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Characterization of Sulfide Mineral Surfaces

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Electrochemistry in Transition
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Abstract

The metal sulfides constitute the most important group of ore minerals since they are the source of the world’s supplies of nonferrous metals. Sulfide minerals are, in general, electronic conductors and can sustain coupled anodic and cathodic reactions at the interface with an electrolyte. The significance of conductivity in determining the properties of sulfides has been recognized for some considerable time. Fox, commenting in 1830 on the properties of metalliferous veins in mines in Cornwall, England, that contained iron, copper, and lead sulfides, stated(1) “many of the phenomena … bear striking analogies to common galvanic combinations and the discovery of electricity in veins seems to complete the resemblance.”

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References

  1. R. W. Fox, Roy. Soc. (London) Phil. Trans. 1830, 399.

    Google Scholar 

  2. R. Tolun and J. A. Kitchener, Bull. Inst. Min. Metall. 73, 313–0000 (1964).

    Google Scholar 

  3. J. R. Gardner and R. Woods, Aust. J. Chem. 26, 1635–0000 (1973).

    Article  CAS  Google Scholar 

  4. S. M. Ahmed, Int. J. Miner. Process. 5, 175–0000 (1978).

    Article  CAS  Google Scholar 

  5. K. C. Pillai and J. O’M. Bockris, J. Electrochem. Soc. 131, 568–0000 (1984).

    Article  CAS  Google Scholar 

  6. P. E. Richardson and E. E. Maust, Jr., in: Flotation—A. M. Gaudin Volume (M. C. Fuerstenau, ed.), Vol. 1, pp. 364–392, SME/AIME, New York (1976).

    Google Scholar 

  7. R. L. Paul, M. J. Nicol, J. W. Diggle, and A. P. Saunders, Electrochim. Acta 23, 625–0000 (1978).

    Article  CAS  Google Scholar 

  8. J. R. Gardner and R. Woods, J. Electroanal. Chem. 100, 447–0000 (1979).

    Article  CAS  Google Scholar 

  9. I. C. Hamilton and R. Woods, in: Proceedings of the International Symposium on Electrochemistry in Mineral and Metal Processing (P. E. Richardson, S. Srinivasan, and R. Woods, eds.), pp. 259–285, The Electrochemical Society, Pennington, New Jersey (1984).

    Google Scholar 

  10. G. W. Poling and M. J. V. Beattie, in: Principles of Mineral Flotation (M. H. Jones and J. T. Woodcock, eds.), pp. 137–146, AusIMM, Melbourne (1984).

    Google Scholar 

  11. M. Lamache, D. Bauer, and J. Pegouret, Electrochim. Acta 26, 1845–0000 (1981).

    Article  CAS  Google Scholar 

  12. W. J. Trahar, in: Principles of Flotation (M. H. Jones and J. T. Woodcock, eds.), pp. 117–135, AusIMM, Melbourne (1984).

    Google Scholar 

  13. R. Woods, in: Principles of Flotation (M. H. Jones and J. T. Woodcock, eds.), pp. 91–115, AusIMM, Melbourne (1984).

    Google Scholar 

  14. R. Woods, J. Phys. Chem. 75, 354–0000 (1971).

    Article  CAS  Google Scholar 

  15. J. R. Gardner and R. Woods, Aust. J. Chem. 30, 981–0000 (1977).

    Article  CAS  Google Scholar 

  16. P. E. Richardson and C. S. O’Dell, J. Electrochem. Soc. 132, 1350–0000 (1985).

    Article  CAS  Google Scholar 

  17. M. D. Pritzker and R. H. Yoon, in: Proceedings of the International Symposium on Electrochemistry in Mineral and Metal Processing (P. E. Richardson, S. Srinivasan, and R. Woods, eds.), pp. 26–53, The Electrochemical Society, Pennington, New Jersey (1984).

    Google Scholar 

  18. A. Kowal and A. Pomianowski, J. Electroanal. Chem. 46, 411–0000 (1973).

    Article  CAS  Google Scholar 

  19. C. S. O’Dell, R. K. Dooley, G. W. Walker, and P. E. Richardson, in: Proceedings of the International Symposium on Electrochemistry in Mineral and Metal Processing (P. E. Richardson, S. Srinivasan, and R. Woods, eds.), pp. 81–95, The Electrochemical Society, Pennington, New Jersey (1984).

    Google Scholar 

  20. C. Basilio, M. D. Pritzker, and R. H. Yoon, SME/AIME Annual Meeting, New York, 1985, Preprint No. 85–86.

    Google Scholar 

  21. S. Chander and D. W. Fuerstenau, J. Electroanal. Chem. 56, 217–0000 (1974).

    Article  CAS  Google Scholar 

  22. N. D. Janetski, S. I. Woodburn, and R. Woods, Int. J. Miner. Process. 4, 227–0000 (1974).

    Article  Google Scholar 

  23. S. Castro and J. Larrondo, J. Electroanal. Chem. 118, 317–0000 (1981).

    CAS  Google Scholar 

  24. P. J. Guy and W. J. Trahar, Int. J. Miner. Process. 12, 15–0000 (1985).

    Article  Google Scholar 

  25. P. J. Guy and W. J. Trahar, in: Flotation of Sulphide Minerals (K. S. E. Forssberg, ed.), pp. 91–110, Elsevier, Amsterdam (1985).

    Google Scholar 

  26. J. Leppinen, On the Interaction of Thiol Collector Ions and Lead Sulfide Surface, University of Turku (1986).

    Google Scholar 

  27. G. W. Heyes and W. J. Trahar, Int. J. Miner. Process. 4, 317–0000 (1977).

    Article  CAS  Google Scholar 

  28. P. E. Richardson and G. W. Walker, in: XVth International Mineral Processing Congress, Cannes, France, Vol. II, pp. 198–210 GEDIM, St. Etienne, France (1985).

    Google Scholar 

  29. D. R. Nagaraj, S. S. Wang, P. V. Avotins, and E. Dowling, Trans. Inst. Min. Metall. 95, C17 (1986).

    CAS  Google Scholar 

  30. R. Woods, D. C. Constable, and I. C. Hamilton, in: Proceedings of the International Symposium on Electrochemistry in Mineral and Metal Processing II (P. E. Richardson and R. Woods, eds.), pp. 113–130, The Electrochemical Society, Pennington, New Jersey (1988).

    Google Scholar 

  31. G. W. Heyes and W. J. Trahar, in: Proceedings of the International Symposium on Electrochemistry in Mineral and Metal Processing (P. E. Richardson, S. Srinivasan, and R. Woods, eds.), 219–232, The Electrochemical Society, Pennington, New Jersey (1984).

    Google Scholar 

  32. S. Fletcher and M. D. Home, in: Electrochemistry, Current and Potential Applications (T. Tran and M. Skyllas-Kazacos, eds.), pp. 152–153, Electrochemistry Division, Royal Australian Chemical Institute, Kensington, New South Wales (1988).

    Google Scholar 

  33. E. Yeager, Surf Sci. 101, 1–0000 (1980).

    Article  CAS  Google Scholar 

  34. D. Brion, Appl. Surf. Sci. 5, 133–0000 (1980).

    Article  CAS  Google Scholar 

  35. A. N. Buckley and R. Woods, in: Proceedings of the International Symposium on Electrochemistry in Mineral and Metal Processing (P. E. Richardson, S. Srinivasan, and R. Woods, eds.), pp. 286–302, The Electrochemical Society, Pennington, New Jersey (1984).

    Google Scholar 

  36. A. N. Buckley and R. Woods, Appl. Surf. Sci. 17, 401–0000 (1984).

    Article  CAS  Google Scholar 

  37. A. N. Buckley and R. Woods, Aust. J. Chem. 36, 1793–0000 (1983).

    Article  CAS  Google Scholar 

  38. A. N. Buckley, I. C. Hamilton, and R. Woods, J. Appl. Electrochem. 14, 63–0000 (1984).

    Article  CAS  Google Scholar 

  39. A. N. Buckley and R. Woods, Aust. J. Chem. 37, 2403–0000 (1984).

    Article  CAS  Google Scholar 

  40. A. N. Buckley and R. Woods, Appl. Surf. Sci. 22/23, 280–0000 (1985).

    Article  Google Scholar 

  41. A. N. Buckley and R. Woods, Appl. Surf. Sci. 20, 472–0000 (1985).

    Article  CAS  Google Scholar 

  42. A. N. Buckley and R. Woods, Appl. Surf Sci. 27, 437–0000 (1987).

    Article  CAS  Google Scholar 

  43. A. N. Buckley, R. Woods, and H. J. Wouterlood, in: Proceedings of the International Symposium on Electrochemistry in Mineral and Metal Processing II (P. E. Richardson and R. Woods, eds.), pp. 211–233, The Electrochemical Society, Pennington, New Jersey (1988).

    Google Scholar 

  44. A. N. Buckley, Aust. J. Chem. 40, 231–0000 (1987).

    Article  CAS  Google Scholar 

  45. D. J. Vaughan and J. R. Craig, Mineral Chemistry of Metal Sulfides, Cambridge University Press, Cambridge (1978).

    Google Scholar 

  46. A. N. Buckley, R. Woods, and H. J. Wouterlood, Aust. J. Chem. 41, 1003–0000 (1988).

    Article  CAS  Google Scholar 

  47. R. K. Clifford, K. L. Purdy, and J. D. Miller, AIChE Symp. Ser. 71, 138–0000 (1975).

    CAS  Google Scholar 

  48. D. L. Perry, L. Tsao, and J. A. Taylor, in: Proceedings of the International Symposium on Electrochemistry in Mineral and Metal Processing (P. E. Richardson, S. Srinivasan, and R. Woods, eds.), pp. 169–184, The Electrochemical Society, Pennington, New Jersey (1984).

    Google Scholar 

  49. V. I. Nefedov, Ya. V. Salyn, P. M. Solozhenkin, and G. Yu. Pulatov, Surf. Interface Anal. 2, 170–0000 (1984).

    Article  Google Scholar 

  50. K. C. Pillai, V. Y. Young, and J. O’M. Bockris, Appl. Surf. Sci. 16, 322–0000 (1983).

    Article  CAS  Google Scholar 

  51. J. Mielczarski and E. Suoninen, Surf. Interface Anal. 6, 34–0000 (1984).

    Article  CAS  Google Scholar 

  52. J. Mielczarski and E. Minni, Surf. Interface Sci. 6, 221–0000 (1984).

    Article  CAS  Google Scholar 

  53. K. C. Pillai, V. Y. Young, and J. O’M. Bockris, J. Colloid Interface Sci. 103, 145–0000 (1985).

    Article  CAS  Google Scholar 

  54. J. Mielczarski, Int. J. Miner. Process. 16, 179–0000 (1986).

    Article  CAS  Google Scholar 

  55. J. Mielczarski, J. Colloid Interface Sci. 120, 201–0000 (1987).

    Article  CAS  Google Scholar 

  56. E. W. Giesekke, Int. J. Miner. Process. 11, 19–0000 (1983).

    Article  CAS  Google Scholar 

  57. G. W. Poling, in: Flotation—A. M. Gaudin Memorial Volume (M. C. Fuerstenau, ed.), Vol. 1, pp. 334–363, SME/AIME, New York (1976).

    Google Scholar 

  58. J. Leja, L. H. Little, and G. W. Poling, Trans. Inst. Min. Metall. 72, 414–0000 (1963).

    Google Scholar 

  59. J. Leppinen and J. Mielczarski, Int. J. Miner. Process. 18, 3–0000 (1986).

    Article  CAS  Google Scholar 

  60. S. C. Termes and P. E. Richardson, Int. J. Miner. Process. 18, 167–0000 (1986).

    Article  CAS  Google Scholar 

  61. J. Mielczarski, Colloids Surf. 17, 251–0000 (1986).

    Article  CAS  Google Scholar 

  62. J. O. Leppinen, C. I. Basilio, and R. H. Yoon, Colloids Surf. 32, 113–0000 (1988).

    Article  CAS  Google Scholar 

  63. J. K. Foley, C. Korzeniewski, J. L. Daschbach, and B. S. Pons, in: Electroanalytical Chemistry, Vol. 14 (A. J. Bard, ed.), pp. 309–340, Marcel Dekker, New York (1986).

    Google Scholar 

  64. J. O. Leppinen, C. I. Basilio, and R. H. Yoon, in: Proceedings of the International Symposium on Electrochemistry in Mineral and Metal Processing II (P. E. Richardson and R. Woods, eds.), pp. 49–65, The Electrochemical Society, Pennington, New Jersey (1988).

    Google Scholar 

  65. L. K. Shannon and W. J. Trahar, in: Advances in Mineral Processing (P. Somasundaran, ed.), pp. 408–425, SEM/AIME, Littleton, Colorado (1986).

    Google Scholar 

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© 1992 Plenum Press, New York

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Woods, R. (1992). Characterization of Sulfide Mineral Surfaces. In: Murphy, O.J., Srinivasan, S., Conway, B.E. (eds) Electrochemistry in Transition. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9576-2_35

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  • DOI: https://doi.org/10.1007/978-1-4615-9576-2_35

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