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Reported solubilities of 738 pesticide chemicals in water

  • F. A. Gunther
  • W. E. Westlake
  • P. S. Jaglan
Part of the Residue Reviews / Rückstands-Berichte book series (RECT, volume 20)

Abstract

There is no single compilation of the solubilities of pesticide chemicals in water, yet both actual and surmised solubility figures are used daily to predict or extrapolate such parameters as systemic penetration into aqueous tissues, distributions from formulations into aqueous spray carriers, transfer coefficients from residence in soils or decomposing vegetation into runoff and ground water, ease of removal from treated commodities by water rinsing, probable water contamination from direct applications or from spillage, and others. Exhaustive search of the literature by titles and by pesticides discloses that comparatively few numerically useful solubilities of pesticide chemicals in water have been recorded, however. As will be discussed later, a description of “slightly soluble” or “practically insoluble” is hardly definitive or even useful. It is hoped that the present exhaustive compilation will stimulate the production of actual solubility data, for even casual examination of the table (Table I) will disclose glaring inconsistencies and lamentable gaps in the literature commonly available to research workers and others interested in even approximate solubility data.

Keywords

Solubility Data Pesticide Chemical Dimethyl Ester Carbamic Acid American Cyanamid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Abel, A. L.: The substituted urea herbicides. Chem. & Ind. 33, 1106 (1957).Google Scholar
  2. 2.
    American Cyanamid Company: Cynem Zinophos (experimental nematocide 18,133) (1961); Information Bull.—ABATE insecticide PE-5360-IM-3/65; Tech. Information—CYPREX fruit fungicide; Tech. Information—THIMET systemic insecticide; Tech. Information—CYGON systemic insecticide for housefly control, certain crops, and ornamental plants.Google Scholar
  3. 3.
    Anonymous (Entomological Society of America): Pesticide reference standards. Bull. Entomol. Soc. Amer. 12, 117, 348, and 356 (1966).Google Scholar
  4. 4.
    Babers, F. H.: The solubility of DDT in water determined radiometrically. J. Amer. Chem. Soc. 77, 4666 (1955).CrossRefGoogle Scholar
  5. 5.
    Bailey, G. W., and J. L. White: Herbicides—A compilation of their physical, chemical, and biological properties. Residue Reviews 10, 97 (1965).PubMedGoogle Scholar
  6. 6.
    Bartley, C. E.: Triazine compounds. Farm Chemicals 122(5), 28(1959)Google Scholar
  7. 6a.
    Biggar, J. W., L. D. Doneen, and R. L. Riggs: Soil interaction with organically polluted water. Summary Report. Dept. of Water Science and Engineering, University of California, Davis, Calif. (1966).Google Scholar
  8. 7.
    Bowman, M. C., F. Agree, and M. K. Corbett: Solubility of C14-DDT in water. J. Agr. Food Chem. 8, 406 (1960).CrossRefGoogle Scholar
  9. 8.
    Bowman, M. C., F. Agree, and M. K. Corbett, C. H. Schmidt, and M. Beroza: Fate of DDT in larvicidal suspensions. J. Econ. Entomol. 52, 1038 (1959)Google Scholar
  10. 9.
    Buch, H. C., and C. W. Todd: 3-(p-Chlorophenyl)-1,1-dimethyl urea—A new herbicide. Science 114, 493 (1951).CrossRefGoogle Scholar
  11. 10.
    Burchfield, H. P., D. E. Johnson, and E. E. Storrs: Guide to the analysis of pesticide residues, 2 vol. Washington, D.C.: U. S. Department of Health, Education, and Welfare, Public Health Service (1965).Google Scholar
  12. 11.
    Cassil, C. C.: Private communication (1966) (see also ref. 19).Google Scholar
  13. 12.
    Chemagro Corporation: BAY 25141 insecticide and nematocide (Jan. 1966); BAY 29493 (BAYTEX, ENTEX) insecticide (Jan. 1966); BAY 37289 insecticide for experimental use only (Jan. 1966); BAYGON insecticide (Jan. 1966); CO-RAL parasiticide (Jan. 1966); DEXON fungicide (Jan. 1966); DI-SYSTON insecticide (Jan. 1966); DYLOX insecticide (Jan. 1966); GUTHION and GUTHION M.E. insecticide (Jan. 1966); METASYSTOX-R insecticide (Jan. 1966); MORESTAN acaricide-insecticide-fungicide (Jan. 1966); SYSTOX insecticide (Jan. 1966).Google Scholar
  14. 13.
    Chitwood, B. G.: Nematocidal action of halogenated hydrocarbons. Adv. Chem. Series 7, 91 (1952).CrossRefGoogle Scholar
  15. 13a.
    CIBA, Ltd.: Personal communication (1967).Google Scholar
  16. 14.
    Cohen, J. M., L. J. Kamphake, A. E. Lemke, C. Henderson, and R. L. Woodward: Effect of fish poisons on water supplies. Part I. Removal of toxic materials. J. Amer. Water Works Assoc. 52, 1551 (1960).Google Scholar
  17. 15.
    Coon, F. B., E. F. Richter, L. W. Hein, and C. H. Krieger: Problems encountered in physio-chemical determination of warfarin. J. Agr. Food Chem. 2, 739 (1954).CrossRefGoogle Scholar
  18. 16.
    David, W. A. L., R. L. Metcalf, and M. Winton: The systemic insecticidal properties of certain carbamates. J. Econ. Entomol. 53, 1021 (1960).Google Scholar
  19. 17.
    Faust, S. D., and O. M. Aly: Evaluation of the solubilities of the calcium and magnesium salts of 2,4-dichlorophenoxy acetic acid. J. Chem. Eng. Data 8, 413 (1963).CrossRefGoogle Scholar
  20. 18.
    Faust, S. D., and O. M. Aly, and I. H. Suffet: Recovery, separation, and identification of organic pesticide from natural and potable waters. Residue Reviews 15, 44 (1966).PubMedGoogle Scholar
  21. 19.
    Food Machinery and Chemical Corporation, Niagara Chemical Division: Tech. Bull. (Apr. 1966).Google Scholar
  22. 20.
    Freed, V. H.: Herbicide mechanisms-Mode of action other than aryloxyalkyl acids. J. Agr. Food Chem. 1, 47 (1953).CrossRefGoogle Scholar
  23. 21.
    Freed, V. H., and P. Burschel: The relationship of water solubility to dosage of herbicides. Z. Pflanzenkrankh. i. Pflanzenschutz 64, 477 (1957).Google Scholar
  24. 22.
    Gauvandan, P., and H. Pousell: Mechanism of insecticidal action of 1,1,1trichloro-2,2-bis(p-chlorophenyl)ethane and the thermodynamic rule applying to different narcotics. Compt. rend. 224, 683 (1947).Google Scholar
  25. 23.
    Geigy Chemical Corporation: Personal communication (Apr. 1966).Google Scholar
  26. 24.
    Gorter, C. J.: Solubilities of plant growth regulators. Mededel. Directeur Tuinbouw 23, 300 (1960).Google Scholar
  27. 25.
    Gysin, H.: Triazine herbicides-Their chemistry, biological properties and mode of action. Chem. & Ind. 31, 1393 (1962).Google Scholar
  28. 26.
    Gysin, H., and E. Knüsli: Chemistry and herbicidal properties of triazine derivatives. Adv. Pest Control Research 3, 289 (1960).Google Scholar
  29. 27.
    Hancock, W., and E. Q. Laws: Determination of traces of benzene hexachloride in water and sewage effluents. Analyst 80, 665 (1955).CrossRefGoogle Scholar
  30. 28.
    Hansens, E. J.: Three new insecticides for housefly control in barns. J. Econ. Entomol. 46, 372 (1953).Google Scholar
  31. 29.
    Hercules Powder Company: DELNAV, a miticide and insecticide toxicant. Bull. AP-107 (1966); Physical and chemical properties of Hercules Toxaphene. Bull. AP-103 (1966); Summary of toxicological investigations of Herbam. Bull. T109A.Google Scholar
  32. 30.
    Hodgman, C. D., ed.: Handbook of chemistry and physics, 43rd ed. Cleveland: Chemical Rubber Co. (1961).Google Scholar
  33. 31.
    Hours, J. P.: Specification for ideal nematocides. Plant Disease Reporter 42, 291 (1958).Google Scholar
  34. 32.
    Ivanov, K. A.: Solubility of benzene hexachloride in water. Gigiena i Sanit. 21, 82 (1956).Google Scholar
  35. 33.
    Jones, H. A., and C. M. Smith: The solubility of rotenone. I. Solubility and optical rotation in certain organic solvents at 20° C. J. Amer. Chem. Soc. 52, 2554 (1930).Google Scholar
  36. 34.
    Leopold, A. C., P. VAN Schaik, and M. Neal: Molecular structure and herbicide adsorption. Weeds 8, 48 (1960).CrossRefGoogle Scholar
  37. 35.
    March, R. B.: The chemistry and action of acaricides. Ann. Rev. Entomol. 3, 355 (1958).CrossRefGoogle Scholar
  38. 36.
    Martin, H.: Guide to the chemicals used in crop protection, 4th ed. Canad. Dept. Agr. Publ. 1093(1961).Google Scholar
  39. 36a.
    Martin, H.: Insecticide and fungicide handbook for crop protection, 1st. ed. Oxford: Blackwell Scientific (1963).Google Scholar
  40. 37.
    McLaughlin Gormley King Company Personal communication (Apr. 1966).Google Scholar
  41. 38.
    McNew, G. L., and O. L. Hoffman: Growth regulant, herbicidal and physical properties of 2,4-D and related compounds. Iowa State College J. Sci. 24, 189 (1950).Google Scholar
  42. 39.
    Minark, C. E.: Pre-emergence herbicides and their behaviour. Proc. NE Weed Control Conf. 5 (Suppl.), 29(1951).Google Scholar
  43. 40.
    Neal, P. A., V. Oettinger, W. F. Smith, W. W. Malmo, R. B. Dunn, R.C. Moran, H. H.Swezey, T. R. Armstrong, and W. C. White: Toxicity and potential dangers of aerosols, mists, and dusting powder containing DDT. U. S. Public Health Service, Reports Suppl. 177(1944).Google Scholar
  44. 41.
    Nex, R. W., and A. W. Swezey: Some chemical and physical properties of weed killers. Weeds 3, 241 (1954).CrossRefGoogle Scholar
  45. 42.
    Orlovsky, V. M.: Maximum permissible concentration of chlorocyclohexane in water basins. Gigiena i Sanit. 27, 24 (1962).Google Scholar
  46. 43.
    Peck, D. R.: Alkali stability of the insecticide E. 605. Chem. & Ind. 33, 526 (1948).Google Scholar
  47. 43a.
    De Pietri-Tonelli, P.: Personal communication (Feb. 28, 1967 ), Montecatini Edison, Milano.Google Scholar
  48. 44.
    Reynolds, H. T., and R. L. Metcalf: Effect of water solubility and soil moisture upon plant uptake of granulated systemic insecticides. J. Econ. Entomol. 55, 2 (1962).Google Scholar
  49. 45.
    Richard, A. G., and L. K. Cutkomp: Correlation between the possession of a chitinous cuticle and sensitivity to DDT. Biol. Bull. 90, 97 (1946).CrossRefGoogle Scholar
  50. 46.
    Richardson, L. T., and D. M. Miller: Fungitoxicity of chlorinated hydrocarbon insecticides in relation to water solubility and vapour pressure. Canad. J. Bot. 38, 163 (1960).CrossRefGoogle Scholar
  51. 47.
    Roeder, K. D., and E. A. Weiant: The site of action of DDT in the cockroach. Science 103, 304 (1946).CrossRefGoogle Scholar
  52. 48.
    Rohm & Haas Company:Tolerances and uses of Rohm & Haas agricultural chemicals (Apr. 1966).Google Scholar
  53. 49.
    Sazonov, P. V., A. A. Bogdarina, and A. S. Gudkova: Biological activity of aqueous solutions of DDT and HCH. Trudy Vsesoyuz Inst. Zashchity Rastenu 7, 128 (1956).Google Scholar
  54. 50.
    Shell Chemical Company:Summary of basic data for: Technical aldrin insecticide, Tech. Bull. SC: 59–45; AQUALIN Herbicide Tech. Bull. SC-60; AZODRIN insecticide Tech. Bull. ACD 65–151; Technical BIDRIN insecticide, Tech. Bull. ACD: 62–2R; Technical CIODRIN insecticide, Tech. Bull. ACD: 62–1; D-D soil fumigant, Tech. Bull. SC: 60–107; Technical dieldrin insecticide, Tech. Bull. SC: 60–102; Technical endrin insecticide, Tech. Bull. SC: 60–103R; NEMAGON C nematocide, Tech. Bull. ACD: 63–102; Methyl parathion insecticide, Tech. Bull. SC: 60–105; PHOSDRIN insecticide, Tech. Bull.; VAPONA insecticide, Tech. Bull. SC: 61–76.Google Scholar
  55. 51.
    Slade, R. E.: The gamma isomer of hexachlorocyclohexane (Gammexane). Chem. & Ind. 40, 314 (1945).Google Scholar
  56. 52.
    Snyder, J. A.: Studies on Warfarin, Dicumarol and, Cyclocumarol. Ph.D. thesis, Univ. of Wisc., Madison, Wisc. (1953).Google Scholar
  57. 53.
    Spiller, D.: A digest of available information on the insecticide malathion. Adv. Pest Control Research 4, 249 (1961).Google Scholar
  58. 54.
    Stauffer Chemical Company:Personal communication (Apr. 1966).Google Scholar
  59. 55.
    Swezey, A. W., and R. W. Nex: Some chemical and physical properties of weed killers. Suppl. I. Weeds 9, 209 (1961).CrossRefGoogle Scholar
  60. 55a.
    The Merck Index, 7th ed. Merck & Co. Inc., Rahway, N. J. (1960).Google Scholar
  61. 56.
    Thompson Hayward Chemical Company: Personal communication (Apr. 1966). 56a. Union Carbide: Technical information on TEMIK and Glyodin (1966).Google Scholar
  62. 57.
    Vineland Chemical Company: SMA-DMA weed control (Apr. 1966).Google Scholar
  63. 57a.
    W. A. Cleary Corporation: Personal communication (Apr. 1966).Google Scholar
  64. 58.
    Weed Control Handbook: Properties of herbicides, 3rd ed., p. 286. E. K. Wooford and S. A. Evans, ed. Oxford: Blackwell Scientific (1963).Google Scholar
  65. 59.
    West, T. F., and G. A. Campbell: DDT and newer persistent insecticides, 2nd ed. rev. London: Chapman & Hall (1952).Google Scholar
  66. 60.
    William, G. F.: Properties of 0,0-diethyl-O-p-nitrophenyl thiophosphate and 0,0-diethyl O-p-nitrophenylphosphate. Ind. Eng. Chem. 43, 950 (1951).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag New York Inc. 1968

Authors and Affiliations

  • F. A. Gunther
    • 1
  • W. E. Westlake
    • 1
  • P. S. Jaglan
    • 1
  1. 1.Department of EntomologyUniversity of California Citrus Research Center and Agricultural Experiment StationRiversideUSA

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