Abstract
It is impossible to predict the mesomorphic behavior (if any) of a compound using modern liquid crystal theory. When the compound belongs to an already recognized liquid crystalline homologous series, it is safe to assume that some liquid crystal behavior will be exhibited. Given the heats and temperatures of transition of neighboring homologs, the transition entropy of the new homolog may be estimated.1 However, if the compound in question belongs to an entirely new homologus series, only intuition and previous experience furnish any guide to possible mesomorphic properties.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Bondi, A., (1967) Chem. Rev. 67, 565.
Brown, G. H. and Shaw, W. G. (1957) Chem. Rev. 57, 1049.
McMillan, W. L. (1974) in Liquid Crystals and Ordered Fluids, J. F. Johnson and R. S. Porter, eds., Vol. 2, Plenum Press, N.Y., p. 141.
Verbit, L. and Tuggey, R. L., ibid., p. 307.
Wegner, G. (1972) Die Makromol. Chem. 154, 35.
Ibid. (1971) 145, 85.
Grant, B., to be submitted or J. of Organic Chemistry.
Doelman, A. (1975) San Francisco ACS Meeting Preprints, Symposium on Analytical Calorimetry, August 31, ANAL77.
Doelman, A., Gregges, A. R., and Barrali, E. M., II, in Analytical Calorimetry, R. S. Porter and J. F. Johnson, eds., Vol. 4, Plenum Press, N.Y., in press.
Barrali, E. M., II, and Diller, R. D. (1970) Thermochim. Acta 1, 509.
Barrali, E. M., II, Porter, R. S., and Johnson, J. F. (1967) J. Phys. Chem. 71, 895.
Barrali, E. M., II, Cox, R. J., Doelman, A., Clecak, N., Logan, J. A., and Gregges, A. R., in Analytical Calorimetry, op. cit., in press.
Barrali, E. M. II, and Johnson, J. F. (1974) in Liquid Crystals and Plastic Crystals, G. W. Gray and P. A. Winsor, eds., John Wiley and Sons, N.Y., p. 268.
Chow, L. C. and Martire, D. E. (1969) J. Phys. Chem. 73, 1127.
Levelut, A. M. and Lambert, M. (1971) C.r. hebd. Seanc. Acad. Sci. Paris 272, 1018.
Coates, D. and Gray, G. W. (1976) Microscope 24, 117.
Taylor, T. R., Arora, S. L., and Ferguson, J. L. (1970) Phys. Rev. Lett. 15, 722.
Flick, J. R., Marshall, A. S., and Petrie, S. E. B., in Analytical Calorimetry, op. cit., p. 97.
Arnold, H. (1964) Z. Phys. Chem. 226, 146.
Herbert, A. J. (1967) Trans. Faraday Soc. 63, 555.
Arnold H. (1964) Z. Phys. Chem. 225, 45.
Barrall, E. M., II, and Guffy, J. C. (1967) in Advances in Chemistry, 63, R. S. Porter and J. F. Johnson, eds., American Chemical Society, Washington, D.C., p. 1.
Stein, R. S., Rhodes, M. B., and Porter, R. S. (1968) Interface Sci. 27, 336.
Baessler, H., Labes, M. M. (1970) Molecular Cryst. and Liquid Cryst. 6, 419.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1978 Springer Science+Business Media New York
About this chapter
Cite this chapter
Barrall, E.M., Grant, B., Gregges, A.R. (1978). Thermal Properties of a New Series of Liquid Crystal Forming Materials: p,p′-DI-n-Alkyldiphenyl and p,p′-DI-n-Alkoxy-Diphenyldiacetylenes. In: Johnson, J.F., Porter, R.S. (eds) Liquid Crystals and Ordered Fluids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8888-7_2
Download citation
DOI: https://doi.org/10.1007/978-1-4615-8888-7_2
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4615-8890-0
Online ISBN: 978-1-4615-8888-7
eBook Packages: Springer Book Archive