Skip to main content

Theory of Ion-Selective Electrodes

  • Chapter

Abstract

Ion-selective electrodes are Potentiometrie sensors containing an electrochemical membrane as an essential component, Besides the glass electrode which was discovered by Cremer and by Haber and Klemensiewicz at the beginning of the century and introduced to practical potentiometry particularly by Maclnnes and Dole, the ion-selective electrodes in a narrow sense of the word date from the sixties with the basic contributions of Pungor, Frant and Ross, Simon and their co-workers (for the review of the history of ion-selective electrodes, see Koryta 1975).

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Beutner, R., 1913, Neue Erscheinungen der Elektrizitätserregung, welche einige bioelektrische Phänomene erklären, Z. Elektrochem., 19:319.

    CAS  Google Scholar 

  • Boles, J.H., and Buck, R.P., 1973, Anion responses and potential functions for neutral carrier membrane electrodes, Anal. Chem., 45:2057.

    Article  CAS  Google Scholar 

  • Bonhoeffer, K.-F., Kahlweit, M., and Strehlow, H., 1953, Ueber elektrochemische Analogien zwischen nichtwässrigen Elektrolytlösungen und Ionenaustauschern, Z. Elektroche., 57:614.

    CAS  Google Scholar 

  • Cammann, K., and Rechnitz, G.A., 1976, Exchange kinetics at ion-selective membrane electrodes, Anal. Chem., 48:856.

    Article  CAS  Google Scholar 

  • Ciani, S., Eisenman, G., and Szabo, G., 1969, A theory for the effects of neutral carriers such as the macrotetralide actin antibiotics on the electric properties of bilayer membranes, J. Membrane Bio., 1:1.

    Article  CAS  Google Scholar 

  • Gavach, C., D’Epenoux, B., and Henry, F., 1975, Transfer of tetra-N-alkylammonium ions from water to nitrobenzene — chronopotentiometric determination of kinetic parameters, J. Electroanal. Chem., 64:107.

    Article  CAS  Google Scholar 

  • Gavach, C., and Henry, F., 1974, Chronopotentiometric investigation of the diffusion overvoltage at the interface between two non-miscible solutions, J. Electroanal. Chem., 54:361.

    Article  CAS  Google Scholar 

  • Gavach, C., Seta, P., and D’Epenoux, B., 1977, The double layer and ion adsorption at the interface between two non-miscible solutions. Part I. Interfacial tension measurements for the water-nitrobenzene tetraalky1ammonium bromide systems, J. Electroanal. Chem., 83:225.

    Article  CAS  Google Scholar 

  • Karpfen, F.M., and Randles, J.A.B., 1953, Ionic equilibria and phase-boundary potentials in oil-water systems, Trans. Farady Soc., 49:823.

    Article  CAS  Google Scholar 

  • Koryta, J., 1975, Ion-selective Electrodes, Cambridge University Press, Cambridge.

    Google Scholar 

  • Koryta, J., 1980, Ed.: “Medical and Biological Applications of Electrochemical Devices”, J. Wiley and Sons, Chichester.

    Google Scholar 

  • Koryta, J., 1979, Electrochemical polarization phenomena at the interface of two immiscible electrolyte solutions, Electrochim. Act., 24:293.

    Article  CAS  Google Scholar 

  • Koryta, J., Vanýsek, P., and Březina, M., 1977a, Electrolysis with electrolyte dropping electrode II. Basic properties of the system, J. Electroanal. Chem., 75:211.

    Article  CAS  Google Scholar 

  • Koryta, J., Vanýsek, P., Khalil, M.W., Mareček, V., and Samec, Z., 1977b, A mechanistic tool for liquid-membrane ion-selective electrode investigation: Polarization of the liquid-liquid interface, i.: Ion Selective Electrodes, Proceedings of the Conference of Ion-Selective Electrodes, Budapest, Pungor, E.,ed., Akademiai Kiado, Budapest.

    Google Scholar 

  • Koryta, J., Březina, M., Hofmanová, A., Homolka, D., Hung, L.Q., Khalil, W., Mareček, V., Samec, Z., Sen, S.K., Vanýsek, P., and Weber, J., 1980, A new model of membrane transport: electrolysis at the interface of two immiscible electrolyte solutions, Bioelectrochem. Bioenerge., 7:61.

    Article  CAS  Google Scholar 

  • Lux, H.D., and Neher, E., 1973, The equilibration time course of [K+]o in cat cortex, Exp. Brain Res., 17:190.

    CAS  Google Scholar 

  • Meier, P.C., Ammann, D., Morf, W.E., and Simon, W., 1980, Liquid-membrane ion-selective electrodes and their biomedical applications, i.: Medical and Biological Applications of Electrochemical Devices, Koryta, J., ed., Wiley and Sons, Chichester,p.13

    Google Scholar 

  • Morf, W.E., Kahr, G., and Simon, W., 1974, Reduction of the anion interference in neutral carrier liquid-membrane electrodes responsive to cations. Anal.Lett., 7:9.

    Article  CAS  Google Scholar 

  • Nernst, W., and Riesenfeld, E.H., 1902, Ueber elektrolytische Erscheinungen an der Grenzfläche zweier Lösungsmittel, Ann. Physi., 8(4):602.

    Google Scholar 

  • Parker, A.J., 1969, Protic-dipolar aprotic solvent effects on rates of bimolecular reactions, Chem. Revs., 69:1

    Article  CAS  Google Scholar 

  • Perry, M., Löbel, E., and Bloch, R., 1976, The mechanism of polymeric valinomycin-based potassium specific electrodes, J. Membrane Sci., 1:233.

    Article  Google Scholar 

  • Samec, Z., and Hájková, D., 1980, private communication.

    Google Scholar 

  • Samec, Z., Mareček, V., and Weber, J., 1979, Charge transfer between two immiscible electrolyte solutions. Part II. The investigation of Cs+ ion transfer across the nitrobenzene/water interface by cyclic voltammetry with IR drop compensation, J. Electroanal. Chem., 100:841.

    Article  CAS  Google Scholar 

  • Sandblom, J., Eisenman, G., and Walker, J.L., 1967a, Electrical phenomena associated with the transport of ions and ion pairs in liquid ion-exchange membranes I. Zero current properties. J. Phys. Chem., 71:3862.

    Article  PubMed  CAS  Google Scholar 

  • Sandblom, J., Eisenman, G., and Walker, J.L., 1967b, Electrical phenomena associated with the transport of ions and ion apirs in liquid ion-exchange membrane II. Nonzero current properties, J. Phys. Chem., 71:3871.

    Article  CAS  Google Scholar 

  • Thomas, A.P., Viviani-Nauer, A., Arvanitis, S., and Simon, W., 1977, Mechanism of neutral carrier mediated ion transport through ion-selective bulk membranes, Anal. Chem., 49:1567.

    Article  Google Scholar 

  • Ujec, E., 1980, private communication.

    Google Scholar 

  • Ujec, E., Keller, O., Pavlík, V., and Machek, J., 1978, Electrical parameters of a coaxial, low-resistance, potassium-selective micro-electrode, Physiol. bohemoslov., 27:570.

    Google Scholar 

  • Ujec, E., Keller, O., Machek, J., and Pavlík, V., 1979, Low impedance coaxial K+ selective microelectrodes, Pflügers Arch., 382:189.

    PubMed  CAS  Google Scholar 

  • Vetter, K.J., 1961, “Elektrochemische Kinetik”, Springer-Verlag, Berlin, p.122.

    Google Scholar 

  • VyskoČil F., and Kříž N., 1972, Modifications of single and double-barrel potassium specific microelectrodes for physiological experiments, Pflügers Arch., 337:265.

    Article  Google Scholar 

  • Walker, J.L., Eisenman, G., and Sandblom, J., 1968, Electrical phenomena associated with the transport of ions and ion pairs in liquid ion-exchange membrane III. Experimental observations in a model system, J. Phys. Chem., 72:978.

    Article  PubMed  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1981 Plenum Press, New York

About this chapter

Cite this chapter

Koryta, J. (1981). Theory of Ion-Selective Electrodes. In: Syková, E., Hník, P., Vyklický, L. (eds) Ion-Selective Microelectrodes and Their Use in Excitable Tissues. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9224-2_1

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-9224-2_1

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-9226-6

  • Online ISBN: 978-1-4615-9224-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics