Abstract
An investigation was made of the position, width, and asymmetry of the Kα1,2 lines of titanium in various chemical compounds. The measurements were made in a focusing vacuum x-ray spectrometer using the fluorescent excitation method. The results obtained made it possible to analyze the valence of titanium in some rare-earth titanates. Use was made of the shift of the Kα1 titanium lines, as well as of their width and asymmetry for different valence states (Ti2+, Ti3+, Ti4+). A comparison was made of the x-ray spectroscopic, the magnetic, and the structure data for the compounds investigated. The advantages of the x-ray spectroscopic method or the magnetic method were demonstrated in the determination of the valence in the specific case of EuTi2O4.
“Crystals,” pp. 150–154 (see page 3).
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© 1972 Consultants Bureau, New York
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Meisel, A., Leonhardt, G. (1972). X-Ray Spectroscopic Investigation of Chemical Bonding in Some Rare-Earth Titanates. In: Sirota, N.N. (eds) Chemical Bonds in Solids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1686-2_4
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DOI: https://doi.org/10.1007/978-1-4684-1686-2_4
Publisher Name: Springer, Boston, MA
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