Abstract
The use of magnetic resonance techniques in studies of structure and molecular dynamics of inclusion compounds has increased dramatically in recent years. Considering the importance of many types of clathrates in catalysis this is to be expected. Considering the inherent charming physical chemical properties of many clathrates, it is surprising that physical chemists among the magnetic resonance community have waited so long to take an in depth look at the properties of these materials. It turns out that deuterium NMR is very well suited for investigating the dynamics of clathrates.
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References
R.R. Vold and R.L. Vold, in “Liquid Crystals and Ordered Fluids” (A.C. Griffin and J.F. Johnson eds.), Vol. 4, 561, 1984.
R.L. Vold, R.R. Vold, J.F. Martin, B.C. Nishida and L. Selwyn, this same book.
J. Szejtli, “Cyclodextrins and their Inclusion Complexes”, Akademiai Kaodo, Budapest (1982).
R.K. McMullan, W. Saenfer, J. Fayos and D. Mootz, Carbohyd.Res. 31, 371 (1973).
K. Flohr, R.M. Patton and E.T. Kaiser, J.Amer.Chem.Soc. 97, 1209 (1975).
H. Ueda and T. Nagai, Chem.Pharm.Bull. 29, 2710 (1981).
M.S. Greenfield, A.D. Ronemus, P.D. Ellis, R.L. Vold and R.R. Vold, to be published.
M. Mehring, in “Principles of High Resolution NMR in Solids”, Springer-Verlag, Berlin, 1983.
J.C. Rayez and J.J. Dannenberg, Chem.Phys. Letters 41, 492 (1976).
O. Bastiansen, Acta Chem.Scand. 3, 408 (1949).
A. d’Annibale, L. Lunazzi, A.C. Boicelli and D. Macciantelli, J.Chem.Soc. Perkin II, 1396 (1973).
M.F. Bengen, Ann.Chem. 565, 204 (1949).
R.M. Barrer, in “Non-Stoichiometric Compounds” (L.Mandelcorn Ed.), Ch. 6, Academic Press, New York, 1964.
A.E. Smith, Acta Cryst. 5, 224 (1952).
D.F.R. Gilson and C.A. McDowell, Mol.Phys. 4, 125 (1961).
H.L. Casal, D.G. Cameron and E. Kelushky, J.Chem.Phys. 80, 1407 (1984).
Y. Chatani,H. Anraku and Y. Taki, Mol.Cryst.Liq.Cryst. 48, 219 (1978).
R.L. Vold,W.H. Dickerson and R.R. Vold, J.Magn.Reson. 43, 213 (1981).
J. Jeener and P. Broekaert, Phys.Rev. 157, 232 (1967).
R.E. London and J. Avitabile, J.Amer.Chem.Soc. 100, 7159 (1978).
R.J. Wittebort and A. Szabo, J.Chem.Phys. 69, 1722 (1978).
J. Ragle and K. Sherk, J.Chem.Phys. 50, 3553 (1969).
T. Caves and M. Karplus, J.Chem.Phys. 45, 1670 (1966).
J.F. Harrison, J.Chem.Phys. 48, 2379 (1968).
S.C. Wofsy, J.S. Muenter and W. Klemperer, J.Chem.Phys. 53, 4005 (1970).
E.R. Henry and A. Szabo, J.Chem.Phys. 82, 4753 (1985).
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© 1986 Birkhäuser Boston, Inc.
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Vold, R.R., Vold, R.L., Greenfield, M.S., Ronemus, A. (1986). Deuterium Relaxation and Molecular Motion in Channel Clathrates. In: Niccolai, N., Valensin, G. (eds) Advanced Magnetic Resonance Techniques in Systems of High Molecular Complexity. Progress in Inorganic Biochemistry and Biophysics, vol 2. Birkhäuser Boston. https://doi.org/10.1007/978-1-4615-8521-3_22
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DOI: https://doi.org/10.1007/978-1-4615-8521-3_22
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