Abstract
In their article on g-strain and A-strain in non-blue Type II copper complexes, Froncisz and Hyde (1) established that best resolution in the g∥ region of powder EPR spectra occurs generally for the turning point assigned to the MI = -½ copper nuclear quantum number using a microwave frequency of about 2 GHz. Under these experimental conditions g-strain and A-strain cancel. The concepts were further elaborated in the review article by Hyde and Froncisz (2) on the role of microwave frequency in EPR spectroscopy of copper complexes.
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References
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Hyde, J.S., Antholine, W.E., Froncisz, W., Basosi, R. (1986). EPR Determination of the Number of Nitrogens Coordinated to Cu in Square-Planar Complexes. In: Niccolai, N., Valensin, G. (eds) Advanced Magnetic Resonance Techniques in Systems of High Molecular Complexity. Progress in Inorganic Biochemistry and Biophysics, vol 2. Birkhäuser Boston. https://doi.org/10.1007/978-1-4615-8521-3_28
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DOI: https://doi.org/10.1007/978-1-4615-8521-3_28
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