Abstract
The anionic polymerization is an addition polymerization, where the active centers, called living ends by Professor Szwarc (1,2), are carbanions. They are negatively charged species; however, since the solution is electrically neutral, positive counterions must be present in an equivalent amount. Most of the investigated polymerizations take place in media having relatively low dielectric constants; therefore, an association of the oppositly charged ions into ion pairs generally occurs (3).
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
M. Szwarc, Nature, 178, 1168 (1956)
M. Szwarc, M. Levy and R. Milkovitch, J. Am. Chem. Soc., 78, 2656 (1956)
M. Szwarc, Carbanions Living Polymers and Electron Transfer Process, Interscience, New-York, chapt. 5
P.J. Flory, Principles of polymer chemistry, Cornell University Press, Ithaca, New York, chapt. 8
S. Bywater, A.F. Johnson and D.J. Worsfold, Can. J. Chem., 42, 1255 (1964)
A. Gourdenne and P. Sigwalt, European Polymer J., 3, 481 (1967)
G. Spach, M. Levy and M. Szwarc, J. Chem. Soc., 355 (1962)
A. Gourdenne and P. Sigwalt, to be published
M. Fontanille and P. Sigwalt, European Polymer J., 5, 553 (1969)
A. Rembaum, Shiao-Ping Siao and N. Indictor, J. Polymer Sci., 56, 517 (1962)
S.N. Khanna, M. Levy and M. Szwarc, Trans. Faraday Soc., 68, 747 (1962)
A. Gourdenne, (unpublished results)
G. Champetier, M. Fontanille and P. Sigwalt, International Symposium on Macromolecular Chemistry, IUPAC, Tokyo-Kyoto N°IV, 55 (1966)
A.A. Korotkov, L.A. Shibaev, L.M. Pyrkov, V.G. Aldoehim and S.I. Frenkel, Vysokomol. Soed., 1, 443 (1959)
S. Schlick and M. Levy, J. Phys. Chem., 64, 883 (1960)
R.J. Angelo, R.M. Ikeda and M.L. Wallach, Polymer, 6, 141 (1965)
P. Sigwalt, Bull. Soc. Chim., 3, 423 (1964)
W. Bushuk and H. Benoit, Can J. Chem., 36, 1616 (1958)
A. Gourdenne and P. Sigwalt, Bull. Soc. Chim., 10, 3678 (1967)
M. Morton and L.J. Fetters, J. Polymer Sci., A2, 3311 (1964)
R.S. Stearns and L.E. Forman, J. Polymer Sci., 41, 381 (1959)
M. Morton, E.E. Bostick, R.A. Livigni and L.J. Fetters, J. Polymer Sci.A 1, 1 735 (1963)
D.J. Worsfold and S. Bywater, Can. J. Chem., 42, 2884 (1964)
A. Rembaum, F.R. Ells, R.C. Morrow and A.V. Tobolsky, J. Polymer Sci., 61, 155 (1962)
S. Boileau, G. Champetier and P. Sigwalt, Makromolekulare Chem., 68, 180 (1963)
P. Sigwalt, Main lecture, International Symposium on macromolecular Chemistry, IUPAC, Budapest (1969)
A. Gourdenne and P. Sigwalt, Bull. Soc. Chim., 10, 3685 (1967)
S. Boileau and P. Sigwalt, Compt. Rend., 261, 132 (1965)
M. Fontanille, A. Gourdenne and P. Sigwalt, to be published.
L.J. Fetters, Polymer Symposia, 26, 1 (1969)
H. Benoit, Robert A. Welch Symposium on Polymers (1966)
A. Skoulios and G. Finaz, Compt. Rend., 252, 3467 (1961)
C. Sadron, Angew. Chem., 75, 472 (1963)
A.J. Kovacs and B. Lotz, Kolloid.Z.Z. Polymere 209, 97 (1966)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1970 Plenum Press, New York
About this paper
Cite this paper
Gourdenne, A. (1970). Preparation of Block Copolymers of Some Ethylenic Monomers and Propylene Sulfide. In: Aggarwal, S.L. (eds) Block Polymers. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1842-2_20
Download citation
DOI: https://doi.org/10.1007/978-1-4684-1842-2_20
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-1844-6
Online ISBN: 978-1-4684-1842-2
eBook Packages: Springer Book Archive