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Radiotracers in Minerals Engineering

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Physicochemical Methods of Mineral Analysis
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Abstract

Radioisotopes and general radiochemical techniques find a multitude of uses in the mineral processing and metallurgical industries, for two principal reasons. Both are based on the simplicity of detecting the radiation emitted by radioisotopes and of using the radiation not only to identify the radioisotope involved but also to measure its concentration in the system being monitored. Thus, on the one hand, a radioactive isotope may be introduced into a reacting system and, because the isotope will behave chemically in a manner identical to all the other isotopes of the same element present, it then becomes possible to follow the reaction without chemically interfering with the system in any way. This ability may be crucial, for example in studying, surface reactions such as froth flotation, where the concentrations of the reagents involved are very small; in studies involving interchange between the solid and the gas phase, as in many processes in pyrometallurgy; or in studies of solvent extraction or ion exchange methods. On the other hand, the fact that many non-radioactive isotopes can be converted into a radioactive form, in situ, can provide a sensitive, non-destructive method of detecting very small concentrations of these elements.

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References

  1. G. FRIEDLANDER, J. W. KENNEDY and J. M. MILLER, ‘Nuclear and Radiochemistry’ (John Wiley and Sons, Inc., New York and London, 1966).

    Google Scholar 

  2. M. B. A. CRESPI, Pure Appl. Chem., 26, 259(1971).

    Google Scholar 

  3. N. FEATHER, Proc. Camb. Phil. Soc., 34, 599 (1938).

    Google Scholar 

  4. G. von HEVESEY and H. LEVI, Kgl. Danske Videnskab Mat. fys. Medd., 14, 5(1936).

    Google Scholar 

  5. G.T. SEABORG and J. J. LIVINGHOOD, J. Am. Chem. Soc., 60, 1784 (1938).

    Google Scholar 

  6. A. A. GRIENBERG, Achievements in Chem., 9, 771 (1940).

    Google Scholar 

  7. J. L. STRAIN, IAEA. Conf. Radiochem. Methods of Anal., Salzburg, SM 55/48 (1965).

    Google Scholar 

  8. A. ZEMANN, Sbornik Ref. Sem. Aktiv. Anal. Modrg. (Czechoslovakia), 14(1963).

    Google Scholar 

  9. W. W. MEINKE, Anal. Chem., 30, 686 (1958).

    Google Scholar 

  10. Y. KUSAKA, Zeits. Anal. Chem., 172, 199 (1960).

    Google Scholar 

  11. A. J. MOSES, ‘Nuclear Techniques in Analytical Chemistry’ (Pergamon Press, Oxford, 1964).

    Google Scholar 

  12. O. REIFENSCHWEILER, Proc. Int. Conf. on Modern Trends in Activation Anal., Gaithersburg, Maryland. paper 20 (1968).

    Google Scholar 

  13. J. E. STRAIN, Prog. in Nucl. Energy, Ser IX, 4, 137 (1965).

    Google Scholar 

  14. J. D. BUCHANAN, Atomparxis, 8, 272 (1962).

    Google Scholar 

  15. V. P. GUINN, Proc. IAEA Seminar Prod. and Use Short Lived Radioisotopes from Reactors, Vienna, 2, 3 (1962).

    Google Scholar 

  16. W. W. MEINKE, Anal Chem., 31, 792 (1959).

    Google Scholar 

  17. H. J. M. BOWEN and D. GIBBONS, ‘Radioactivation Analysis’ (Oxford, Clarendon Press, Oxford, 1963).

    Google Scholar 

  18. G. LELIAERT, J. HOSTE and Z. EECKAUT, Nature, 182, 600 (1958).

    Google Scholar 

  19. J. HOSTE, F. BOUTEN and F. ADAMS, Nucleonics, 19(3), 118 (1961).

    Google Scholar 

  20. W. W. MEINKE, Proc. Int. Conf. on Modern Trends in Activation Anal, College Station, Texas, paper 36, (1961).

    Google Scholar 

  21. J. RUZICKA and J. STARY, Talanta, 10, 287 (1963).

    Google Scholar 

  22. J. STARY, J. RUZICKA and A. ZEMANN, Anal Chirn. Acta, 29, 103 (1963).

    Google Scholar 

  23. D. F. COVELL, Anal. Chem., 31, 1785 (1959).

    Google Scholar 

  24. W. D. EHMANN, Fortschr. Chem. Forsch., 14, 49 (1970).

    Google Scholar 

  25. W. E. KUYKENDALL JR, R. E. WAINERDI and ASSOCIATES, Proc. Use Radioisotopes Phys. Sci. and Ind., Copenhagen, 233 (1960).

    Google Scholar 

  26. W. E. KUYKENDALL JR. and R. E. WAINERDI, Trans. Amer. Nucl. Soc., 3, 95(1960).

    Google Scholar 

  27. O. U. andERS and W. H. BEAMER, Anal. Chem., 33, 226 (1961).

    Google Scholar 

  28. J. W. NOSTRand JR, A. J. FAVELE, H. WINTON and M. D. D’ABOSTINO, Trans. Amer. Nucl. Soc., 3, 412 (1960).

    Google Scholar 

  29. W. R. BURRUS, Trans. Amer. Nucl Soc., 6, 173 (1963).

    Google Scholar 

  30. D. L. MORRISON and D. N. SUNDERMAN, Trans. Amer. Nucl. Soc., 6, 174(1963).

    Google Scholar 

  31. J. W. WINCHESTER and J. A. CATAGGIO, Proc. Use Nucl. Tech. Prospecting and Development Min. Resources, IAEA, Buenos Aires, 435 (1968).

    Google Scholar 

  32. H. P. YULE, Anal Chem., 37, 37 (1965).

    Google Scholar 

  33. E. N. JENKINS and A. A. SMALES, Quart. Rev. Chem. Soc., 10, 83 (1956).

    Google Scholar 

  34. A. K. DE and W. W. MEINKE, Anal Chem., 30, 1474 (1958).

    Google Scholar 

  35. S. C. MATHUR and G. OLDHAM, Nucl Energy, 136 (1967).

    Google Scholar 

  36. W. E. MOTT and J. M. ORANGE, Anal Chem, 37, 1338 (1965).

    Google Scholar 

  37. J. D. MAHONY and S. S. MARKOVITZ, Anal. Chem., 33, 329 (1961).

    Google Scholar 

  38. H. R. LUKENS, J. W. OTVOS and C. D. WAGNER, Int. J. Appl. Radiation Isotopes, 11, 30(1961).

    Google Scholar 

  39. J. W. OTVOS, V. P. GUINN, H. R. LUKENS and C. D. WAGNER, Nucl Instr. Methods, 11, 187 (1961).

    Google Scholar 

  40. R. C. GREENWOOD and J. REED, Proc. Int. Conf. on Modem Trends in Activation Anal, College Station, Texas, paper (1961).

    Google Scholar 

  41. T. B. PIERCE, P. F. PECK and W. M. HENRY, Nature, 204, 571 (1964).

    Google Scholar 

  42. T. B. PIERCE, P. F. PECK and W. M. HENRY, Analyst, 90, 339 (1965).

    Google Scholar 

  43. J. W. HAFFNER and D. OESTREICH, Trans. Amer. Nucl. Soc., 5, 290 (1962).

    Google Scholar 

  44. G. von HEVESEY and F. A. PANETH, ‘Radioactivity’ (Oxford, Clarendon Press, Oxford, 1938).

    Google Scholar 

  45. H. BEQUEREL, Compt. Rend., 122, 1086 (1896).

    Google Scholar 

  46. M. M. SHAPIRO, Rev. Mod. Phys., 13, 58 (1941).

    Google Scholar 

  47. J. H. WEBB, Phys. Rev., 74, 511 (1948).

    Google Scholar 

  48. H. YAGODA, ‘Radioactive Measurements with Nuclear Emulsions’ (John Wiley and Sons, Inc., New York and London, 1949).

    Google Scholar 

  49. A. BIESER, Mod. Phys., 24, 273 (1952).

    Google Scholar 

  50. W. P. NORRIS and L. A. WOODRUFF, Ann. Rev. Nucl. Sci., 5, 297 (1955).

    Google Scholar 

  51. Y. GOLDSCHMIDT-CLERMONT, Ann. Rev. Nucl Sci., 3, 141 (1953).

    Google Scholar 

  52. P. J. FITZGERALD, E. B. SIMMEL, J. WENSTEIN and C. MARTIN, Lab. Invest., 2, 181 (1953).

    Google Scholar 

  53. J. GROSS, R. BOGOROCH, N. J. NADLER and C. P. LEBLOND, Amer. J. Roentg. Radium Therapy, 65, 420 (1951).

    Google Scholar 

  54. S. H. U. BOWIE, ‘Physical Methods in Determinative Mineralogy’, J. Zussmann (ed) (Academic Press, London and New York, 1967), Chapter 12.

    Google Scholar 

  55. S. H. U. BOWIE, Bull. Geol. Surv. Gt. Brit., 3, 58 (1951).

    Google Scholar 

  56. P. B. PRICE and R. M. WALKER, Appl. Phys. Lett., 2, 23 (1963).

    Google Scholar 

  57. R. F. FLEISCHER, C. W. NAESER, P. B. PRICE, R. M. WALKER and U. B. MARWIN, Science, 148, 629(1965).

    Google Scholar 

  58. D. E. FISHER and K. BOSTRUM, Nature, 224, 64 (1969).

    Google Scholar 

  59. V. MURALI, P. P. PAREKH and M. SANKARDAS, Anal. Chim. Acta, 50, 71 (1970).

    Google Scholar 

  60. J. W. WINCHESTER, ‘Radioactivation Analysis in Inorganic Geochemistry’, Prog. in Inorg. Chem., Vol. 2, F. A. Cotton (ed), (Interscience, New York, 1960).

    Google Scholar 

  61. G. H. MORRISON (ed), ‘Trace Analysis, Physical Methods’ (Inter-science, New York, 1960).

    Google Scholar 

  62. M. PINTA, ‘Detection and Determination of Trace Elements’ (Daniel Davey, New York, 1966).

    Google Scholar 

  63. W. W. MEINKE and B. F. SCRIBNER (editors), ‘Trace Characterization, Chemical and Physical’, U.S.N.B.S. Monograph 10D, Washington, D.C. (1967).

    Google Scholar 

  64. N. D. CHERONIS (ed), ‘Submicrogram Experimentation’ (Interscience, New York, 1961).

    Google Scholar 

  65. T. B. PIERCE, Sec. Symp. Rec. Devel. Neutron Activation Anal, Cambridge, U.K., 3(1971).

    Google Scholar 

  66. R. W. TOLMIE and L. J. THOMPSON, Proc. Symp. Use Nucl. Tech. Prospecting and Development of Min. Resources, IAEA, Buenos Aires, 504(1968).

    Google Scholar 

  67. R. E. WAINERDI, E. A. UKEN, G. G. SANTOS and H. P. YULE, Ibid, 533.

    Google Scholar 

  68. G. E. GORDON, K. RandLE, G. G. GOLE, J. B. CORLISS, M. H. BEESON and S. S. OXLEY, Geochim. Cosmochim. Acta, 32, 369 (1968).

    Google Scholar 

  69. M. RAKOVIC, ‘Activation Analysis’ (Iliffe, London, 1970).

    Google Scholar 

  70. L. LOVBERG, H. KUNZENDORF and J. HANSEN, Proc. Symp. Use Nucl. Tech. Prospecting and Development of Min. Resources, IAEA, Buenos Aires, 197 (1968).

    Google Scholar 

  71. J. H. CZUBEK, Ibid, 3.

    Google Scholar 

  72. C. W. TITTLE, Proc. Symp. Radioisotope Instr. Ind. Geophys., IAEA, Warsaw, 3(1968).

    Google Scholar 

  73. A. PRADZYNSKI, Proc. Symp. Use Nucl. Tech. Prospecting and Development Min. Resources, IAEA, Buenos Aires, 451 (1968).

    Google Scholar 

  74. A. M. GAUDIN, Trans. I. M. M., 62, 29 (1952).

    Google Scholar 

  75. T. C. MARTIN, Trans. Amer. Nucl. Soc., 6, 181 (1963).

    Google Scholar 

  76. C. POOVEY and D. Q. COVAULT, Georgia Inst. Tech., Eng. Exptl. Station, Atlanta, Publ. SRO-47 (1961).

    Google Scholar 

  77. R. LIEBERMAN, C. W. TOWNLEY, C. T. BROWN, J. E. HOWES JR, R. E. EWING and D. N. SUNDERMAN, Battelle Memorial Inst., Columbus, Ohio, Publ. BMI-1505 (1961).

    Google Scholar 

  78. H. HAMAGUCHI, R. KURODA, T. SHIMIZU, R. SUGISITA, I. TSUKAHARA and R. YAMAMOTA, Nippon Genshirhoku Gekkaishi, 3, 800(1961).

    Google Scholar 

  79. G. C. GOODE, C. W. BAKER and N. M. BROOKE, Analyst, 94, 728 (1969).

    Google Scholar 

  80. A. V. TOPCHIEV, I. T. ALADIEV and P. S. SAVITSKI, Proc. Sec. Int. Conf. Peaceful Uses of Atomic Energy, Geneva, 19, 61 (1958).

    Google Scholar 

  81. A. B. TESMAN, Metal Prog., 115(1959).

    Google Scholar 

  82. M. SERIZAWA, Tetsu to Hagane, 43, 938 (1957).

    Google Scholar 

  83. T. WINKLER and J. CHAPMAN, Amer. Inst. Min. Eng. Tech. Publ. 1987(1946).

    Google Scholar 

  84. I. S. KULIKOV and A. A. ZHOKHOVITSKY, Prod. and Treat. of Steel, Vol. XXXII of Collected Works of Stalin Inst. Moscow, State Metalle Publ. Houses 54 (1954).

    Google Scholar 

  85. I. N. PLAKSIN, Annals Acad. Sci. U.S.S.R., Dept. Tech, Sci., 1, 109 (1955).

    Google Scholar 

  86. J. FODOR and C. VARGA, Proc. Sec. Int. Conf. Peaceful Uses Atomic Energy, 19, 231 (1958).

    Google Scholar 

  87. T. SAITO, Proc. Sec. Int. Conf. Peaceful Uses Atomic Energy, 19, 201 (1958).

    Google Scholar 

  88. M. S. BELTSKY and V. P. MATCHOVETZ, Tzvetnce Metalle, xx, (1955).

    Google Scholar 

  89. U. A. LUOTA, Nag. Symp. Instr. Ind. Sparamn., Teck. foren. Fin. forhandl, 5 (1957).

    Google Scholar 

  90. U. BEEN and E. SAELand, Proc. First Int. Conf. Peaceful Uses Atomic Energy, 15, 170(1955).

    Google Scholar 

  91. A. M. GAUDIN, H. R. SPEDDEN and M. P. CORRIVEAU, Min. Eng., 3, 780(1951).

    Google Scholar 

  92. A. M. GAUDIN and C. S. CHANG, Trans. Amer. Inst. Min. Met. Engrs., 193, 193(1952).

    Google Scholar 

  93. A. M. GAUDIN, D. W. FUERSTENAU and M. M. TURKANUS, Min. Eng., 9, 65(1957).

    Google Scholar 

  94. O. S. BOGDANOV, B. Y. HAINMAN, M. A. YANIS and A. K. PODNEK, Proc. Int. Conf. Radioisotopes Sci. Res., Paris, P/72 (1957).

    Google Scholar 

  95. I. N. PLAKSIN, Proc. Sec. Int. Cong. Surf. Act. Butterworths, London, 1957.

    Google Scholar 

  96. I. N. PLAKSIN, R. SH. SHAFEEV and S. P. ZAITSEVA, Dokl. Akad. Nauk S.E.S.R., 108, 905(1956).

    Google Scholar 

  97. I. N. PLAKSIN, Proc. Conf. Use Radioisotopes Phys. Sci. and Ind., IAEA, Copenhagen, 1, 483 (1960).

    Google Scholar 

  98. I. N. PLAKSIN, Proc. Sec. Int. Conf. Peaceful Uses Atomic Energy, 19, 249(1958).

    Google Scholar 

  99. Y. P. GUPTA and T. B. KING, Trans. Met. Soc. AIME, 238, 1701 (1967).

    Google Scholar 

  100. P. G. SHEWMAN and F. N. RHINES, J. Metals, 6, 1021 (1954).

    Google Scholar 

  101. B. BROOK, A. ZAVYALOV and G. KAPIRIN, Proc. Sec. Int. Conf Peaceful Uses Atomic Energy, 19, 219 (1958).

    Google Scholar 

  102. H. L. TAVERES, P. E. AUN, A. A. MAESTRINI and M. T. MAGALHAES, Proc. Third Int. Conf Peaceful Uses Atomic Energy, 15, 341 (1965).

    Google Scholar 

  103. T. B. PIERCE, Selected Ann. Rev. Anal. Sci., 1, 133 (1971).

    Google Scholar 

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Lakshmanan, V.I., Lawson, G.J. (1975). Radiotracers in Minerals Engineering. In: Nicol, A.W. (eds) Physicochemical Methods of Mineral Analysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2046-3_4

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  • DOI: https://doi.org/10.1007/978-1-4684-2046-3_4

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