Abstract
The discovery of Ney, Nummy, and Barnes,1 that 2-pyrrolidone can be polymerized to nylon 4 by basic catalysts, stimulated much subsequent work on the preparation, physico-chemical characterization, and utilization of the polymer. The great interest in this polymer is due to the fact that nylon 4 textile fibers combine the good strength properties of nylon 6 or 66 with the hydrophilicity of cotton.2
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References
W. O. Ney, Jr., W. R. Nummy, and C. E. Barnes, U.S. Patent 2,638, 463 (1953).
E. M. Peters and J. A. Gervasi, Chemtech., p 16, January 1972.
L. Szego, La Chimica E L’Industria, 55, 280 (1973).
C. E. Barnes, U.S. Patent 3,721, 652 (1973).
R. Bacskai, U.S. Patents 4,098,774 (1978), 4,100,146 (1978), 4,101,531 (1978), and 4,218, 558 (1980).
J. P. tollman, U.S. Patent 4,073,778 (1978); R. Bacskai, U.S. Patent 4,169, 936 (1979).
R. Bacskai and B. A. Fries, J. Polym. Sci. Chem. Ed., 20, 2341 (1982).
J. B. Kinsinger, In Encyclopedia of Polymer Science and Technology, Vol 14; H. F. Mark, N. G. Gaylord, and N. M. Bikales, Eds., Interscience, New York, 1971, p 727.
Z. Tuzar, J. Kleteckova, and J. Kralicek, Coll. Czech. Chem. Comm., 39, 2206 (1974).
H. Sekiguchi, P. R. Tsourkas, and B. Coutin, J. Polymer Sei., Symposium No. 42, 51 (1973).
N. Sakata, Japanese Patent 71–26195 (1972).
H. K. Hall, Jr., J. Am. Chem. Soc., 80, 6404 (1958).
L. J. Mathias, J. Macromol. Sci. Chem., A15 (5), 853 (1981).
H. Sekiguchi, P. Tsourkas, and B. Coutin, Makromol. Chem., 178, 2135 (1977).
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© 1984 Plenum Press, New York
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Bacskai, R. (1984). Synthesis of Ultrahigh Molecular Weight Nylon 4 with Onium Salt and Crown Ether-Containing Catalysts. In: Mathias, L.J., Carraher, C.E. (eds) Crown Ethers and Phase Transfer Catalysis in Polymer Science. Polymer Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9349-2_14
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DOI: https://doi.org/10.1007/978-1-4615-9349-2_14
Publisher Name: Springer, Boston, MA
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