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Butadiene Polymers and Copolymers

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Emulsion Polymerization and Its Applications in Industry

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Abstract

1,3-Butadiene (bivinyl) is the simplest representative of a series of hydrocarbons with conjugated double bonds and is, at the same time, the cheapest of them. It is not surprising, therefore, that this hydrocarbon is used worldwide as a principal monomer in the industrial production of emulsion rubberlike polymers which are capable of vulcanization via formation of sulfur bridges between the macromolecules.

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References

  1. F. A. Bovey, I. M. Kolthoff, A. I. Medalia, and E. J. Meehan, Emulsion Polymerization, Wiley-Interscience, New York-London (1955).

    Google Scholar 

  2. G. S. Whitby,Synthetic Rubber [Russian translation], Goskhimizdat, Leningrad (1957).

    Google Scholar 

  3. F. C. Foster and J. L. Binder, J. Am. Chem. Soc., 75: 2910–2913 (1953).

    Article  Google Scholar 

  4. K. E. Beu,Polym. 3: 801–803 (1948).

    Google Scholar 

  5. V. A. B aland in a,Izd. Akad. Nauk SSSR, 2: 397–407, 423–433 (1936).

    Google Scholar 

  6. K. V. Berezan, A. V. Dobromyslova, and B. A. Dogadkin, Izv. Akad. Nauk SSSR, 2: 409–422 (1936).

    Google Scholar 

  7. A. I. Yurzhenko and M. F. Kolechkova, Dokl. Akad. Nauk SSSR, 47:354–357 (1945); A. I. Yurzhenko and S. M. Mints, Dokl. Akad. Nauk SSSR, 55: 339–342 (1947).

    Google Scholar 

  8. Yu. M. Yakovlev, A. V. Lebedev, and D. N. Vasil’eva, in: New Synthetic Latexes and Theoretical Foundations of Latex Technology [in Russian], TsNIITEneftekhim, Moscow (1973), pp. 91–92.

    Google Scholar 

  9. M. Morton, P. Salatiello, and H. Landfield, Polym. Sci., 8: 279–287 (1952).

    Article  Google Scholar 

  10. P. J. Flory, Chem. Rev., 35: 51–75 (1944).

    Article  Google Scholar 

  11. G. B. Handlock, J. T. Cox, and O. W. Burke, Chem. Eng. News, 27: 27–28 (1949).

    Article  Google Scholar 

  12. I. Ya. Poddubnyi, A. V. Lebedev, and V. G. Nazarov, in: Research in the Field of Polymerization in the Presence of Free Radicals [in Russian], OBTIP Glavkauchuka, Moscow (1951), pp. 316–327; I. Ya. Poddubnyi and E. G. Erenburg, ibid, pp. 328–355.

    Google Scholar 

  13. A. N. Planovskii, Khim. Promst., 5: 22–23; 6: 5–9 (1944).

    Google Scholar 

  14. S. A. Selivancvskii and N. A. Fermor, in: Synthesis of Latexes and Their Application [in Russian], Goskhimizdat, Leningrad (1961), p. 103.

    Google Scholar 

  15. A. E. Kalaus, M. G. Lapuk, and T. D. Vikuylova, Byull. Obmenu Opytom Promst. Sint. Kauch. Sint. Rezina, 3:33–42 (1956),Khim. Promst., 3: 5–10 (1958).

    Google Scholar 

  16. E. J. Meehan, J. Am. Chem. Soc., 71: 628–633 (1949).

    Google Scholar 

  17. S. A. Selivanovskii and N. A. Fermor, in: Synthesis and Uses of Latexes [in Russian], Goskhimizdat, Leningrad (1961), pp. 102–107; D. A. Miilen, Kauch. Rezina, 12:5–10 (1963).

    Google Scholar 

  18. E. A. Wilson, J. R. Miller, and E. H. Rowe, Phys. Chem., 53: 357 - 365 (1949).

    Article  Google Scholar 

  19. K. G. Denbigh, Trans. Faraday Soc., 43: 648–660 (1947).

    Google Scholar 

  20. F. T. Wall, C. J. Delbecq, and F. C. Florin, J. Polym. Sci., 9: 177–192 (1952).

    Article  Google Scholar 

  21. T. Sato and J. Taniyama, Kogyo Kagaku Zasshi, 68. 61–69, 106–110 (1965).

    Article  Google Scholar 

  22. S. N. Sautin, Dissertation, Lensovet Leningrad Technical Institute (1969).

    Google Scholar 

  23. A. V. Lebedev, USSR Patent 166,142 (1961); Byull. Izobr., No. 21 (1964).

    Google Scholar 

  24. D. C. Blackley, High Polymer Latices, Garden City Press, London-New York (1966).

    Google Scholar 

  25. E. Madge, Latex Foam Rubber, Wiley-Interscience, New York (1962), 270 pp.Kauch. Rezina, 6: 23–31 (1970).

    Google Scholar 

  26. Copolymer Rubber and Chemical Corp., U.S. Patent 3,318, 831 (1963).

    Google Scholar 

  27. N. A. Fermor et al., Production of Synthetic Latexes [in Russian], TsNIITEneftekhim, Moscow (1971).

    Google Scholar 

  28. O. B. Litvin, Fundamentals of the Technology of Rubber Synthesis [in Russian], 3rd edn., Khimiya, Moscow (1972).

    Google Scholar 

  29. L. Talalay, Fourth Int. Rubber Technol. Conf., London (\962)\Rubber Chem. Technol., 36:581–596; B. F. Goodrich Co., British Patent 758,622 (1954); L. Talalay, Italian Patent 528, 151 (1955).

    Google Scholar 

  30. B. D. Jones, Fourth Int. Rubber Technol. Conf., London (1962).

    Google Scholar 

  31. L. H. Howland et al., Rubber Plast. Age, 42:868–874 (1961); L. H. Howland and R. W. Brown, Rubber Chem. Technol., 34:1501–1520 (1961); U.S. Rubber Co., Belgian Patent 592, 204 (1960).

    Google Scholar 

  32. A. R. Gudheim, Rubber Age, 87: 466–469 (1960).

    Google Scholar 

  33. The Elastomer Manual, Synthetic Rubber by Tapes-Properties-Producers, International Institute of Synthetic Rubber Products, New York-Brussels-Tokyo ( 1965, 1970 ).

    Google Scholar 

  34. Texas-U.S. Chemical Co., U.S. Patent 3, 322, 746 (1964).

    Google Scholar 

  35. C. A. McCall, W. Nudenberg, and H. Goldstein, Rubber World, 148:31–32 (1963); H. De Decker, C. McCall, and W. Bahery, Rubber Plast. Age, 46: 286–292 (1965).

    Google Scholar 

  36. W. I. Fraser, Chem. Ind., 8 (13): 1399–1405 (1966).

    Google Scholar 

  37. A. B. Zaitseva, in: Problems in the Synthesis and Processing of Latexes [in Russian], TsNIITEneftekhim, Moscow (1968), p. 57; E. N. Eremina, in: Production and Processing of Plastics, Resins, and Glass Fibers [in Russian], No. 9, NIIPM, Moscow (1969), p. 61.

    Google Scholar 

  38. R. J. Noble, Latexes in Technology [Russian translation], Goskhimizdat, Leningrad (1962).

    Google Scholar 

  39. P. I. Rakhlin, Applications of Synthetic Latexes [in Russian], TsNIITEneftekhim, Moscow (1971).

    Google Scholar 

  40. J. Vialle, J. Guillot, and A. Guyot, J. Macromol. Sci., Chem., Part A, 5 (6): 1031–1042 (1971).

    Google Scholar 

  41. M. Fineman and S. D. Ross, J. Polym. Sci., 5: 259–262 (1950).

    Article  Google Scholar 

  42. H. P. Brown, U.S. Patent 2,669,550 (1950);H. P. Brown and N. G. Duke,Rubber World, 130:784-788 (1954); H. P. Brown and C. Gibbs,Ind. Eng. Chem., 47:1006–1012 (1955);Rubber Chem. Technol., 30 (5): 1347–1386 (1957).

    Google Scholar 

  43. B. A. Dolgoplosk, Kauch. Rezina, 3:11–14 (1957); 6: 1–6 (1957).

    Google Scholar 

  44. A. I. Ezrielev, USSR Patent 169,243 (1960);Byull. Izobr., No. 6, p. 60 (1965).

    Google Scholar 

  45. W. Cooper and T. B. Bird, Ind. Eng. Chem., 50: 771–776 (1958).

    Article  Google Scholar 

  46. A. I. Ezrielev, USSR Patent 248,216 (1964); OtkrytiyaIzobr. Promst. Obraz., No. 23 (1969).

    Google Scholar 

  47. A. I. Ezrielev and I. G. Khazanovich, in: New Synthetic Latexes and Theoretical Foundations of Latex Technology [in Russian], TsNIITEneftkhim, Moscow (1973), p. 64.

    Google Scholar 

  48. I. G. Khazanovich, N. A. Fermor, and A. B. Peizner, Kauch. Rezina, 5: 17–20 (1963).

    Google Scholar 

  49. T. A. Larkina, Kozh. Obuvn. Promst., 2: 17–21 (1970).

    Google Scholar 

  50. L. M. Novichkova, Dokl. Akad. Nauk SSSR, 210: 402–404 (1973).

    Google Scholar 

  51. L. M. Kogan, Dissertation, Lensovet Leningrad Technical Institute (1970).

    Google Scholar 

  52. I. A. Livshits, S. I. Il’ina, and V. N. Reikh, in: Research in the Field of Polymerization in the Presence of Free Radicals [in Russian], OBTIP Glavkauchuka, Moscow (1951), p. 356.

    Google Scholar 

  53. B. A. Dolgoplosk, in: Investigation in the Field of Polymerization [in Russian], Gos- khimizdat, Leningrad (1948).

    Google Scholar 

  54. B. A. Dolgoplosk and Z. E. Kogan, in: Research in the Field of Polymerization in the Presence of Free Radicals [in Russian], OBTIP Glavkauchuka, Moscow (1951), p. 416.

    Google Scholar 

  55. C. Walling and J. A. Davidson, J. Amer. Chem. Soc., 73: 5736–5738 (1951).

    Article  Google Scholar 

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Authors
  1. V. I. Eliseeva
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  2. S. S. Ivanchev
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  3. S. I. Kuchanov
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  4. A. V. Lebedev
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© 1981 Consultants Bureau, New York

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Eliseeva, V.I., Ivanchev, S.S., Kuchanov, S.I., Lebedev, A.V. (1981). Butadiene Polymers and Copolymers. In: Emulsion Polymerization and Its Applications in Industry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1641-1_4

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  • DOI: https://doi.org/10.1007/978-1-4684-1641-1_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-1643-5

  • Online ISBN: 978-1-4684-1641-1

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