Skip to main content

X-ray Fluorescence

  • Chapter
  • 200 Accesses

Abstract

The status of chemical analysis by X-ray fluorescence has developed from that of a laboratory curiosity in the decade 1940–50 to its current position as an almost universal method with, according to a recent estimate, over 8000 spectrometers in use throughout the world. The rapid growth and the advances in technique during that time are largely due to post-war developments in vacuum technology and electronics, which not only have replaced pumped X-ray tubes by the more stable sealed versions, but also have led to direct methods of detecting and estimating X-ray photons superseding film based methods. The modern X-ray spectrometer is, therefore, a sophisticated electronic instrument capable of accurate, fully automatic analysis, with obvious potential in on-line process control, as discussed in Chapter 6.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. DEPARTMENT OF EMPLOYMENT AND PRODUCTIVITY, ‘Code of Practice for the protection of persons exposed to ionising radiations in research and teaching’; H.M.S.O., London, 1968.

    Google Scholar 

  2. ‘Report of International Union of Crystallography’, Acta Cryst., 16, 324(1963).

    Google Scholar 

  3. R. JENKINS and D. J. HAAS, X-ray Spectrom., 2, 135 (1973).

    Article  Google Scholar 

  4. H. G. J. MOSELEY, Phil Mag., 27, 703 (1914).

    Google Scholar 

  5. T. B. JOHANSSON, R. AKSELSSON, and S. A. E. JOHANSSON, Nucl. Instrum. Meth., 84, 141 (1970).

    Article  Google Scholar 

  6. G. VON HEVESY, ‘Chemical Analysis by X-rays and its Applications’; McGraw-Hill, New York, 1932.

    Google Scholar 

  7. B. J. PRICE, ‘Metals and Materials’, 140(1973).

    Google Scholar 

  8. S. H. U. BOWIE, Mining Mag., 118, 1 (1968).

    Google Scholar 

  9. J. R. RHODES, in A.S.T.M. Special Tech. Publ. 485, 243 (1970).

    Google Scholar 

  10. H. A. KRAMERS, Phil. Mag., 46, 836 (1923).

    Google Scholar 

  11. K. LONSDALE (ed), ‘International Tables for X-ray Crystallography’, Vol. III; International Union of Crystallography, Kynoch Press, Birmingham, 1962.

    Google Scholar 

  12. A.S.T.M., ‘X-ray Emission and Absorption Wavelengths and Two-Theta Tables’, A.S.T.M. Data Series DS 37A (1970).

    Google Scholar 

  13. J. A. VICTOREEN, J.Appl. Phys., 20, 1141 (1949).

    Article  Google Scholar 

  14. K. F. J. HEINRICH, The Electron Microprobe’; John Wiley and Sons, New York and London, 1966.

    Google Scholar 

  15. R. THEISEN and D. VOLLARTH, Tables of X-ray Mass Attenuation Coefficients’; Verlag Stahleisen M.B.H., Düsseldorf, 1967.

    Google Scholar 

  16. R. JENKINS and J. L. DE VRIES, ‘Practical X-ray Spectrometry’; Macmillan, London and New York, 1967.

    Google Scholar 

  17. R. JENKINS, X-ray Spectrom., 1, 23 (1972).

    Article  Google Scholar 

  18. B. POST and R. JENKINS, X-ray Spectrom., 1, 161 (1972).

    Article  Google Scholar 

  19. G. L. HENDRY, X-ray Spectrom. (In Press).

    Google Scholar 

  20. R. JENKINS and P. W. HURLEY, Can. Spectros., 13, 35 (1968).

    Google Scholar 

  21. L. V. SUTFIN and R. E. OGILVIE, in A.S.T.M. Special Tech. Publ. 485, 197(1970).

    Google Scholar 

  22. B. L. HENKE, ‘Advances in X-ray Analysis’; 5, 288 (1961).

    Google Scholar 

  23. W. L. BAUN and E. W. WHITE, Anal. Chem., 41, 831 (1969).

    Article  Google Scholar 

  24. C. F. GAMAGE, X-ray Spectrom., 1, 99 (1972).

    Article  Google Scholar 

  25. H. WOLLENBERG, H. KUNZENDORF, and J. ROSE-HANSEN, Econ. Geol., 66, 1048(1971).

    Article  Google Scholar 

  26. A.S.T.M., ‘Energy Dispersion X-ray Analysis: X-ray and Electron Probe Analysis’, A.S. T.M. Special Tech. Publ. 485, (1970).

    Google Scholar 

  27. A.S.T.M., ‘X-ray Emission Wavelengths and KeV Tables for Non-diffractive Analysis’, A.S. T.M. Report DS46 (1971).

    Google Scholar 

  28. R. G. MUSKET and W. BAUER, J.Appl. Phys., 43, 4786 (1972).

    Article  Google Scholar 

  29. R. JENKINS and J. L. DE VRIES, ‘Practical X-ray Spectrometry’; Macmillan, London and New York, 1967, Chapter 5.

    Google Scholar 

  30. R. O. MüLLER, ‘Spectrochemical Analysis by X-ray Fluorescence’; Adam Hilger, London, 1972.

    Google Scholar 

  31. G. L. HENDRY, Proc. 5th. Conf. on X-ray Anal. Methods, Swansea,72 (1966).

    Google Scholar 

  32. B. GUNN, ‘Advances in X-ray Analysis’, 4, 382 (1960).

    Google Scholar 

  33. W. K. de JONGH, Proc. 6th Conf. on X-ray Anal. Methods, Southampton, 1 (1968).

    Google Scholar 

  34. C. HUTCHISON, ‘Laboratory Handbook of Petrographic Techniques’, Wiley Interscience, 1974.

    Google Scholar 

  35. F. CLAISSE, Quebec Dept. Mines, Prelim. Rept., 32 (1956).

    Google Scholar 

  36. G. K. CZAMANSKI, J. HOWER, and R. C. MILLARD, Geochim. et Cosmochim. Acta, 30, 745 (1966).

    Article  Google Scholar 

  37. K. NORRISH and J. T. HUTTON, Geochim. et Cosmochim. Acta, 33, 431 (1969).

    Article  Google Scholar 

  38. P. K. HARVEY, D. M. TAYLOR, R. D. HENDRY, and F. BANCROFT, X-ray Spectrom., 2, 33 (1973).

    Article  Google Scholar 

  39. P. R. HOOPER and L. ATKINS, Miner Mag., 37, 409 (1969).

    Article  Google Scholar 

  40. R. TERTIAN, Spectrochim. Acta, 24B, 447 (1969).

    Google Scholar 

  41. Z. H. KALMAN and L. HELLER, Anal Chem., 34, 946 (1962).

    Article  Google Scholar 

  42. S. D. RASBERRY and F. J. HEINRICH, Proc. Colloq. Spectro-scopicum Internationale XVI, Heidelberg, 1, 337 (1971).

    Google Scholar 

  43. R. TERTIAN, X-ray Spectrom., 2, 95 (1973).

    Article  Google Scholar 

  44. P. G. LUMB, Proc. 7th Conf. on X-ray Anal Methods, Durham, 27 (1970).

    Google Scholar 

  45. T. PADFIELD and A. GRAY, Bull FS 35, Anal. Equipment Dept., Philips, Eindhoven, 1970.

    Google Scholar 

  46. B. E. LEAKE, G. L. HENDRY, A. KEMP, A. G. PLANT, P. K. HARVEY, J. R. WILSON, J. S. COATES, J. W. AUCOTT, T. LüNEL, and R. J. HOWARTH, Chem. Geol., 5, 7 (1969).

    Article  Google Scholar 

  47. K. NORRISH and B. W. CHAPPEL, ‘Physical Methods in Determinative Mineralogy’, J. Zussman (ed.); Academic Press, London and New York, 1967, Chapter 4.

    Google Scholar 

  48. T. J. CULLEN, Anal. Chem., 34, 812 (1962).

    Article  Google Scholar 

  49. R. C. REYNOLDS, Amer. Min., 48, 1133 (1963).

    Google Scholar 

  50. J. SHERMAN, Spectrochim. Acta, 7, 283 (1955).

    Google Scholar 

  51. H. J. BEATTIE and R. M. BRISSEY, Anal. Chem., 26, 980 (1954).

    Article  Google Scholar 

  52. W. MARTI, Spectrochim. Acta, 18, 1499 (1962).

    Google Scholar 

  53. G. R. LACHANCE and R. J. TRAILLE, Can. Spectros., 11, 43 (1966).

    Google Scholar 

  54. H. J. LUCAS-TOOTH and B. J. PRICE, Metallurgia, 64, 149 (1961).

    Google Scholar 

  55. R. JENKINS and A. CAMPBELL-WHITELAW, Can. Spectros., 15, 32 (1970).

    Google Scholar 

  56. W. JOHNSON, Proc. 4th. Conf. on X-ray Anal. Methods, Sheffield, 73 (1964).

    Google Scholar 

  57. W. K. DE JONGH, X-ray Spectrom., 2, 151 (1973).

    Article  Google Scholar 

  58. J. SHERMAN, ‘Advances in X-ray Analysis’, 1, 231 (1958).

    Google Scholar 

  59. R. TERTIAN, Spectrochim. Acta, 27B, 159 (1972).

    Google Scholar 

  60. R. TERTIAN and R. GENISCA, X-ray Spectrom., 1, 83 (1972).

    Article  Google Scholar 

  61. W. K. STEELE, Chem. Geol, 11, 149 (1973).

    Article  Google Scholar 

  62. R. W. LE MAITRE and M. T. HAUKKA, Geochim. et Cosmochim. Acta, 37, 708(1973).

    Article  Google Scholar 

  63. F. J. FLANAGAN, Geochim. et Cosmochim. Acta, 34, 121 (1970).

    Article  Google Scholar 

  64. F. J. FLANAGAN, Geochim. et Cosmochim. Acta, 37, 1201 (1973).

    Article  Google Scholar 

  65. N. G. WEST, G. L. HENDRY and N. T. BAILEY, X-ray Spectrom., 3, 78(1974).

    Article  Google Scholar 

  66. R. VIE le SAGE and B. GRUBIS, X-ray Spectrom, 2, 189 (1973).

    Article  Google Scholar 

  67. G. R. WEBBER, Geochim. et Cosmochim. Acta, 29, 229 (1965).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1975 Plenum Press, New York

About this chapter

Cite this chapter

Hendry, G.L. (1975). X-ray Fluorescence. In: Nicol, A.W. (eds) Physicochemical Methods of Mineral Analysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2046-3_3

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-2046-3_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-2048-7

  • Online ISBN: 978-1-4684-2046-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics