Skip to main content

Beam Studies of Ion-Molecule Reactions

  • Chapter

Abstract

Since the beginning of systematic studies of chemical reactions of gaseous ions, large amounts of data have been assembled by classical mass spectrometric methods. This information relates largely to what reactions and reaction sequences occur and the probabilities, or cross sections, of such processes. Beam studies of ion-molecule reactions can also provide such data; however, their great advantage is that they can determine not only the nature of products, but also their velocities and angular distributions. This makes possible a much more detailed and definitive insight into the mechanisms involved.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. D. R. Herschbach, Advan. Chem. Phys. 10, 332 (1966).

    Google Scholar 

  2. A. Henglein, K. Lacmann, and G. Jacobs, Ber. Bunsenges. Phys. Chem. 69, 279 (1965).

    CAS  Google Scholar 

  3. A. Ding, K. Lacmann, and A. Henglein, Ber. Bunsenges. Phys. Chem. 71, 596 (1967).

    CAS  Google Scholar 

  4. A. Ding, A. Henglein, and K. Lacmann, Z. Naturforsch. 23a, 779 (1968).

    CAS  Google Scholar 

  5. A. Ding, A. Henglein, D. Hyatt, and K. Lacmann, Z. Naturforsch. 23a, 2084 (1968).

    Google Scholar 

  6. R. D. Fink and J. S. King, Jr., J. Chem. Phys. 47, 1857 (1967).

    Article  CAS  Google Scholar 

  7. R. L. Champion, L. D. Doverspike, and T. L. Bailey, J. Chem. Phys. 45, 4377 (1966).

    Article  CAS  Google Scholar 

  8. W. R. Gentry, E. A. Gislason, Yuah-Tseh Lee, B. H. Mahan, and Chi-Wing Tsao, Disc. Faraday Soc. 44, 137 (1967).

    Article  Google Scholar 

  9. W. R. Gentry, E. A. Gislason, B. H. Mahan, and Chi-Wing Tsao, J. Chem. Phys. 49, 3058 (1968).

    Article  CAS  Google Scholar 

  10. B. Mahan, Acc. Chem. Res. 1, 217 (1968).

    Article  CAS  Google Scholar 

  11. L. D. Doverspike, R. L. Champion, and T. L. Bailey, J. Chem. Phys. 45, 4385 (1966).

    Article  CAS  Google Scholar 

  12. B. R. Turner, M. A. Fineman, and R. F. Stebbings, J. Chem. Phys. 42, 4088 (1965).

    Article  CAS  Google Scholar 

  13. Z. Herman, J. D. Kerstetter, T. L. Rose, and R. Wolfgang, Rev. Sci. Instr. 40, 538 (1969)

    Article  CAS  Google Scholar 

  14. R. Wolfgang, Acc. Chem. Res. 2, 248 (1969).

    Article  CAS  Google Scholar 

  15. E. Gustafsson and E. Lindholm, Ark. Fys. 18, 219 (1960).

    CAS  Google Scholar 

  16. D. R. Bates (Ed.), “Atomic and Molecular Processes,” p. 705, Academic Press, London (1962).

    Google Scholar 

  17. P. K. Rol and E. A. Entemann, J. Chem. Phys. 49, 1430 (1968).

    Article  CAS  Google Scholar 

  18. P. K. Rol and E. A. Entemann, Air Force Cambridge Research Laboratories Final Report, AFCLR-69–0022.

    Google Scholar 

  19. J. Durup and M. Durup, J. Chem. Phys. 64, 386 (1967).

    CAS  Google Scholar 

  20. M. Durup and J. Durup, in “Advances in Mass Spectrometry,” Vol. 4, p. 677, Institute of Petroleum (1968).

    Google Scholar 

  21. L. Malus, I. Opauszky, D. Hyatt, A. J. Mason, K. Birkinshaw, and M. J. Henchman, Disc. Faraday Soc. 44, 146 (1967).

    Article  Google Scholar 

  22. M. Henchman, private communication.

    Google Scholar 

  23. A. L. Schmeltekopf, F. C. Fehsenfeld, G. I. Gilman, and E. E. Ferguson, Planetary Space Sci. 15, 401 (1967).

    Article  CAS  Google Scholar 

  24. J. C. Tully, Z. Herman, and R. Wolfgang, J. Chem. Phys. 54, 1730 (1971).

    Article  CAS  Google Scholar 

  25. T. L. Rose, Thesis, Yale University 1967.

    Google Scholar 

  26. J. B. Anderson, R. P. Andres, and J. B. Fenn, Advan. Chem. Phys., 10, 275 (1966).

    Article  Google Scholar 

  27. E. A. Gislason, B. H. Mahan, Chi-Wing Tsao, and A. S. Werner, J. Chem. Phys. 50, 142 (1969).

    Article  CAS  Google Scholar 

  28. P. M. Hierl, Z. Herman, and R. Wolfgang, J. Chem. Phys. 53, 660 (1970).

    Article  CAS  Google Scholar 

  29. R. Wolfgang and R. J. Cross, Jr., J. Phys. Chem. 73, 743 (1969).

    Article  CAS  Google Scholar 

  30. J. Tully, private communication.

    Google Scholar 

  31. W. B. Miller, S. A. Safron, and D. R. Herschbach, Disc. Faraday Soc. 44, 108 (1967).

    Article  Google Scholar 

  32. R. Wolfgang, Acc. Chem. Res. 3, 48 (1970).

    Article  CAS  Google Scholar 

  33. P. Langevin, Ann. Chim. Phys. 5, 245 (1905).

    CAS  Google Scholar 

  34. G. Gioumousis and O. P. Stevenson, J. Chem. Phys. 29, 294 (1958).

    Article  CAS  Google Scholar 

  35. K. Lacmann and A. Henglein, Ber. Bunsenges. Phys. Chem. 69, 286 (1965).

    Google Scholar 

  36. K. Lacmann and A. Henglein, Ber. Bunsenges. Phys. Chem. 69, 292 (1965).

    Google Scholar 

  37. K. Lacmann, A. Henglein, and B. Knoll, J. Chem. Phys. 43, 1048 (1965).

    Article  Google Scholar 

  38. A. Henglein, in “Ion-Molecule Reactions in Gases” (Advances in Chemistry Series, No. 58, P. J. Ausloos, ed.), p. 63, American Chemical Society, Washington, D.C. (1966).

    Chapter  Google Scholar 

  39. V. Termâk and Z. Herman, Nucleonics 19, 106 (1961).

    Google Scholar 

  40. F. S. Klein and L. Friedman, J. Chem. Phys. 41, 1789 (1964).

    Article  CAS  Google Scholar 

  41. Z. Herman, J. Kerstetter, T. L. Rose, and R. Wolfgang, Disc. Faraday Soc. 44, 123 (1967).

    Article  Google Scholar 

  42. P. Hierl, Z. Herman, J. Kerstetter, and R. Wolfgang, J. Chem. Phys. 48, 4319 (1968).

    Article  CAS  Google Scholar 

  43. Z. Herman, J. Kerstetter, T. Rose, and R. Wolfgang, J. Chem. Phys. 46, 2844 (1967).

    Article  CAS  Google Scholar 

  44. J. Kerstetter, Thesis, Yale University (1969);

    Google Scholar 

  45. J. Kerstetter, and R. Wolfgang, J. Chem. Phys. 53, 3765 (1970).

    Article  CAS  Google Scholar 

  46. R. Suplinskas, J. Chem. Phys. 49, 5046 (1968).

    Article  CAS  Google Scholar 

  47. T. George and R. Suplinskas, J. Chem. Phys. 51, 3666 (1969).

    Article  CAS  Google Scholar 

  48. T. George and R. Suplinskas, J. Chem. Phys. 54, 1037 (1971).

    Article  CAS  Google Scholar 

  49. M. Chiang, E. A. Gislason, B. H. Mahan, C. W. Tsao, and A. S. Werner, J. Chem. Phys. 52, 2698 (1970).

    Article  CAS  Google Scholar 

  50. a. D. T. Chang and J. C. Light, J. Chem. Phys. (in press).

    Google Scholar 

  51. J. C. Light and S. Chan, J. Chem. Phys. 51, 1008 (1969).

    Article  CAS  Google Scholar 

  52. P. Kuntz, Chem. Phys. Letters 4, 129 (1969).

    Article  CAS  Google Scholar 

  53. J. L. Franklin and M. A. Haney, J. Phys. Chem. 73, 2857 (1969).

    Article  CAS  Google Scholar 

  54. P. Kuntz and J. C. Polanyi, Disc. Faraday Soc. 44, 180 (1967).

    Google Scholar 

  55. Z. Herman, P. Hierl, A. Lee, and R. Wolfgang, J. Chem. Phys. 51, 454 (1969).

    Article  CAS  Google Scholar 

  56. A. Ding, A. Henglein, and K. Lacmann, Z. Naturforsch. 23a, 780 (1968).

    CAS  Google Scholar 

  57. L. Matus, D. J. Hyatt, and M. J. Henchman, J. Chem. Phys. 46, 2439 (1967).

    Article  CAS  Google Scholar 

  58. R. F. Pottie, and W. H. Hamill, J. Phys. Chem. 63, 877 (1959);

    Article  CAS  Google Scholar 

  59. A. Henglein, Z. Naturforsch. 17a, 44 (1962);

    Google Scholar 

  60. A. Henglein, Z. Naturforsch. 18a, 98 (1963).

    Google Scholar 

  61. A. Ding, A. Henglein, D. Hyatt, and K. Lacmann, Z. Naturforsch. 23a, 2090 (1969).

    Google Scholar 

  62. A. Ding and A. Henglein, Ber. Bunsenges. Phys. Chem. 73, 562 (1969)

    CAS  Google Scholar 

  63. Z. Herman, A. Lee, and R. Wolfgang, J. Chem. Phys. 51, 452 (1969).

    Article  CAS  Google Scholar 

  64. A. Lee, Z. Herman, and R. Wolfgang, to be published.

    Google Scholar 

  65. E. A. Gislason, B. H. Mahan, Chi-Wing Tsao, and A. S. Werner, J. Chem. Phys. 50, 5418 (1969).

    Article  CAS  Google Scholar 

  66. F. A. Abramson and J. H. Futrell, J. Chem. Phys. 45, 1925 (1966).

    Article  CAS  Google Scholar 

  67. H. S. Johnston, “Gas Phase Reaction Rate Theory,” Ronald Press, New York (1966).

    Google Scholar 

  68. R. A. Marcus, J. Chem. Phys. 21, 359 (1952).

    Article  Google Scholar 

  69. L. S. Kassel, “Kinetics of Homogenous Gas Reactions,” The Chemical Catalog Co., New York (1932).

    Google Scholar 

  70. A. Ding, Z. Naturforsch. 24a, 856 (1969).

    CAS  Google Scholar 

  71. L. D. Doverspike and R. C. Champion, J. Chem. Phys. 46, 4718 (1967).

    Article  CAS  Google Scholar 

  72. W. R. Gentry, E. A. Gislason, B. H. Mahan, and Chi-Wing Tsao, J. Chem. Phys. 47, 1856 (1967).

    Article  CAS  Google Scholar 

  73. R. L. Champion and L. D. Doverspike, J. Chem. Phys. 49, 4321 (1968).

    Article  CAS  Google Scholar 

  74. D. W. Vance and T. L. Bailey, J. Chem. Phys. 44, 486 (1966).

    Article  CAS  Google Scholar 

  75. D. Hyatt and K. Lacmann, Z. Naturforsch. 23a, 2080 (1968).

    CAS  Google Scholar 

  76. J. Krenos and R. Wolfgang, J. Chem. Phys., 52, 5961 (1970).

    Article  CAS  Google Scholar 

  77. I. G. Csizmadia, J. C. Polanyi, A. C. Roach, and W. H. Wong, Can. J. Chem. 47, 4097 (1969).

    Article  CAS  Google Scholar 

  78. J. Krenos, R. Preston, R. Wolfgang, and J. Tully, Chem. Phys. Letters 10, 17 (1971).

    Article  CAS  Google Scholar 

  79. J. Krenos, Thesis, Yale University (1972).

    Google Scholar 

  80. M. G. Holliday, J. T. Muckerman, and L. Friedman, J. Chem. Phys. 54, 1058 (1971).

    Article  CAS  Google Scholar 

  81. W. B. Maier, II, J. Chem. Phys. 54, 2732 (1971).

    Article  CAS  Google Scholar 

  82. R. K. Preston and J. C. Tully, J. Chem. Phys. 54, 4297 (1971).

    Article  CAS  Google Scholar 

  83. J. C. Tully and R. K. Preston, J. Chem. Phys. 55, 562 (1971).

    Article  CAS  Google Scholar 

  84. M. Chiang, E. A. Gislason, B. H. Mahan, C. W. Tsao, and A. S. Werner, J. Chem. Phys. 52, 2698 (1970).

    Article  CAS  Google Scholar 

  85. E. A. Gislason, B. H. Mahan, C. W. Tsao, and A. S. Werner, J. Chem. Phys. 54, 3897 (1971).

    Article  CAS  Google Scholar 

  86. W. Felder, N. Sbar, and J. Dubrin, Chem. Phys. Letters 6, 385 (1970).

    Article  CAS  Google Scholar 

  87. J. J. Leventhal, J. Chem. Phys. 54, 3279 (1971).

    Article  CAS  Google Scholar 

  88. J. J. Leventhal, J. Chem. Phys. 54, 5102 (1971).

    Article  CAS  Google Scholar 

  89. J. J. Leventhal, J. Chem. Phys. 54, 4654 (1971).

    Article  Google Scholar 

  90. G. Bosse, A. Ding, and A. Henglein, Z. Naturforsch. 26a, 932 (1971).

    CAS  Google Scholar 

  91. G. Bosse, A. Ding, and A. Henglein, Ber. Bunsenges. Phys. Chem. 75, 413 (1971).

    CAS  Google Scholar 

  92. M. H. Chiang, B. H. Mahan, C. W. Tsao, and A. S. Werner, J. Chem. Phys. 53, 3752 (1970).

    Article  CAS  Google Scholar 

  93. A. Lee, R. L. LeRoy, Z. Herman, R. Wolfgang, and J. C. Tully, Chem. Phys. Letters (in press).

    Google Scholar 

  94. W. D. Held, J. Schöttler, and J. P. Toennies, Chem. Phys. Letters 6, 304 (1970).

    Article  CAS  Google Scholar 

  95. H. Udseth, C. F. Giese, and W. R. Gentry, J. Chem. Phys. 54, 3642 (1971).

    Article  CAS  Google Scholar 

  96. T. F. Moran, F. Petty, and G. S. Turner, Chem. Phys. Letters 9, 379 (1971).

    Article  CAS  Google Scholar 

  97. F. A. Herrero, E. M. Nemeth, and T. L. Bailey, J. Chem. Phys. 50, 4591 (1969).

    Article  CAS  Google Scholar 

  98. H-P. Weise, H. U. Mittmann, A. Ding, and A. Henglein, Z. Naturforsch. 25a, 1154 (1970).

    CAS  Google Scholar 

  99. R. L. Champion, L. D. Doverspike, W. G. Rich, and S. M. Bobbio, Phys. Rev. A2, 2328 (1970).

    Google Scholar 

  100. H. U. Mittmann, H.-P. Weise, A. Ding, and A. Henglein, Z. Naturforsch. 26a, 1112 (1971);

    CAS  Google Scholar 

  101. H. U. Mittmann, H.-P. Weise, A. Ding, and A. Henglein, Z. Naturforsch. 26a, 1122 (1971).

    Google Scholar 

  102. H. U. Mittmann, H.-P. Weise, A. Ding, and A. Henglein, Z. Naturforsch. 26a, 1282 (1971).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1972 Plenum Press, New York

About this chapter

Cite this chapter

Herman, Z., Wolfgang, R. (1972). Beam Studies of Ion-Molecule Reactions. In: Franklin, J.L. (eds) Ion-Molecule Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1938-2_5

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-1938-2_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-1940-5

  • Online ISBN: 978-1-4684-1938-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics