Skip to main content

Reported solubilities of 738 pesticide chemicals in water

  • Conference paper

Part of the book series: Residue Reviews / Rückstands-Berichte ((RECT,volume 20))

Abstract

There is no single compilation of the solubilities of pesticide chemicals in water, yet both actual and surmised solubility figures are used daily to predict or extrapolate such parameters as systemic penetration into aqueous tissues, distributions from formulations into aqueous spray carriers, transfer coefficients from residence in soils or decomposing vegetation into runoff and ground water, ease of removal from treated commodities by water rinsing, probable water contamination from direct applications or from spillage, and others. Exhaustive search of the literature by titles and by pesticides discloses that comparatively few numerically useful solubilities of pesticide chemicals in water have been recorded, however. As will be discussed later, a description of “slightly soluble” or “practically insoluble” is hardly definitive or even useful. It is hoped that the present exhaustive compilation will stimulate the production of actual solubility data, for even casual examination of the table (Table I) will disclose glaring inconsistencies and lamentable gaps in the literature commonly available to research workers and others interested in even approximate solubility data.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Abel, A. L.: The substituted urea herbicides. Chem. & Ind. 33, 1106 (1957).

    Google Scholar 

  2. American Cyanamid Company: Cynem Zinophos (experimental nematocide 18,133) (1961); Information Bull.—ABATE insecticide PE-5360-IM-3/65; Tech. Information—CYPREX fruit fungicide; Tech. Information—THIMET systemic insecticide; Tech. Information—CYGON systemic insecticide for housefly control, certain crops, and ornamental plants.

    Google Scholar 

  3. Anonymous (Entomological Society of America): Pesticide reference standards. Bull. Entomol. Soc. Amer. 12, 117, 348, and 356 (1966).

    Google Scholar 

  4. Babers, F. H.: The solubility of DDT in water determined radiometrically. J. Amer. Chem. Soc. 77, 4666 (1955).

    Article  CAS  Google Scholar 

  5. Bailey, G. W., and J. L. White: Herbicides—A compilation of their physical, chemical, and biological properties. Residue Reviews 10, 97 (1965).

    PubMed  CAS  Google Scholar 

  6. Bartley, C. E.: Triazine compounds. Farm Chemicals 122(5), 28(1959)

    Google Scholar 

  7. Biggar, J. W., L. D. Doneen, and R. L. Riggs: Soil interaction with organically polluted water. Summary Report. Dept. of Water Science and Engineering, University of California, Davis, Calif. (1966).

    Google Scholar 

  8. Bowman, M. C., F. Agree, and M. K. Corbett: Solubility of C14-DDT in water. J. Agr. Food Chem. 8, 406 (1960).

    Article  CAS  Google Scholar 

  9. Bowman, M. C., F. Agree, and M. K. Corbett, C. H. Schmidt, and M. Beroza: Fate of DDT in larvicidal suspensions. J. Econ. Entomol. 52, 1038 (1959)

    CAS  Google Scholar 

  10. Buch, H. C., and C. W. Todd: 3-(p-Chlorophenyl)-1,1-dimethyl urea—A new herbicide. Science 114, 493 (1951).

    Article  Google Scholar 

  11. Burchfield, H. P., D. E. Johnson, and E. E. Storrs: Guide to the analysis of pesticide residues, 2 vol. Washington, D.C.: U. S. Department of Health, Education, and Welfare, Public Health Service (1965).

    Google Scholar 

  12. Cassil, C. C.: Private communication (1966) (see also ref. 19).

    Google Scholar 

  13. Chemagro Corporation: BAY 25141 insecticide and nematocide (Jan. 1966); BAY 29493 (BAYTEX, ENTEX) insecticide (Jan. 1966); BAY 37289 insecticide for experimental use only (Jan. 1966); BAYGON insecticide (Jan. 1966); CO-RAL parasiticide (Jan. 1966); DEXON fungicide (Jan. 1966); DI-SYSTON insecticide (Jan. 1966); DYLOX insecticide (Jan. 1966); GUTHION and GUTHION M.E. insecticide (Jan. 1966); METASYSTOX-R insecticide (Jan. 1966); MORESTAN acaricide-insecticide-fungicide (Jan. 1966); SYSTOX insecticide (Jan. 1966).

    Google Scholar 

  14. Chitwood, B. G.: Nematocidal action of halogenated hydrocarbons. Adv. Chem. Series 7, 91 (1952).

    Article  Google Scholar 

  15. CIBA, Ltd.: Personal communication (1967).

    Google Scholar 

  16. Cohen, J. M., L. J. Kamphake, A. E. Lemke, C. Henderson, and R. L. Woodward: Effect of fish poisons on water supplies. Part I. Removal of toxic materials. J. Amer. Water Works Assoc. 52, 1551 (1960).

    CAS  Google Scholar 

  17. Coon, F. B., E. F. Richter, L. W. Hein, and C. H. Krieger: Problems encountered in physio-chemical determination of warfarin. J. Agr. Food Chem. 2, 739 (1954).

    Article  CAS  Google Scholar 

  18. David, W. A. L., R. L. Metcalf, and M. Winton: The systemic insecticidal properties of certain carbamates. J. Econ. Entomol. 53, 1021 (1960).

    CAS  Google Scholar 

  19. Faust, S. D., and O. M. Aly: Evaluation of the solubilities of the calcium and magnesium salts of 2,4-dichlorophenoxy acetic acid. J. Chem. Eng. Data 8, 413 (1963).

    Article  CAS  Google Scholar 

  20. Faust, S. D., and O. M. Aly, and I. H. Suffet: Recovery, separation, and identification of organic pesticide from natural and potable waters. Residue Reviews 15, 44 (1966).

    PubMed  CAS  Google Scholar 

  21. Food Machinery and Chemical Corporation, Niagara Chemical Division: Tech. Bull. (Apr. 1966).

    Google Scholar 

  22. Freed, V. H.: Herbicide mechanisms-Mode of action other than aryloxyalkyl acids. J. Agr. Food Chem. 1, 47 (1953).

    Article  CAS  Google Scholar 

  23. Freed, V. H., and P. Burschel: The relationship of water solubility to dosage of herbicides. Z. Pflanzenkrankh. i. Pflanzenschutz 64, 477 (1957).

    CAS  Google Scholar 

  24. Gauvandan, P., and H. Pousell: Mechanism of insecticidal action of 1,1,1trichloro-2,2-bis(p-chlorophenyl)ethane and the thermodynamic rule applying to different narcotics. Compt. rend. 224, 683 (1947).

    Google Scholar 

  25. Geigy Chemical Corporation: Personal communication (Apr. 1966).

    Google Scholar 

  26. Gorter, C. J.: Solubilities of plant growth regulators. Mededel. Directeur Tuinbouw 23, 300 (1960).

    CAS  Google Scholar 

  27. Gysin, H.: Triazine herbicides-Their chemistry, biological properties and mode of action. Chem. & Ind. 31, 1393 (1962).

    Google Scholar 

  28. Gysin, H., and E. Knüsli: Chemistry and herbicidal properties of triazine derivatives. Adv. Pest Control Research 3, 289 (1960).

    CAS  Google Scholar 

  29. Hancock, W., and E. Q. Laws: Determination of traces of benzene hexachloride in water and sewage effluents. Analyst 80, 665 (1955).

    Article  CAS  Google Scholar 

  30. Hansens, E. J.: Three new insecticides for housefly control in barns. J. Econ. Entomol. 46, 372 (1953).

    CAS  Google Scholar 

  31. Hercules Powder Company: DELNAV, a miticide and insecticide toxicant. Bull. AP-107 (1966); Physical and chemical properties of Hercules Toxaphene. Bull. AP-103 (1966); Summary of toxicological investigations of Herbam. Bull. T109A.

    Google Scholar 

  32. Hodgman, C. D., ed.: Handbook of chemistry and physics, 43rd ed. Cleveland: Chemical Rubber Co. (1961).

    Google Scholar 

  33. Hours, J. P.: Specification for ideal nematocides. Plant Disease Reporter 42, 291 (1958).

    Google Scholar 

  34. Ivanov, K. A.: Solubility of benzene hexachloride in water. Gigiena i Sanit. 21, 82 (1956).

    CAS  Google Scholar 

  35. Jones, H. A., and C. M. Smith: The solubility of rotenone. I. Solubility and optical rotation in certain organic solvents at 20° C. J. Amer. Chem. Soc. 52, 2554 (1930).

    CAS  Google Scholar 

  36. Leopold, A. C., P. VAN Schaik, and M. Neal: Molecular structure and herbicide adsorption. Weeds 8, 48 (1960).

    Article  CAS  Google Scholar 

  37. March, R. B.: The chemistry and action of acaricides. Ann. Rev. Entomol. 3, 355 (1958).

    Article  CAS  Google Scholar 

  38. Martin, H.: Guide to the chemicals used in crop protection, 4th ed. Canad. Dept. Agr. Publ. 1093(1961).

    Google Scholar 

  39. Martin, H.: Insecticide and fungicide handbook for crop protection, 1st. ed. Oxford: Blackwell Scientific (1963).

    Google Scholar 

  40. McLaughlin Gormley King Company Personal communication (Apr. 1966).

    Google Scholar 

  41. McNew, G. L., and O. L. Hoffman: Growth regulant, herbicidal and physical properties of 2,4-D and related compounds. Iowa State College J. Sci. 24, 189 (1950).

    CAS  Google Scholar 

  42. Minark, C. E.: Pre-emergence herbicides and their behaviour. Proc. NE Weed Control Conf. 5 (Suppl.), 29(1951).

    Google Scholar 

  43. Neal, P. A., V. Oettinger, W. F. Smith, W. W. Malmo, R. B. Dunn, R.C. Moran, H. H.Swezey, T. R. Armstrong, and W. C. White: Toxicity and potential dangers of aerosols, mists, and dusting powder containing DDT. U. S. Public Health Service, Reports Suppl. 177(1944).

    Google Scholar 

  44. Nex, R. W., and A. W. Swezey: Some chemical and physical properties of weed killers. Weeds 3, 241 (1954).

    Article  Google Scholar 

  45. Orlovsky, V. M.: Maximum permissible concentration of chlorocyclohexane in water basins. Gigiena i Sanit. 27, 24 (1962).

    Google Scholar 

  46. Peck, D. R.: Alkali stability of the insecticide E. 605. Chem. & Ind. 33, 526 (1948).

    Google Scholar 

  47. De Pietri-Tonelli, P.: Personal communication (Feb. 28, 1967 ), Montecatini Edison, Milano.

    Google Scholar 

  48. Reynolds, H. T., and R. L. Metcalf: Effect of water solubility and soil moisture upon plant uptake of granulated systemic insecticides. J. Econ. Entomol. 55, 2 (1962).

    CAS  Google Scholar 

  49. Richard, A. G., and L. K. Cutkomp: Correlation between the possession of a chitinous cuticle and sensitivity to DDT. Biol. Bull. 90, 97 (1946).

    Article  Google Scholar 

  50. Richardson, L. T., and D. M. Miller: Fungitoxicity of chlorinated hydrocarbon insecticides in relation to water solubility and vapour pressure. Canad. J. Bot. 38, 163 (1960).

    Article  CAS  Google Scholar 

  51. Roeder, K. D., and E. A. Weiant: The site of action of DDT in the cockroach. Science 103, 304 (1946).

    Article  CAS  Google Scholar 

  52. Rohm & Haas Company:Tolerances and uses of Rohm & Haas agricultural chemicals (Apr. 1966).

    Google Scholar 

  53. Sazonov, P. V., A. A. Bogdarina, and A. S. Gudkova: Biological activity of aqueous solutions of DDT and HCH. Trudy Vsesoyuz Inst. Zashchity Rastenu 7, 128 (1956).

    Google Scholar 

  54. Shell Chemical Company:Summary of basic data for: Technical aldrin insecticide, Tech. Bull. SC: 59–45; AQUALIN Herbicide Tech. Bull. SC-60; AZODRIN insecticide Tech. Bull. ACD 65–151; Technical BIDRIN insecticide, Tech. Bull. ACD: 62–2R; Technical CIODRIN insecticide, Tech. Bull. ACD: 62–1; D-D soil fumigant, Tech. Bull. SC: 60–107; Technical dieldrin insecticide, Tech. Bull. SC: 60–102; Technical endrin insecticide, Tech. Bull. SC: 60–103R; NEMAGON C nematocide, Tech. Bull. ACD: 63–102; Methyl parathion insecticide, Tech. Bull. SC: 60–105; PHOSDRIN insecticide, Tech. Bull.; VAPONA insecticide, Tech. Bull. SC: 61–76.

    Google Scholar 

  55. Slade, R. E.: The gamma isomer of hexachlorocyclohexane (Gammexane). Chem. & Ind. 40, 314 (1945).

    Google Scholar 

  56. Snyder, J. A.: Studies on Warfarin, Dicumarol and, Cyclocumarol. Ph.D. thesis, Univ. of Wisc., Madison, Wisc. (1953).

    Google Scholar 

  57. Spiller, D.: A digest of available information on the insecticide malathion. Adv. Pest Control Research 4, 249 (1961).

    CAS  Google Scholar 

  58. Stauffer Chemical Company:Personal communication (Apr. 1966).

    Google Scholar 

  59. Swezey, A. W., and R. W. Nex: Some chemical and physical properties of weed killers. Suppl. I. Weeds 9, 209 (1961).

    Article  Google Scholar 

  60. The Merck Index, 7th ed. Merck & Co. Inc., Rahway, N. J. (1960).

    Google Scholar 

  61. Thompson Hayward Chemical Company: Personal communication (Apr. 1966). 56a. Union Carbide: Technical information on TEMIK and Glyodin (1966).

    Google Scholar 

  62. Vineland Chemical Company: SMA-DMA weed control (Apr. 1966).

    Google Scholar 

  63. W. A. Cleary Corporation: Personal communication (Apr. 1966).

    Google Scholar 

  64. Weed Control Handbook: Properties of herbicides, 3rd ed., p. 286. E. K. Wooford and S. A. Evans, ed. Oxford: Blackwell Scientific (1963).

    Google Scholar 

  65. West, T. F., and G. A. Campbell: DDT and newer persistent insecticides, 2nd ed. rev. London: Chapman & Hall (1952).

    Google Scholar 

  66. William, G. F.: Properties of 0,0-diethyl-O-p-nitrophenyl thiophosphate and 0,0-diethyl O-p-nitrophenylphosphate. Ind. Eng. Chem. 43, 950 (1951).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1968 Springer-Verlag New York Inc.

About this paper

Cite this paper

Gunther, F.A., Westlake, W.E., Jaglan, P.S. (1968). Reported solubilities of 738 pesticide chemicals in water. In: Gunther, F.A. (eds) Residue Reviews. Residue Reviews / Rückstands-Berichte, vol 20. Springer, New York, NY. https://doi.org/10.1007/978-1-4615-8428-5_1

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-8428-5_1

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4615-8430-8

  • Online ISBN: 978-1-4615-8428-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics