Abstract
This paper deals with the relationship between strength of adhesion and density of chemical bonding at the interface between an elastomer and a glass substrate. Reactive sites of varying surface density were obtained by treating glass plates with mixtures of vinyl and ethyl silanes in varying proportions. A layer of polybutadiene or poly(ethylene-co-propylene) containing dicumyl peroxide (DCP) was then pressed into contact with the treated glass surface and cross-linked in situ by heating to the decomposition temperature of DCP. Interfacial chemical bonding via vinyl groups (when present) in the silane-treated surface was assumed to occur simultaneously with the cross-linking reaction. Evidence for this was obtained from near-infrared spectroscopy of model systems, using finely-divided silica in place of glass.
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© 1975 Plenum Press, New York
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Ahagon, A., Gent, A.N., Hsu, E.C. (1975). On Bonding Rubber to Glass. In: Lee, LH. (eds) Adhesion Science and Technology. Polymer Science and Technology, vol 9. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8201-4_20
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DOI: https://doi.org/10.1007/978-1-4615-8201-4_20
Publisher Name: Springer, Boston, MA
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