Skip to main content
SpringerLink
Log in

The determination of organophosphate pesticides and their residues by paper chromatography

  • Conference paper
Residue Reviews / Rückstands-Berichte

Part of the book series: Reviews of Environmental Contamination and Toxicology ((RECT,volume 2))

Abstract

Determining the type and amount of organophosphate pesticide residue in food products is a complex problem, and one which concerns both the companies which manufacture the pesticides and the Governmental agencies which enforce their proper use.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Acree, F., jr., F.H. Babers, and N. Mitlin: Preparation of P32-labeled Bayer L 13/59 and COLP, and their absorption and translocation in the American cockroach. J. Econ. Entomol. 49, 808 (1956).

    CAS  Google Scholar 

  • Block, R., E.L. Durrum, and G. Zweig: A Manual of Paper Chromatography and Paper Electrophoresis. 2ed New York: Academic Press 1958.

    Google Scholar 

  • Bowman, J.S., and J.E. Casida: Metabolism of the systemic insecticide O,O-diethyl-S-ethyl-thiono ethyl phosphorodithioate (Thimet) in plants. J. Agr. Food Chem. 5, 192 (1957).

    Article  CAS  Google Scholar 

  • Cook, J.W.: In vitro destruction of some organophosphate pesticides by bovine rumen fluid. J. Agr. Food Chem. 5, 859 (1957).

    Article  CAS  Google Scholar 

  • Cook, J.W.: Paper chromatography of some organic phosphate insecticides. I. New spot test. J. Assoc. Official Agr. Chemists 37, 984 (1954).

    CAS  Google Scholar 

  • Cook, J.W.: Paper chromatography of some organic phosphate insecticides. II. Separation and identification. J. Assoc. Official Agr. Chemists 37, 987 (1954).

    CAS  Google Scholar 

  • Cook, J.W.: Paper chromatography of some organic phosphate insecticides. III. Effects of light on systox and isosystox. J. Assoc. Official Agr. Chemists 37, 989 (1954).

    CAS  Google Scholar 

  • Cook, J.W.: Paper chromatography of some organic phosphate insecticides. IV. Spot test for in vitro Cholinesterase inhibitors. J. Assoc. Official Agr. Chemists 38, 150 (1955).

    CAS  Google Scholar 

  • Cook, J.W., J.R. Blake, G. Yip, and M. Williams: Malathionase. I. Activity and inhibition. J. Assoc. Official Agr. Chemists 41, 399 (1958).

    CAS  Google Scholar 

  • Cook, J.W., and R. Ottes: Nate on the conversion of some organophosphate pesticides to less polar compounds by ultraviolet light. J. Assoc. Official Agr. Chemists 42 (1959).

    Google Scholar 

  • Cook, J.W., and G. Yip: Malathionase. II. Identity of malathion metabolite. J. Assoc. Official Agr. Chemists 41, 407 (1958).

    CAS  Google Scholar 

  • Fiori, A.: Isolation and identification of parathion in biological material. Nature 178, 423 (1956).

    Article  PubMed  CAS  Google Scholar 

  • Fukuto, T.R., J.P., III Wolfe, R.L. Metcalf, and R.B. March: Plant metabolism of the thiol isomer of Systox. J. Econ. Entomol. 49, 147 (1956).

    CAS  Google Scholar 

  • Fukuto, T.R., J.P., III Wolfe, R.L. Metcalf, and R.B. March: Identification of the sulfone plant metabolite of the thiono isomer of Systox. J. Econ. Entomol. 50, 399 (1957).

    CAS  Google Scholar 

  • Getz, M.E.: A cleanup method and paper chromatographic procedure for the identification of six phosphate pesticide residues in green leafy vegetables. J. Assoc. Official Agr. Chemists 45, 393 (1962).

    CAS  Google Scholar 

  • Getz, M.E.: A study of the degradation esters of Systox, Di-Syston, and Thimet on field-sprayed kale. J. Assoc. Official Agr. Chemists 45, 397 (1962).

    CAS  Google Scholar 

  • Hais, I.M., and K. Macek: Handbuch der Papierchromatographie: Band I. Jena: Gustav Fischer 1958.

    Google Scholar 

  • Hanes, C.S., and F.A. Isherwood: Separation of the phosphoric esters on the filter paper chromatogram. Nature 164, 1107 (1949).

    Article  PubMed  CAS  Google Scholar 

  • Kaplanis, J.N., W.E. Robbins, D.I. Darrow, D.E. Hopkins, R.E. Monroe, and G. Treiber: The metabolism of Dimethoate in cattle. J. Econ. Entomol. 52, 1190 (1959).

    CAS  Google Scholar 

  • Lederer, E., and M. Lederer: Chromatography. 2ed New York: Elsevier 1957.

    Google Scholar 

  • McKinley, W.P., and S.I. Read: Esterase inhibition technique for the detection of organophosphorus pesticides. J. Assoc. Official Agr. Chemists 45, 467 (1962).

    CAS  Google Scholar 

  • MacRae, H.R., and W.P. McKinley: Chromatographic identification of some organophosphate insecticides. J. Assoc. Official Agr. Chemists 44, 207 (1961).

    CAS  Google Scholar 

  • MacRae, H.R., and W.P. McKinley: A cleanup procedure for the chromatographic identification of some organophosphate insecticides. Presented at the 140th Meeting, Amer. Chem. Soc., Chicago, September 6, 1961.

    Google Scholar 

  • March, R.B., R.L. Metcalf, and T.R. Fukuto: Paper chromatography of the systemic insecticides demeton and schradan. J. Agr. Food Chem. 2, 732 (1954).

    Article  CAS  Google Scholar 

  • March, R.B., T.R. Fukuto, R.L. Metcalf, and M.G. Maxon: Fate of P32-labeled malathion in the laying hen, white mouse, and American cockroach. J. Econ. Entomol. 49, 185 (1956).

    CAS  Google Scholar 

  • Menn, J.J., W.R. Erwin, and H.T. Gordon: Color reactions of 2,6-dibromo-N-chloro-p-quinoneimine with thiophosphate insecticides on paper chromatograms. J. Agr. Food Chem. 5, 601 (1957).

    Article  CAS  Google Scholar 

  • Metcalf, R.L., and R.B. March: Reversed phase paper chromatography of parathion and related phosphate esters. Science 117, 527 (1953).

    Article  PubMed  CAS  Google Scholar 

  • Metcalf, R.L., and R.B. March, T.R. Fukuto, and M.G. Maxon: The nature and significance of Systox residues in plant materials. J. Econ. Entomol. 48, 364 (1955).

    CAS  Google Scholar 

  • Metcalf, R.L., T.R. Fukuto, and R.B. March: Plant metabolism of Dithio-Systox and Thimet. J. Econ. Entomol. 50, 338 (1957).

    CAS  Google Scholar 

  • Mitchell, L.C.: Ascending chromatography: A way to do it. J. Assoc. Official Agr. Chemists 40, 999 (1957).

    CAS  Google Scholar 

  • Mitchell, L.C.: Separation and identification of eleven organophosphate pesticides by paper chromatography: Delnav, EPN, Guthion, malathion, methyl-parathion, parathion, Phosdrin, Ronnel, Systox, and Trithion. J. Assoc. Official Agr. Chemists 43, 810 (1961).

    Google Scholar 

  • Moddes, R., and J.W. Cook: The extraction and identification of parathion and Diazinon. J. Assoc. Official Agr. Chemists 42, 208 (1958).

    Google Scholar 

  • Murakami, A.: Studies on organic phosphorus malathion. Japanese J. Legal Med. 13, 175 (1959).

    Google Scholar 

  • Müller, R., G. Ernst, and H. Schock: Der Nachweis von Insekticidrückständen auf Pflanzenmaterial (Gemüse und Früchte) und die Trennung einzelner Schädlingsbekämpfungsmittel mit Hilfe der Papierchromatographie. Mitt. Gebiete Lebensm. u. Hyg. 48, 152 (1957).

    Google Scholar 

  • O’brien, R.D., G.D. Thorn, and R.W. Fisher: New organophosphate insecticides developed on rational principles. J. Econ. Entomol. 51, 714 (1958).

    Google Scholar 

  • Otter, I.K.H.: A general method for locating the spots on a paper chromatogram of tertiary alkyl phosphates, thiolophosphates and thionophosphates. Nature 176, 1078 (1955).

    Article  CAS  Google Scholar 

  • Plapp, F.W., jr., W.S. Bigley, and D.I. Darrow: Studies on the metabolism and residues of P32-labeled Delnav in a Hereford steer, J. Econ. Entomol. 53, 60 (1960).

    CAS  Google Scholar 

  • Robbins, W.E., T.L. Hopkins, and G.W. Eddy: The metabolism of P32-labeled L 13/59 in a cow. J. Econ. Entomol. 49, 801 (1956).

    CAS  Google Scholar 

  • Robbins, W.E., T.L. Hopkins, and G.W. Eddy: Metabolism and excretion of phosphorus-32 labeled Diazinon in a cow. J. Agr. Food Chem. 5, 509 (1957).

    Article  CAS  Google Scholar 

  • Robbins, W.E., T.L. Hopkins, D.I. Darrow, and G.W. Eddy: Studies with P32-labeled Bayer 21/199 sprayed on cattle. J. Econ. Entomol. 52, 214 (1959).

    CAS  Google Scholar 

  • Santi, R.: Penetrazione, translocazione e metabolismo del Rogor-P32-applicato sul tronco di piante di limone. Montecatini, Società Generale per l’Industria Minerarai e Chimica, Milano 1961.

    Google Scholar 

  • Shishido, T., and M. Suwanai: Chromatography of organic insecticides. Part 1. Separation of insecticides on phenylcellosolve-treated paper. J. Agr. Chem. Soc. Japan 32, 956 (1958).

    CAS  Google Scholar 

  • Smith, I.: Chromatographic Techniques. New York: Interscience 1958.

    Google Scholar 

  • Wood, T.: A reagent for the detection of chloride and of certain purines and pyrimidines on paper chromatograms. Nature 176, 175 (1955).

    Article  PubMed  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Division of Food, Food and Drug Administration, U.S. Department of Health, Education and Welfare, Washington 25, D.C., USA

    Melvin E. Getz

Authors
  1. Melvin E. Getz
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Riverside, USA

    Francis A. Gunther

Rights and permissions

Reprints and permissions

Copyright information

© 1963 Springer-Verlag OHG Berlin · Göttingen · Heidelberg

About this paper

Cite this paper

Getz, M.E. (1963). The determination of organophosphate pesticides and their residues by paper chromatography. In: Gunther, F.A. (eds) Residue Reviews / Rückstands-Berichte. Reviews of Environmental Contamination and Toxicology, vol 2. Springer, New York, NY. https://doi.org/10.1007/978-1-4615-8374-5_2

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-8374-5_2

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4615-8376-9

  • Online ISBN: 978-1-4615-8374-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation