Abstract
Free base form of primary amines is added in a reversible reaction to phenyl vinyl ketone. Kinetics verified the scheme (B)—(D). Alkyl groups R in RNH2 exert considerable steric effects on this reaction. The nucleophilic reactivity of amines in this reaction parallels the reactivity in other nucleophilic reactions of amines.
Part VIII: This Journal 31, 827 (1966).
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Šestáková, J., Horák, V., Zuman, P. (1970). Fission of Activated Carbon-Nitrogen and Carbon-Sulfur Bonds. IX. Polarographic Study of Addition of Primary Amines to Phenyl Vinyl Ketone. In: Zuman, P. (eds) Topics In Organic Polarography. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1812-5_14
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DOI: https://doi.org/10.1007/978-1-4684-1812-5_14
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