so numerous. This is mostly due to the difficulty in assessing quantitatively the defect structure of powder catalysts. Also in this sphere, different explanations have been suggested to account for changes in powder activity originated by thermal and mechanical treatment (8 – 9).
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J.M. Thomas, Adv. Catal. 19, 293 (1969)
K.B. Keating, A.G.Rozner and J.L.Youngblood,J.Catal. 4, 608 (1965)
E.M.A. Willhoft, Chem. Commun. 3, 146 (1968).
R. Schmidt, Dissertation, Physikalisch-Chemisches Institut der Universität München (1971).
S. Kishimoto, J.Phys.Chem. 77, 1719 (1973).
J.M.Criado,E.J.Herrera and J.M.Trillo, Proc 5th Int. Congr. on Catal.,North Holland Pub.Co., Amsterdam (1073) p. 541.
J.Carrión,J.M.Criado,F.Gonzâlez,E.J.Herrera and J.M. Trillo, Electrón. Fisc. Apli. 17, 221 (1974).
E.M.Hofer et al., Trans. Faraday Soc. 60, 1457 (1964).
R. Schrader et al., Acta Chim.Acad.Sci.Hung. 55, 39 (1968).
W.A.Rachinger,J.Sci Instr. 25, 254 (1948).
J.M.Trillo et al., Catal. Rev., 7, 51 (1972).
J.M. Criado et al., Rev. Chim. Min., 1041 (1970).
J.M.Criado et al., Thermochim. Acta 12, 337 (1975)
M. Polanyi,E.Wigner,Trans.Farad.Soc. 40, 488 (1944).
A.W.Coats and J.P. Redfern,Nature 201, 68 (1964).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1977 Springer Science+Business Media New York
About this chapter
Cite this chapter
Carrión, J., Criado, J.M., Herrera, E.J., Torres, C. (1977). Some Observations on the Chemical Reactivity of Nickel Powder Mechanically Treated by Grinding. In: Wood, J., Lindqvist, O., Helgesson, C., Vannerberg, NG. (eds) Reactivity of Solids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2340-2_38
Download citation
DOI: https://doi.org/10.1007/978-1-4684-2340-2_38
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-2342-6
Online ISBN: 978-1-4684-2340-2
eBook Packages: Springer Book Archive