Skip to main content

Vibrational Spectroscopy of Molecules Adsorbed on Vapor-Deposited Metals

  • Chapter
Surface Enhanced Raman Scattering

Abstract

In the present chapter we will present the SERS spectra of a number of molecules adsorbed on silver and lithium metals vapor-deposited in vacuum onto a cooled substrate. The results will be used to illustrate a number of points.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. D.P. DiLella, A. Gohin, R.H. Lipson, P. McBreen and M. Moskovits, Enhanced Raman spectroscopy of C.O adsorbed on vapor-deposited silver, J Chem. Phys. 73:4282 (1980).

    Article  ADS  Google Scholar 

  2. M. Moskovits and D. P. DiLella, Enhanced Raman spectra of ethylene and propylene adsorbed on silver, Chem. Phys. Lett. 73:500 (1980).

    Article  ADS  Google Scholar 

  3. D. P. DiLella and M. Moskovits, The surface-enhanced Raman spectra of some butènes adsorbed on silver, J. Phys. Chem. in press (1981).

    Google Scholar 

  4. H. Abe, K. Manzel, W. Schulze, M. Moskovits and D. P. DiLella, Surface-enhanced Raman spectroscopy of CO adsorbed on colloidal silver particles, J. Chem. Phys. 74:792 (1981).

    Article  ADS  Google Scholar 

  5. J. Gersten and A. Nitzan, Electromagnetic theory of enhanced Raman scattering by molecules adsorbed on rough surfaces, J. Chem. Phys. 73:3023 (1980).

    Article  ADS  Google Scholar 

  6. M. Kerker, D.-S. Wang and H. Chew, Surface enhanced Raman scattering (SERS) by molecules adsorbed at spherical particles, Appl. Opt. 19:3373, 4159 (1980).

    Article  ADS  Google Scholar 

  7. S. L. McCall, P. M. Platzman and P. Wolff, Surface enhanced Raman scattering, Phys. Lett. 77A:381 (1980).

    ADS  Google Scholar 

  8. C.A. Murray, D. L. Aliara and M. Rhinewine, Surface enhanced Raman scattering in multi-layer film structures, in: “Proceedings of the 7th International Conference on Raman Spectroscopy,” W. F. Murphy, ed., North-Holland, Amsterdam (1980), p. 406.

    Google Scholar 

  9. D. A. Zwemer, C. V. Shank and J. E. Rowe, Surface-enhanced Raman scattering as a function of molecule-surface separation, Chem. Phys. Lett. 73:201 (1980).

    Article  ADS  Google Scholar 

  10. See, for example, Fig. 3 of reference 5.

    Google Scholar 

  11. D. P. DiLella and M. Moskovits, to be published.

    Google Scholar 

  12. K. G. Caulton, R. L. DeKock and R. F. Fenske, A comparison of carbon monoxide and nitrogen as ligands in transition metal complexes, J. Amer. Chem. Soc. 92:515 (1970).

    Article  Google Scholar 

  13. M. Moskovits and D. P. DiLella, Surface-enhanced Raman spectroscopy of benzene and benzene-d6 adsorbed on silver, J. Chem. Phys. 73:6068 (1980).

    Article  ADS  Google Scholar 

  14. E. B. Wilson Jr., J. C. Decius and P. C. Cross, “Molecular Vibrations,” McGraw-Hill, New York (1955).

    Google Scholar 

  15. A. D. Buckingham, Permanent and induced molecular moments and long-range intermolecular forces, in: “Advances in Chemical Physics,” 12:107 (1967), J. O. Hirschfelder, ed.

    Chapter  Google Scholar 

  16. J. K. Sass, H. Neff, M. Moskovits and S. Holloway, Electric field gradient effects on the spectroscopy of adsorbed molecules, J. Phys. Chem. 85:621 (1981).

    Article  Google Scholar 

  17. A. D. Buckingham and L. D. Barron, Rayleigh and Raman scattering from optically active molecules, Mol. Phys. 20:1111 (1971).

    Article  ADS  Google Scholar 

  18. P. J. Feibelman, Microscopic calculations of electromagnetic fields in refraction at a jellium-vacuum interface, Phys. Rev. B 12:1319 (1975).

    Article  ADS  Google Scholar 

  19. M. Moskovits, Surface roughness and the enhanced intensity of Raman scattering by molecules adsorbed on metals, J. Chem. Phys. 69:4159 (1978)

    Article  ADS  Google Scholar 

  20. M. Moskovits, Enhanced Raman scattering by molecules adsorbed on electrodes—a theoretical model, Solid State Commun. 32:59 (1979).

    Article  ADS  Google Scholar 

  21. J. R. Anderson, B. G. Baker and J. V. Sanders, Structure and properties of evaporated metal films, J. Catal. 1:443 (1962).

    Article  Google Scholar 

  22. S. J. Cyvin, J. E. Rauch and J. C. Decius, Theory of hyper-Raman effects (nonlinear inelastic light scattering): Selection rules and depolarization ratios for the second-order polarizability, J. Chem. Phys. 43:4083 (1965).

    Article  ADS  Google Scholar 

  23. P. N. Sanda, J. E. Demuth, J. C. Tsang and J. M. Warlaumont, this volume.

    Google Scholar 

  24. G. Varsányi, “Vibrational Spectra of Benzene Derivatives,” Academic, New York (1969).

    Google Scholar 

  25. R. Dornhaus, M. B. Long, R. E. Benner and R. K. Chang, Time development of SERS from pyridine, pyrimidine, pyrazine and cyanide adsorbed on Ag electrodes during an oxidation-reduction cycle, Surf. Sci. 93:240 (1980).

    Article  ADS  Google Scholar 

  26. M. R. Mahoney, M. W. Howard and R. P. Cooney, Carbon dioxide conversion to hydrocarbons at silver electrode surfaces. Raman spectroscopic evidence for surface carbon intermediates, Chem. Phys. Lett. 71:59 (1980).

    Article  ADS  Google Scholar 

  27. R. G. Meisenheimer and J. N. Wilson, Interaction of oxygen and ethylene dichloride with silver surfaces, J. Catal. 1:151 (1962).

    Article  Google Scholar 

  28. B. Pettinger and H. Wetzel, this volume.

    Google Scholar 

  29. R. Naaman, S. J. Buelow, O. Cheshovsky and D. R. Herschbach, Surface-enhanced Raman scattering from molecules adsorbed on mercury, J. Phys. Chem. 84:2692 (1980).

    Article  Google Scholar 

  30. H. Yamada and Y. Yamamoto, Surface enhanced Raman spectra of pyridine adsorbed on silver, gold, nickel and platinum metals, Chem. Phys. Lett. 77:520 (1981).

    Article  ADS  Google Scholar 

  31. W. Schulze and M. Moskovits, unpublished results.

    Google Scholar 

  32. H. Metiu and W. E. Palke, The infrared spectroscopy of chemisorbed molecules: A dynamical theory of the line shape, J. Chem. Phys. 69:2574 (1978).

    Article  ADS  Google Scholar 

  33. P. H. McBreen, Ph.D. Thesis, “U.V. Visible Spectroscopy of Molecules Adsorbed on Metals,” University Microfilms, Ann Arbor, Michigan (1981); D. P. DiLella, R. H. Lipson, P. McBreen and M. Moskovits, Metal molecules, metal clusters and metal bumps, J. Vac. Sci. Tech, in press (1981).

    Google Scholar 

  34. F. Wooten, “Optical Properties of Solids,” Academic, New York (1976).

    Google Scholar 

  35. P. B. Johnson and R. W. Christy, Optical constants of noble metals, Phys. Rev. B 6:4370 (1972).

    Article  ADS  Google Scholar 

  36. A. Otto, I. Pockrand, J. Billmann and C. Pettenkofer, this volume.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1982 Plenum Press, New York

About this chapter

Cite this chapter

Moskovits, M., DiLella, D.P. (1982). Vibrational Spectroscopy of Molecules Adsorbed on Vapor-Deposited Metals. In: Chang, R.K., Furtak, T.E. (eds) Surface Enhanced Raman Scattering. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9257-0_13

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-9257-0_13

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-9259-4

  • Online ISBN: 978-1-4615-9257-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics