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Polarographic Reduction of Aldehydes and Ketones. V. Reduction Course of Some β-Ketosulphides and Effects of Alkyl Groups on Sulphur

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Topics In Organic Polarography

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Abstract

β-Ketosulphides of the type C6H5COCH2CH(C6H5)SR are reduced at the carbonyl group. The protonized carbonyl group is reduced in two one-electron steps, the unprotonized form in one two-electron process, which differs from the reduction of corresponding β-aminoketones. The effects of alkyl groups at sulphur and nitrogen on the reduction of the carbonyl group are compared.

Part IV: This Journal 33, 3213 (1968).

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Author information

Author notes

  1. P. Zuman

    Present address: Department of Chemistry, University of Birmingham, Great Britain

Authors and Affiliations

  1. J. Heyrovský Institute of Polarography, Czechoslovak Academy of Sciences, Prague, Czech Republic

    I. Šestáková & P. Zuman

  2. Department of Organic Chemistry, Charles University, Prague, Czech Republic

    J. Pecka

Authors
  1. I. Šestáková
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  2. J. Pecka
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  3. P. Zuman
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Editor information

Editors and Affiliations

  1. Department of Chemistry, University of Birmingham, Birmingham, England

    P Zuman

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© 1970 Plenum Publishing Company Ltd.

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Šestáková, I., Pecka, J., Zuman, P. (1970). Polarographic Reduction of Aldehydes and Ketones. V. Reduction Course of Some β-Ketosulphides and Effects of Alkyl Groups on Sulphur. In: Zuman, P. (eds) Topics In Organic Polarography. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1812-5_15

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  • DOI: https://doi.org/10.1007/978-1-4684-1812-5_15

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-1814-9

  • Online ISBN: 978-1-4684-1812-5

  • eBook Packages: Springer Book Archive

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