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Fluctuations and Ordering in Nematic Liquid Crystals

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Abstract

The paper discusses the odd-even fluctuation of the various thermodynamic properties of two homologous series of nematic liquid crystals near the nematic/isotropic transition temperature. A new alignment phenomenon not previously discussed in the literature (associated with horizontally aligned films between glass substrates) is reported. The degree of alignment near the nematic/isotropic transition temperature increases, while the order parameter decreases, reversibly with increasing temperature. Development of a rigorous theory of anisotropic intermolecular interactions to interpret quantitatively these experimental observations is suggested.

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References

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© 1978 Springer Science+Business Media New York

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Chang, R. (1978). Fluctuations and Ordering in Nematic Liquid Crystals. In: Johnson, J.F., Porter, R.S. (eds) Liquid Crystals and Ordered Fluids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8888-7_24

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  • DOI: https://doi.org/10.1007/978-1-4615-8888-7_24

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-8890-0

  • Online ISBN: 978-1-4615-8888-7

  • eBook Packages: Springer Book Archive

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