Skip to main content

Abstract

Adsorption at various types of interfaces will take place when a liquid phase is in contact with another immiscible phase which may be solid, liquid, or gas. For adsorption to occur in excess, one or both of the phases should contain more than one component. Two immiscible bulk phases must be in contact with each other so that some of these components are accumulated in excess at the interfacial region and the process of transfer of the component from the bulk to the surface will continue until a state of adsorption equilibrium is reached. The component which is preferentially accumulated at the interface is frequently termed an adsorbate. The term adsorbent is also used for the powdered solid on the surface of which adsorbates from the liquid phase are accumulated in excess. The types of the interfaces are usually designated by names of the bulk phases in contact with each other such as air-water, benzene-water, mercury-water, or alumina-water interfaces.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. A. W. Adamson, Physical Chemistry of Surfaces, 3 Edition (John Wiley & Sons, New York, 1976 ).

    Google Scholar 

  2. N. D. Parkyns and K. S. W. Sing, Colloid Science, Vol. 2 edited by D. H. Everett (The Chemical Society, London, 1975 ), p. 1.

    Chapter  Google Scholar 

  3. J. W. Gibbs, The Collected Works of J. W. Gibbs, Vol. 1 ( Longmans, Green, New York, 1931 ).

    Google Scholar 

  4. C. Tanford, The Hydrophobic Effect, 2 Edition (John Wiley & Sons, New York, 1980).

    Google Scholar 

  5. K. L. Mittal and P. Mukherjee, in Micellization, Solubilization and Microemulsions, Volume 1, edited by K. L. Mittal ( Plenum Press, New York, 1977 ), p. 1.

    Chapter  Google Scholar 

  6. R. H. Haschemeyer and A. E. V. Haschemeyer; Proteins ( John Wiley and Sons, New York, 1973 ).

    Google Scholar 

  7. J. W. Watson, Molecular Biology of Genes, 3 Edition (W. A. Benjamin, Inc., Menlo Park, California, 1977 ).

    Google Scholar 

  8. L. Pauling and R. B. Corey, Proc. Natl. Acad. Sci. U.S.A., 37, 251, 729 (1951).

    Article  CAS  Google Scholar 

  9. L. Pauling, R. B. Corey, and H. R. Branson, Proc. Natl. Acad. Sci. U.S.A., 37, 205 (1951).

    Article  CAS  Google Scholar 

  10. G. N. Ramachandran and V. Sasisekharan, Adv. Protein Chem., 21, 283 (1968).

    Article  Google Scholar 

  11. B. Pullman and A. Pullman, Adv. Protein Chem., 28 (1974).

    Google Scholar 

  12. C. Tanford, Adv. Protein Chem., 23, 122 (1970).

    Google Scholar 

  13. H. B. Bull, An Introduction to Physical Biochemistry, 2 Edition (F. A. Davis, Philadelphia, 1971 ), p. 237.

    Google Scholar 

  14. E. A. Guggenheim, Thermodynamics, 3 Edition (North-Holland, Amsterdam, 1957 ).

    Google Scholar 

  15. K. Denbigh, The Principles of Chemical Equilibrium, 3 Edition (Cambridge University Press, Cambridge, 1971 ).

    Google Scholar 

  16. I. M. Klotz, Chemical Thermodynamics (Prentice-Hall Inc., Englewood Cliffs, New Jersey, 1950 ).

    Google Scholar 

  17. R. Defay, I. Prigogine, and A. Bellemans, Surface Tension and Adsorption, D. H. Everett trans. (Longmans Green, London, 1966 ).

    Google Scholar 

  18. E. A. Guggenheim, Trans. Faraday Soc., 36, 398 (1940).

    Google Scholar 

  19. G. S. Schay, in Physical Chemistry: Enriching Topics from Colloid and Surface Science, edited by H. von Holphen and K. J. Mysels ( Therorex, La Jolla, California, 1975 ).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1984 Plenum Press, New York

About this chapter

Cite this chapter

Chattoraj, D.K., Birdi, K.S. (1984). Introduction. In: Adsorption and the Gibbs Surface Excess. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8333-2_1

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-8333-2_1

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-8335-6

  • Online ISBN: 978-1-4615-8333-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics