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Acid-base Behaviour

  • Chapter
Physical Chemistry of Organic Solvent Systems

Abstract

So ubiquitous is water on this planet that our view of chemistry, by custom and convenience, is strongly biased in favour of aqueous solutions. What then are we to make of other solvents where the strongest acid may be the least ionised, where a respectable acid like CH3CO2H behaves as a base, where an anion base achieves stabilisation only by bonding to a molecule of its conjugate acid? Examination of acids and bases in non-aqueous solvents cannot fail to be enlightening.

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  1. Department of Chemistry, Barnard College, Columbia University, New York, USA

    E. J. King

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  1. Department of Physical Chemistry, University of Newcastle upon Tyne, Newcastle, England

    A. K. Covington

  2. Electrochemisty Research Laboratory, Department of Physical Chemistry, University of Newcastle upon Tyne, Newcastle, England

    T. Dickinson

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King, E.J. (1973). Acid-base Behaviour. In: Covington, A.K., Dickinson, T. (eds) Physical Chemistry of Organic Solvent Systems. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1959-7_3

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