Abstract
An experimental and analytical investigation of the kinetics of formation of NO in shock-induced combustion of methane-oxygen-nitrogen mixtures diluted by argon has been carried out. Concentration histories of NO, OH and CO2 were measured during reaction behind reflected shock waves using spectroscopic techniques. Experimental concentration profiles were obtained for an oxidizer-rich and a fuel-rich mixture for initial post-shock temperatures in the range 2600–3200°K and for an initial post-shock pressure of 3.5 ± 0.5 atm. Time rates of change of species concentrations and thermodynamic properties during reaction were calculated by numerically integrating the coupled reaction kinetic, state and energy equations. Calculated concentration profiles were compared with experimental profiles to obtain information on the reaction mechanism for formation of NO. Observed NO formation rates in both the oxidizer-rich and fuel-rich mixture were consistent with a three-reaction mechanism for nitrogen chemistry,
Reactions 1 and 2 were found to be the principal NO formation reactions, with reaction 3 being of minor importance for the fuel-rich mixture.
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References
Ya. B. Zeldovich, P. Ya. Sadovnikov and D. A. Frank-Kamenetskii, “Oxidation of Nitrogen in Combustion.” Academy of Sciences of USSR, Institute of Chemical Physics, Moscow-Leningrad (trans, by M. Shelef), 1947.
C. P. Fenimore, “Formation of Nitric Oxide in Premixed Hydrocarbon Flames.” Thirteenth Symposium (International) on Combustion: The Combustion Institute, Pittsburgh, 1971, pp. 373–379.
H. K. Newhall and S. M. Shahed, “Kinetics of Nitric Oxide Formation in High-Pressure Flames.” Thirteenth Symposium (International) on Combustion: The Combustion Institute, Pittsburgh, 1971, pp. 381–388.
S. M. Shahed and H. K. Newhall, “Kinetics of Nitric Oxide Formation in Propane-Air and Hydrogen-Air-Diluent Flames. “Combustion and Flame, Vol 17 (in press).
M. E. Harris, V. R. Rowe, E. B. Cook and J. Grumer, “Reduction of Air Pollutants from Gas Burner Flames.” Bureau of Mines Bulletin 653, 1970.
C. T. Bowman, “Investigation of Nitric Oxide Formation Kinetics in Combustion Processes: The Hydrogen-Oxygen-Nitrogen Reaction.” Combustion Science and Technology, Vol. 3, 1971, pp. 37–45.
D. J. Seery and C. T. Bowman, “Dissociation of HCl Behind Shock Waves.” J. Chem. Phys., Vol. 48, 1968, pp. 4314–4317.
C. T. Bowman, “An Experimental and Analytical Investigation of the High-Temperature Oxidation Mechanisms of Hydrocarbon Fuels.” Combustion Science and Technology, Vol. 2, 1970, pp. 161–172.
D. J. Seery and C. T. Bowman, “An Experimental and Analytical Study of Methane Oxidation Behind Shock Waves.” Combustion and Flame, Vol. 14, 1970, pp. 37–48.
R. M. R. Higgin and A. Williams, “A Shock-Tube Investigation of the Combustion of Lean Methane and n-Butane Mixtures with Oxygen.” Twelfth Symposium (International) on Combustion: The Combustion Institute, Pittsburgh, 1969, pp. 579–587.
D. K. Stull (ed.), “JANAF Thermochemical Tables.” Midland, Michigan: Dow Chemical Company, 1965.
W. E. Wilson, “A Critical Review of the Combustion Reactions of the Hydroxyl Radical.” Paper presented at the Spring Meeting, Western Section, The Combustion Institute, Lajolla, California, April 1967.
A. A. Westenberg and N. deHaas, “Reinvestigation of the Rate Coefficients for O+H2 and O + CH4.”J. Chem. Phys. Vol. 50, 1969, pp. 2512–2516.
M. J. Kurylo and R. B. Timmons, “ESR Study of the Kinetics of the Reaction of H Atoms with Methane.” J. Chem.Phys. Vol. 50, 1969, pp. 5076–5087.
D. L. Baulch, D. D. Drysdale and A. C. Lloyd, “Critical Evaluation of Rate Data for Homogeneous Gas-Phase Reactions of Interest In High-Temperature Systems.” Dept. of Phys. Chem. Report Nos. 1–3, Leeds, England, 1968–69.
G. L. Schott and P. F. Bird, “Kinetics Studies of Hydroxyl Radicals in Shock Waves. IV. Recombination Rates in Rich Hydrogen-Oxygen Mixtures.” J. Chem. Phys., Vol. 41, 1964, pp. 2869–2876.
N. A. Generalov, S. A. Losev and V. A. Maksimenko, “Absorption of Ultraviolet Radiation by Strongly Heated Carbon Dioxide Gas.” Optics and Spectroscopy, Vol. 15, 1963, pp. 12–14.
P. Sulzer and K. Wieland, “Intensity Distribution of a Continuous Absorption Spectrum as a Function of Temperature and Wavenumber.” Helv. Phys. Acta, Vol. 25, 1952, pp. 653–676.
A. J. Blake, J. H. Carver and G. N. Haddad, “Photo-absorption Cross-sections of Molecular Oxygen between 1250 Å and 2350 Å.” I.Q.S.R.T., Vol. 6, 1966, pp. 451–459.
D. L. Baulch, D. D. Drysdale, D. G. Home and A. C. Lloyd, “Critical Evaluation of Rate Data for Honogeneous Gas-Phase Reactions of Interest in High-Temperature Systems.” Dept. of Phys. Chem. Report No. 4, Leeds, England, 1969.
I. M. Campbell and B. A. Thrush, “Reactivity of Hydrogen to Atomic Nitrogen and Atomic Oxygen.” Trans. Faraday Soc, Vol. 64, 1968, pp. 1265–1274.
J. B. Heywood, “Gas Turbine Combustor Modeling for Calculating Nitric Oxide Emissions.” Paper 71–712 presented at AIAA/SAE 7th Propulsion Joint Specialist Conference, Salt Lake City, Utah, June 1971.
R. S. Fletcher and J. B. Heywood, “A Model for Nitric Oxide Emissions from Aircraft Gas Turbine Engines.” Paper No. 71–123 presented at AIAA 9th Aerospace Sciences Meeting, New York, January 1971.
C. T. Bowman, unpublished results.
A. A. Westenberg, “Kinetics of NO and CO in Lean, Premixed Hydrocarbon-Air Flames”. Combustion Science and Technology, Vol. 4, 1971, pp. 59–64.
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Bowman, C.T., Seery, D.J. (1972). Investigation of No Formation Kinetics in Combustion Processes: the Methane-Oxygen-Nitrogen Reaction. In: Cornelius, W., Agnew, W.G. (eds) Emissions from Continuous Combustion Systems. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1998-6_7
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DOI: https://doi.org/10.1007/978-1-4684-1998-6_7
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