Advertisement

Thin-layer chromatography in the determination of pesticide residues

  • Robert A. Conkin
Conference paper
Part of the Residue Reviews / Rückstands-Berichte book series (RECT, volume 6)

Abstract

Chromatography, in its many forms, has provided the residue chemist with one of the most significant techniques for the separation and subsequent identification of pesticide residues. The growing need for general but systematic analytical procedures for the detection of several pesticides has been largely fulfilled by the introduction of chromatographic techniques.

Keywords

Pesticide Residue Silicic Acid Iodine Vapor Methyl Parathion Solvent Front 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Anwar, M. H.: Separation of plant pigments by thin-layer chromatography. J. Chem. Ed. 40, 29 (1963).CrossRefGoogle Scholar
  2. Applewhite, T. H., M. J. Diamond, and L. A. Goldblatt: Chromatostrip analysis of fatty acid derivatives. J. Amer. Oil Chemists ’ Soc. 38, 609 (1961).CrossRefGoogle Scholar
  3. Averell, P. R., and M. V. Norris: Estimation of small amounts of O,O-diethyl-O-p-nitrophenyl thiophosphate. Anal. Chem. 20, 753 (1948).CrossRefGoogle Scholar
  4. Bäumler, J., and S. Rippstein: Dünnschichtchromatographischer Nachweis von Insektiziden. Helv. Chim. Acta 44, 1162 (1961).CrossRefGoogle Scholar
  5. Bedersky, I.: Spray technique for the preparation of thin-layer chromatography plates. Anal. Chem. 35, 261 (1963).CrossRefGoogle Scholar
  6. Beroza, M.: Identification of 3, 4-methylenedioxyphenyl synergists by thin-layer chromatography. J. Agr. Food Chem. 11, 51 (1963).CrossRefGoogle Scholar
  7. Blinn, R. C., and F. A. Gunther: Procedure for distinguishing compound OW-9 residues from Aramite residues on citrus fruits. J. Assoc. Official Agr. Chemists 46, 204 (1963).Google Scholar
  8. Cassil, C. C.: Pesticide residue analysis by microcoulometric gas chromatography. Residue Reviews 1, 37 (1962).Google Scholar
  9. Cook, J. W., and R. Ottes: Note on the conversion of some organophosphate pesticides to less polar compounds by ultraviolet light. J. Assoc. Official Agr. Chemists 42, 211 (1959).Google Scholar
  10. Coulson, D. M.: Gas chromatography of pesticides. Adv. Pest Control Research 5, 153 (1962).Google Scholar
  11. Davies, B. H.: A simple saturation chamber for thin-layer chromatography. J. Chromatography 10, 518 (1963).CrossRefGoogle Scholar
  12. Demole, E.: Application de la microchromatographie d’adsorption sur couches minces. J. Chromatography 1, 24 (1958).CrossRefGoogle Scholar
  13. Demole, E.: Progrès récents de la microchromatographie sur couches minces. J. Chromatography 6, 2 (1961).CrossRefGoogle Scholar
  14. Duncan, G. R.: The transfer of chromatoplate resolutions to large scale separations on adsorption columns. A new apparatus for producing thin layers. J. Chromatography 8, 37 (1962).CrossRefGoogle Scholar
  15. Eneroth, P.: Thin-layer chromatography of bile acids. J. Lipid Research 4, 11 (1963).Google Scholar
  16. Fischer, R., and W. Klingelholler: Der Nachweis und die quantitative Bestimmung von Thiophosphorsâureestern in biologisdiem Material. Arch. Toxikol. 19, 119 (1961).CrossRefGoogle Scholar
  17. Gajan, R. J.: Application of polarography for the detection and determination of pesticides and their residues. Residue Reviews 5, 80 (1964).PubMedGoogle Scholar
  18. Gajan, R. J.: Recent developments in the detection and determination of pesticides and their residues by oscillographic polarography. Residues Reviews 6, 75 (1964).Google Scholar
  19. Gaston, L.: Personal communication.Google Scholar
  20. Getz, M. E.: A cleanup method and paper chromatographic procedure for the identification of six phosphate pesticide residues in green leafy vegetables. J. Assoc. Official Agr. Chemists 45, 393 (1962).Google Scholar
  21. Getz, M. E.: The determination of organophosphate pesticides and their residues by paper chromatography. Residue Reviews 2, 9 (1963).PubMedGoogle Scholar
  22. Guinn, V. P., and R. A. Schmitt: Determination of pesticide residues in foods by instrumental neutron activation analysis. Residue Reviews 5, 148 (1964).PubMedGoogle Scholar
  23. Hansbury, E. D., G. Ott, and J. D. Perrings: Thin-layer chromatography apparatus. J. Chem. Ed. 40, 31 (1963).CrossRefGoogle Scholar
  24. Kirchner, J. G., J. M. Miller, and R. G. Rice: Quantitative determination of biphenyl in citrus fruits and fruit products by means of chromatostrips. J. Agr. Food Chem. 2, 1031 (1954).CrossRefGoogle Scholar
  25. Kirchner, J. G., J. M. Miller, and G. J. Keller: Separation and identification of some terpenes by a new chromatographic technique. Anal. Chem. 23, 420 (1951).CrossRefGoogle Scholar
  26. Lederer, E., and M. Lederer: Chromatography. 2 ed. New York: Elsevier 1957.Google Scholar
  27. Mangold, H. K.: Thin-layer chromatography of lipids. J. Amer. Oil Chemists ’ Soc. 38, 708 (1961).CrossRefGoogle Scholar
  28. Mangold, H. K., and R. Kammereck: New methods of analyzing industrial lipids. J. Amer. Oil Chemists ’ Soc. 39, 201 (1962).CrossRefGoogle Scholar
  29. Martens, P. H., and P. Nangniot: La determination de résidus d’insecticides et de fongicides par la méthode polarographique. Residue Reviews 2, 26 (1963).Google Scholar
  30. Metcalf, R. L., and R. B. March: Reversed phase paper chromatography of parathion and related phosphate esters. Science 117, 527 (1953).PubMedCrossRefGoogle Scholar
  31. Miller, J. M., and J. G. Kirchner: Apparatus for the preparation of chromatostrips. Anal. Chem. 26, 2002 (1954).Google Scholar
  32. Mills, P. A.: Detection and semiquantitative estimation of chlorinated organic pesticide residues in foods by paper chromatography. J. Assoc. Official Agr. Chemists 42, 734 (1959).Google Scholar
  33. Moats, W. A.: One-step chromatographic cleanup of chlorinated hydrocarbon pesticide residues in butterfat. I. Chromatography on silicic acid. J. Assoc. Official Agr. Chemists 45, 355 (1962).Google Scholar
  34. Moffitt, R. A., W. Meckler, and B. Burger: Improvements in paper chromatographic technique for pesticide determinations. J. Assoc. Official Agr. Chemists 44, 795 (1961).Google Scholar
  35. Rollins, C.: Thin-layer chromatographic separation of leaf pigments. J. Chem. Ed. 40, 32 (1963).CrossRefGoogle Scholar
  36. Stahl, E.: Dünnsshicht-Chromatographie. Berlin-Gôttingen-Heidelberg: Springer-Verlag 1962.Google Scholar
  37. Suryaraman, M. G., and W. T. Cave: Personal communication.Google Scholar
  38. Walker, K. C., and M. Beroza: Thin-layer chromatography for insecticide analysis. J. Assoc. Official Agr. Chemists 46, 250 (1963).Google Scholar
  39. Wasicky, R.: Thin-layer chromatography on microslides. Anal. Chem. 34, 1346 (1962).CrossRefGoogle Scholar
  40. Watts, J. O., and A. K. Klein: Determination of chlorinated pesticide residues by electron-capture gas chromatography. J. Assoc. Official Agr. Chemists 45, 102 (1962).Google Scholar
  41. Woolish, E. G., M. Schmall, and M. Hawrylyshyn: Thin-layer chromatography. Recent developments in equipment and applications. Anal. Chem. 33, 1138 (1961).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag OHG · Berlin · Göttingen · Heidelberg 1964

Authors and Affiliations

  • Robert A. Conkin
    • 1
  1. 1.Agricultural DivisionMonsanto Chemical CompanySt. Louis 66USA

Personalised recommendations