Abstract
In Chapters 3, 4, and 5, we have discussed extensively the detailed thermodynamic aspects of the adsorption of solute and solvent at the interface formed by the contact of either liquid-gas or liquid-liquid phases. The surfaces in all these cases are regarded as homogeneous across the plane of contact, although perpendicular to the surface plane the surface phase is considered as inhomogeneous. Surface free energy (or interfacial tension) in such systems involving liquid interface can be accurately measured in the presence of solute component in the bulk solution so that excess adsorption at the interface can be calculated using the Gibbs adsorption equation.
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References
J. J. Kipling, Adsorption from Solutions of Nonelectrolytes ( Academic Press, London, 1965 ).
D. H. Everett, Colloid Science, Vol. 1, edited by D. H. Everett ( The Chemical Society, London, 1973 ), p. 49.
C. E. Brown and D. H. Everett, Colloid Science, Vol. 2, edited by D. H. Everett (The Chemical Society, London, 1975 ), p. 52.
A. W. Adamson, Physical Chemistry of Surfaces, 3 Edition (John Wiley & Sons, New York, 1976 ), p. 385.
K. L. Mittal, Adsorption at Interfaces, ACS Symposium Series, No. 8 ( American Chemical Society, Washington D.C., 1975 ).
R. Chatterjee and D. K. Chattoraj, Indian J. Biochem. Biophys., 16, 158 (1979).
G. Schay, Surface and Colloid Science, Vol. 2, edited by E. Matijevic ( Wiley-Interscience, New York, 1969 ), p. 155.
G. D. Parfitt and P. C. Thompson, Trans. Faraday Soc., 67, 3371 (1971).
L. G. Nagy and G. Schay, Magyr. Kern Folyoirat, 66, 31 (1960).
G. Schay and L. G. Nagy, Peridica Polytechn. Budapest, 4, 45 (1960).
G. Schay and L. G. Nagy, J. Chim. Phys., 149 (1961).
I. Dckany, F. Szanto, L. G. Nagy, and G. Foti, J. Colloid Interface Sci., 50, 265 (1975).
I. Dekany, L. G. Nagy, and G. Schay, J. Colloid Interface Sci., 66, 197 (1978).
R. Defay and I. Prigogine, Trans. Faraday Soc., 46, 199 (1950).
S. Ono and S. Kondo, in Handbuch der Physik, edited by S. Flugge ( Springer, Berlin, 1960 ), Vol. 1, p. 134.
A. M. Williams, Medd K. Vetenskapsalead Nobelinst, 2, No. 27 (1913).
J. J. Kipling and D. A. Tester, J. Chem. Soc., 4123, 1952.
A. Blackburn and J. J. Kipling, J. Chem. Soc., 1493, 1955.
F. G. Tryhorn and W. F. Wyatt, Trans. Faraday Soc., 21, 1925 (1925).
D. C. Jones and L. Outridge, J. Chem. Soc., 1574, 1930.
M. R. A. Rao, J. Indian Chem. Soc., 12, 345 (1993)
D. H. Everett, Trans. Faraday Soc., 60, 1803 (1964).
D. H. Everett, Trans. Faraday Soc., 61, 2478 ( 1965
S. G. Ash, D. H. Everett, and G. H. Findenegg, Trans. Faraday Soc., 66, 708, 1970.
C. Orr and J. M. Dallaville, Fine Particle Measurement, Size, Surface and Pore Volume, pp. 207–215 (The MacMillan Company, New York, 1959 ).
Somasundaran and Fuerstenau, J. Phys. Chem., 68, 3562 (1964).
S. P. Mitra and D. K. Chattoraj, Indian J. Biochem. Biophys., 15, 147 (1978).
J. J. Kipling and E. H. M. Wright, J. Chem. Soc., 855 (1962).
P. V. Cornford, J. J. Kipling, and E. H. M. Wright, Trans. Faraday Soc., 58, 74 (1962).
E. L. Cook and N. Hackerman, J. Phys. Chem., 55, 549 (1951).
G. Venturello and A. M. Ghee, Gazzetta, 89, 1181 (1959).
R. N. Smith, C. F. Geiger, and C. Pierce, J. Phys. Chem., 57, 382, 1953.
J. J. Kipling and E. H. M. Wright, J. Chem. Soc., 855 (1962).
C. H. Giles, T. H. MacEwan, S. N. Nakhwa, and D. Smith, J. Chem. Soc., 39 73 (1960).
W. B. Weiser, Colloid Chemistry ( Wiley, New York, 1950 ).
S. Voyutsky, Colloid Chemistry ( Mir Publishers, Moscow, 1978 ).
E. J. W. Verwey and J. Th. G. Overbeek, Theory of the Stability of Lyophobic Colloids ( Elsevier, New York, 1948 ).
B. N. Ghosh, S. C. Rakshit, and D. K. Chattoraj, Trans. Faraday Soc., 50, 729 (1954).
B. N. Ghosh and D. K. Chattoraj, Kolloid Z., 154, 48 (1957).
I. D. Rattee and M. M. Breuer, The Physical Chemistry of Dye Adsorption ( Academic Press, New York, 1974 ).
S. Iyer, S. R. Srinivasan, and N. T. Baddi, Textile Res. J., 38, 693 (1968).
C. H. Giles, Text. Research J., 31, 141 (1961).
S. R. S. Iyer, A. S. Chanekar, and G. Srinivasan, in Adsorption at Interfaces, edited by K. L. Mittal, ACS Symposium Series ( American Chemical Society, Washington, D.C., 1975 ).
G. R. F. Rose, A. S. Weatherburn, and C. H. Bayley, Textile Res. J., 21, 427 (1951).
M. L. Corrin, E. L. Lind, A. Roginsky, and W. D. Harkins, J. Colloid Sci., 4, 485 (1949).
A. Fava and H. Eyring, J. Phys. Chem., 60, 890 (1956).
R. D. Vold and N. H. Sivaramakrishnan, J. Phys. Chem., 62, 984 (1958).
B. Tamamushi and K. Tamaki, Proceedings of the Second International Congress of Surface Activity (Butterworths, London, 1957 ), Vol. III, p. 449.
B. Tamamushi and K. Tamaki, Trans. Faraday Soc., 55, 1007 (1959).
P. Connor and R. H. Ottewill, J. Colloid Interface Sci., 37, 595 (1964).
P. Mukerjee and A. Anavil, in Adsorption at Interfaces, edited by K. L. Mittal, ACS Sympsoim Series No. 8 ( Amer. Chem. Soc., Washington D.C., 1975), p. 107.
P. Somasundaran and D. H. Fuerstenau, J. Phys. Chem., 70, 90 (1966).
P. Somasundaran, T. W. Healy, and D. W. Fuerstenau, J. Phys. Chem., 68, 3562 (1964).
W. R. Foster, J. Petrol. Technol., February, 205 (1973).
V. K. Bansal and D. O. Shah, in Micellization, Solubilization and Micro-emulsions, Vol. 1, edited by K. L. Mittal ( Plenum Press, New York, 1977 ).
M. S. French, G. W. Keys, G. L. Stegemeier, R. C. Uber, A. Abrams, and H. J. Hill, J. Petrol. Technol., February, 195 (1973).
F. J. Trogus, R. S. Schechter, and W. H. Wade, J. Colloid Interface Sci., 70, 293 (1979).
R. Ulman, J. Koral, and F. R. Eirich, Proc. Intern. Cong. Surface Activity, 2nd, London, 1957, Vol. III, p. 485.
F. Rowland, R. Bulas, E. Rothstein, and F. R. Eirich, Ind. Eng. Chem., September 1965, p. 46.
S. G. Ash, in Colloid Science, Vol. 1, edited by D. H. Everett ( The Chemical Society, London, 1973 ), p. 103.
V. K. Dunn and R. D. Vold, Adsorption at Interfaces, edited by K. L. Mittal, ACS Symposium Series No. 8 (Amer. Chem. Soc., Washington, D.C., 1975 ), p. 96.
F. S. Chan, P. S. Minhas, and A. A. Robertson, J. Colloid Interface Sci., 33, 586 (1970).
F. R. Eirich, R. Bulas, E. Rothstein, and F. Rowland, in Chemistry and Physics of Interfaces, edited by D. E. Guestve, p. 109 ( American Chemical Society, Washington, D.C., 1965 ).
R. Ulman, J. Koral, and F. R. Eirich, Proc. International Congress of Surface Activity, 2nd, London, Vol. III, p. 485 (1957).
W. Heller, Pure Appl. Chem., 12, 249 (1966).
B. J. Fontana and J. R. Thomas, J. Phys. Chem., 65, 480 (1961).
R. Simha, H. L. Frisch, and F. R. Eirich, J. Phys. Chem., 57, 584 (1953).
H. L. Frisch and R. Simha, J. Phys. Chem., 58, 507 (1954).
H. L. Frisch, J. Phys. Chem., 59, 633 (1955).
H. L. Frisch, M. Y. Hellman, and J. L. Lundberg, J. Polymer Sci., 38, 441 (1959).
A. Silberberg, J. Phys. Chem., 66, 1872 (1962).
A. Silberberg, J. Chem. Phys., 48, 2835 (1968).
A. Silberberg, J. Colloid Interface Sci., 38, 217 (1972).
C. A. Hoeve, E. A. Dimarzio, and P. Peyser, J. Chem. Phys., 42, 2558 (1965).
C. A. Hoeve, J. Polym. Sci., 34, 1 (1971).
S. G. Ash, D. Everett, and G. H. Findenegg, Trans. Faraday Soc., 66, 708 (1970).
J. M. Anderson, Nature Lond., 253, 536 (1975).
B. Pesosac and V. Defendi, Science, 175, 898 (1972).
H. P. Schneble and M. M. Burger, Proc. Nat. Acad. Sci., USA, 69, 3825 (1972).
G. Stoner and S. Srinivasan, J. Phys. Chem., 74, 1088 (1970).
J. L. Brash and D. J. Lyman, The Chemistry of Biosurfaces, edited by M. L. Hair, p. 1977 ( Marcel Dekker, New York, 1971 ).
J. M. Singer, Bull. Rheum. Dis., 24, 762 (1974).
Y. Kobayashi and S. Aomine, Soil Sci. Pl. Nutr., 13, 189 (1967).
G. R. Stark, edited, Biochemical Aspects of Reactions on Solid Supports ( Academic Press, New York, 1971 ).
H. B. Bull, Biochim. Biophys. Acta, 19, 464 (1956).
H. B. Bull, Arch. Biochem. Biophys., 68, 102 (1957).
D. K. Chattoraj and H. B. Bull, J. Amer. Chem. Soc., 81, 5128 (1959).
I. R. Miller and D. Bach, Surface and Colloid Science, Vol. 6, edited by E. Matijevic ( Wiley Interscience, New York, 1973 ).
W. J. Dilman and I. R. Miller, J. Colloid Interface Sci., 44, 221 (1973).
B. W. Morrissey and R. R. Stromberg, J. Colloid Interface Sci., 44, 221 (1974).
S. P. Mitra and D. K. Chattoraj, Indian J. Biochem. Biophys., 15, 147 (1978).
V. Hlady and H. Furedi-Milhofer, J. Colloid Interface Sci., 69, 460 (1979).
W. Norde and J. Lyklema, J. Colloid Interface Sci., 71, 350 (1979).
W. Norde and J. Lyklema, J. Colloid Interface Sci., 66, 257, 266, 277, 285, 295 (1978).
W. Norde, “Proteins at Interface,” doctoral thesis (1976), Agricultural University, Wageningen, The Netherlands.
S. P. Mitra and D. K. Chattoraj, Indian J. Biochem. Biophys., 15, 147 (1978).
C. L. Riddiford and B. R. Jennings, Biochim. Biophys. Acta, 126, 71 (1966).
D. Lang and M. Mitani, Biopolymers, 9, 373 (1970).
A. K. Kleinschmidt, Biochim. Biophys. Acta, 61, 857 (1962).
J. D. Watson, Molecular Biology of the Gene, 3 Edition (W. A. Watson, Benzamin Inc., Menlo Park, California, 1977 ), p. 246.
I. R. Miller, J. Mol. Biol., 3, 229, 357 (1961).
I. R. Miller, Biochim Biophys. Acta, 103, 219 (1965).
M. A. Frommer and I. R. Miller, J. Phys. Chem., 72, 2862 (1968).
D. K. Chattoraj, P. Chowrashi, and K. Chakravarti, Biopolymers, 5, 173 (1967).
P. Chowrashi, D. K. Chattoraj, and K. Chakravarti, Biopolymers, 6, 97 (1968).
M. A. Frommer and I. R. Miller, J. Colloid Interface Sci., 21, 245 (1966).
S. N. Upadhyay and D. K. Chattoraj, Biochim. Biophys. Acta, 161, 561 (1968).
D. J. Crisp, J. Colloid Sci., 11, 356 (1956).
S. G. Daniel, Trans. Faraday Soc., 47, 1345 (1951).
H. B. Bull, An Introduction to Physical Biochemistry (F. A. Davis Co., Philadelphia).
H. Freundlich, Colloid and Capillary Chemistry ( Methuen, London, 1926 ).
D. C. Henry, Phil Mag., 44 (6), 689 (1922).
J. Oscik, A. Dabrowski, M. Jaronec, and W. Rudzinski, J. Colloid Interface Sci., 56, 403 (1976).
J. Oscik, A. Dabrowski, and W. Rudzinski, Colloid Polymer Sci., 255, 50 (1977).
B. Chopra and V. Ramakrishna, Indian J. Chem., 10, 187 (1972).
M. T. Coltrap and N. Hackerman, J. Colloid Interface Sci., 43, 185 (1976).
B. R. Puri, O. P. Mahajan, and B. C. Kaistha, Indian J. Chem., 12, 161 (1974).
S. Sircar and A. L. Myers, AI ChE J., 19, 159 (1973).
A. Dabrowski, J. Oscik, W. Rudzinski, and M. Jaroniec, J. Colloid Interface Sci., 69, 287 (1979).
M. Borowko, M. Jaroniec, J. Oscik, and R. Kusak, J. Colloid Interface Sci., 69, 311 (1979).
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Chattoraj, D.K., Birdi, K.S. (1984). Adsorption at Solid-Liquid Interfaces. In: Adsorption and the Gibbs Surface Excess. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8333-2_8
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DOI: https://doi.org/10.1007/978-1-4615-8333-2_8
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