Abstract
The paper discusses the odd-even fluctuation of the various thermodynamic properties of two homologous series of nematic liquid crystals near the nematic/isotropic transition temperature. A new alignment phenomenon not previously discussed in the literature (associated with horizontally aligned films between glass substrates) is reported. The degree of alignment near the nematic/isotropic transition temperature increases, while the order parameter decreases, reversibly with increasing temperature. Development of a rigorous theory of anisotropic intermolecular interactions to interpret quantitatively these experimental observations is suggested.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
R. Chang, Mol. Cryst. and Liq. Cryst. 30, 155 (1975).
R. Chang, F. B. Jones, Jr., and J. J. Ratto, Mol. Cryst. and Liq. Cryst. 33, 13 (1976).
M. Born and E. Wolf, “Principles of Optics”, MacMillan, New York, 1964, p. 965.
G. Pelzl and H. Sackmann, Sym. Faraday Soc. No. 5, 68 (1971).
See Reference (2).
E. G. Hanson and Y. R. Shen, Mol. Cryst. and Liq. Cryst. 36, 143 (1976).
G. R. van Hecke, B. D. Santarsiero, and L. J. Theodore, Mol. Cryst. and Liq. Cryst. (in press).
P. G. de Gennes, “The Physics of Liquid Crystals”, Clarendon Press, Oxford, 1974.
W. Maier and A. Saupe, Z. Naturforsch., 13a, 564 (1958); 14a, 882 (1959); 15a, 287 (1960); 16a, 816 (1961).
S. Marcelja, J. Chem. Phys. 60, 3599 (1974).
A. Pines, D. J. Ruben, and S. Allison, Phys. Rev. Letters 33, 1002 (1974).
H. Meirovitch, Chem. Physics 21, 251 (1977).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1978 Springer Science+Business Media New York
About this chapter
Cite this chapter
Chang, R. (1978). Fluctuations and Ordering in Nematic Liquid Crystals. In: Johnson, J.F., Porter, R.S. (eds) Liquid Crystals and Ordered Fluids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8888-7_24
Download citation
DOI: https://doi.org/10.1007/978-1-4615-8888-7_24
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4615-8890-0
Online ISBN: 978-1-4615-8888-7
eBook Packages: Springer Book Archive