Skip to main content

Correlation Effects in Electron-Atom Scattering

  • Chapter
Atomic Physics 7
  • 242 Accesses

Abstract

Although the independent-electron model is usually a good first approximation when considering atomic structure or electron-atom collision processes, and the model can usually be improved pertur-batively to take account of the effects of electron-electron correlations, there remain nevertheless some essentially non-perturbative systems in which these correlations are of major importance. These correlation-dominated examples include transitions in which two electrons essentially change their state simultaneously, and systems in which electron-electron correlations are so strong that the independent-electron model fails to provide an adequate starting basis for classification purposes (see for example Fano 1976, Herrick and Keilman 1980, Fano 1980).

Written while on study leave at FOM-Instituut voor Atoom- en Molecuulfysica, Amsterdam.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Brunt J.N.H., King G.C. and Read F.H., 1976, A study of resonance structure in Ne, Ar, Kr and Xe using metastable excitation by electron impact with high energy resolution, J.Phys.B (Atom. Molec.Phys.)9, 2195–2207.

    Article  ADS  Google Scholar 

  • Brunt J.N.H., King G.C. and Read F.H., 1977a, A study of resonance structure in helium using metastable excitation by electron impact with high energy resolution, J.Phys.B (Atom.Molec.Phys.) 10, 433–448.

    Article  ADS  Google Scholar 

  • Brunt J.N.H., King G.C. and Read F.H., 1977b, Resonance structure in elastic electron scattering from He, Ne and Ar, J.Phys.B (Atom.Molec.Phys.)10 1289–1301.

    Article  ADS  Google Scholar 

  • Brunt J.N.H., Read F.H. and King G.C, 1977c, The realization of high energy resolution using the hemispherical electrostatic energy selector in electron-impact spectrometry, J.Phys.E (Sci. Instrum.) 10, 134–9.

    Article  ADS  Google Scholar 

  • Bryant H.C., 1981, Photodetachment studies on a relativistic H-beam, this volume.

    Google Scholar 

  • Burke P.G., and McVicar D.D., 1965, Resonances in e - He+ scattering and the photoionization of He, Proc.Phys.Soc. 86, 989–1006.

    Article  ADS  Google Scholar 

  • Cooke W.E. and Gallagher T.F., 1980, Effects of blackbody radiation on highly excited atoms, Phys.Rev. A21, 588–593.

    ADS  Google Scholar 

  • Cooper J.W., Fano U. and Prats F., 1963, Classification of two-electron excitation levels of helium, Phys.Rev.Lett. 10, 518–21.

    Article  ADS  Google Scholar 

  • Cvejanovic S. and Read F.H., 1974, Studies of the threshold electron-impact ionization of helium, J.Phys.B (Atom. Molec. Phys . )7, 1841–1852.

    Article  ADS  Google Scholar 

  • Fano U., 1974, Excitation of atoms to states of high orbital momentum, J.Phys.B (Atom.Molec.Phys.)7, L401–4.

    Article  ADS  Google Scholar 

  • Fano U., 1976, Dynamics of electron excitation, Physics Today 29 (no.9) 32–41.

    Article  ADS  Google Scholar 

  • Fano U., 1980, Wave propagation and diffraction on a potential ridge, Phys.Rev., in press.

    Google Scholar 

  • Fano U. and Lin CD., 1975, Correlations of excited electrons, in: “Atomic Physics 4”, G. zu Putlitz, E.W. Weber and A. Winnacker, eds., Plenum Press, New York and London, pp.47–70.

    Google Scholar 

  • Hammond P., King G.C. and Read F.H., Investigation of electron-impact resonances of Ne, Ar and Kr, to be published.

    Google Scholar 

  • Heideman H.G.M., Van der Water W. and Van Moergestel L.J.M. , 1980, The effect of long-range electron correlations on the polarization of atomic line radiation excited by electron impact, J.Phys. B (Atom.Molec.Phys.), in press.

    Google Scholar 

  • Herrick D.R. and Keilman Ì.Å., 1980, Novel supermultiplet energy levels for doubly excited He, Phys.Rev. A21, 418–425.

    ADS  Google Scholar 

  • Herrick D.R. and Sinanoglu O., 1975, Comparison of doubly-excited helium energy levels, isoelectronic series, autoionization lifetimes, and group-theoretical configuration mixing predictions with large-configuration-interaction calculations and experimental spectra, Phys.Rev. A 11, 97–110.

    ADS  Google Scholar 

  • Keilman M.E. and Herrick D.R., 1978, Rotor-like spectra for some doubly-excited two-electron states, J.Phys.B (Atom.Molec.Phys.) 11, L755–759.

    Article  ADS  Google Scholar 

  • Klar Ç. and Klar M., 1980, An accurate treatment of two-electron systems using hyperspherical coordinates, J.Phys.B (Atom.Molec. Phys.) 13, 1057–1072.

    Article  ADS  Google Scholar 

  • Klar Ç. and Schlecht W. , 1976, Threshold multiple ionization of atoms: energy dependence for double and triple escape, J.Phys.B (Atom.Molec.Phys.) 9, 1699–1711.

    Article  ADS  Google Scholar 

  • Koch P.R., Hieronymus H., Van Raan A.F.J, and Raith W., 1980, Direct observation of the interaction between Rydberg atoms and black-body radiation, Phys.Lett. 75A, 273–5.

    ADS  Google Scholar 

  • Kruit P., Read F.H. and Van der Wiel Ì.J., 1980, private communication.

    Google Scholar 

  • Langendam P.J.K. and Van der Wiel M.J., 1978, Fine structure of the neon 18.5 — 18.7 eV resonances resolved by means of resonant free-free radiative absorptions, J.Phys.B (Atom.Molec.Phys.) 11, 3603–3613.

    Article  ADS  Google Scholar 

  • Langlois J. and Sichel J.M., 1980, Calculation of doubly-excited energy levels of rare-gas atoms by frozen-core superposition of configurations method: odd-parity levels of neon and coupling of subshell angular momenta, J.Phys.B (Atom.Molec.Phys.) 13, 881–889.

    Article  ADS  Google Scholar 

  • Lin CD., 1974, Correlations of excited electrons: the study of channels in hyperspherical coordinates, Phys.Rev. 10A, 1986–2001.

    ADS  Google Scholar 

  • Lin CD., 1975, Feshbach and shape resonances in the e-H 1P system, Phys.Rev.Lett. 35, 1150–3.

    Article  ADS  Google Scholar 

  • Lipsky L., Anania R. and Connealy M.J., 1977, Energy levels and classifications of doubly-excited states in two-electron systems with nuclear charge Z = 1 to 5 below the N = 2 and 3 thresholds, At.Data and Nucl.Data Tables 20, 127–41.

    Article  ADS  Google Scholar 

  • Macek J., 1968, Properties of autoionizing states of He, J.Phys.B (Atom.Molec.Phys.) 1, 831–43.

    Article  ADS  Google Scholar 

  • Madden R.P. and Codling K, 1963, New autoionizing atomic energy levels in He, Ne and Ar, Phys.Rev.Lett. 10, 516–8.

    Article  ADS  Google Scholar 

  • Marchand P., Paquet C, and Marmet P., 1969, Threshold behaviour of the cross-section for ionization of He and Ar by mono-energetic electrons, Phys.Rev. 180, 123–132.

    Article  ADS  Google Scholar 

  • Nesbet R.K., 1978, Resonances, cusp effects and a virtual state in e — He scattering near the n = 3 thresholds, J.Phys.B (Atom.Molec. Phys.) 11, L21–4.

    Article  ADS  Google Scholar 

  • Peterkop R., 1971, WKB approximation and threshold law for electron-atom ionization, J.Phys.B (Atom.Molec.Phys.) 4, 513–521.

    Article  ADS  Google Scholar 

  • Pichou F., Huetz A, Joyez G. and Landau M, 1978, Near-threshold ionization of helium by electron impact, J.Phys.B (Atom.Molec. Phys.) 11, 3683–3692.

    Article  ADS  Google Scholar 

  • Rau A.R.P., 1971, Two-electrons in a Coulomb potential: double-continuum wave-funetions and threshold law for electron-atom ionization, Phys.Rev. A 4, 207–220.

    ADS  Google Scholar 

  • Read F.H., 1977, A modified Rydberg formula, J.Phys.B (Atom.Molec. Phys.) 10, 449–457.

    Article  ADS  Google Scholar 

  • Read F.H., Brunt J.N.H. and King G.C., 1976, The classification of resonances in electron-impact on Ne, Ar, Kr and Xe, J.Phys.B (Atom.Molec.Phys.) 9, 2209–2218.

    Article  ADS  Google Scholar 

  • Rehmus P., Keilman Ì.E. and Berry R.S., 1978, spatial correlation of atomic electrons in He**, Chem.Phys. 31, 239–262.

    Google Scholar 

  • Schulz G.J., 1973, Resonances in electron impact on atoms, Rev.Mod. Phys. 45, 378–422.

    Google Scholar 

  • Simpson J.A. and Fano U., 1963, Classification of resonances in the electron scattering cross-section of Ne and He, Phys.Rev.Lett. 11, 158–9.

    Article  ADS  Google Scholar 

  • Sinanoglu O. and Herrick D.R., 1975, Group-theoretical prediction of configuration mixing effects due to Coulomb repulsions in atoms with applications to doubly-excited spectra, J.Chem.Phys. 62, 886–892.

    Article  ADS  Google Scholar 

  • Spence D., 1975, Electron correlation effects near threshold for electron-impact ionization of helium, Phys.Rev. A 11, 1539–42.

    ADS  Google Scholar 

  • Tarr S.M. , Schiavone J.A. and Freund R.S., 1980, Observation of direct excitation of high-orbital-angular momentum high-Rydberg states by threshold-energy electron collisions, Phys.Rev.Lett. 44, 1660–3.

    Article  ADS  Google Scholar 

  • Van der Wiel M.J., 1972, Threshold behaviour of double photo-ioniza-tion in He , Phys.Lett. 41A, 389–390.

    ADS  Google Scholar 

  • Vinkalns I. and Gailitis M., 1967, The threshold behaviour of ionization cross-sections, in: Vth ICPEAC, eds. I.P. Flaks, E.S. Solovyov, Nauka, Leningrad, pp.648–650.

    Google Scholar 

  • Wannier G.H., 1953, The threshold law for single ionization of atomsor ions by electrons, Phys.Rev. 90, 817–825.

    Article  ADS  MATH  Google Scholar 

  • Wulfman C., 1973, Approximate dynamical symmetry of two-electron atoms, Chem.Phys.Lett. 23, 370–372.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1981 Plenum Press, New York

About this chapter

Cite this chapter

Read, F.H. (1981). Correlation Effects in Electron-Atom Scattering. In: Kleppner, D., Pipkin, F.M. (eds) Atomic Physics 7. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9206-8_19

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-9206-8_19

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-9208-2

  • Online ISBN: 978-1-4615-9206-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics