Abstract
Thin liquid draining films of poloxamer 407 block co-polymeric surfactant solutions have been investigated using reflected laser light intensity to determine film thicknesses. Only in IM NaCl do stable thin films form. A discontinuous stepwise thinning has been found in these systems with metastable film thicknesses of, for example, 80nm and 58nm forming prior to forming a final stable film thickness of 28nm.
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References
H-G. Elias, “Polymerization of Organized Systems”. Gordon and Breach: London (1977).
C.M. Paleos, Chem.Soc.Rev., 14, 45 (1985).
L. Gros, H. Ringsdorf, and H. Schapp, Angew. Chem. Int.Ed.Eng., 20, 305 (1981).
T.K. Law, A.T. Florence, and T.L. Whateley, Colloid and Polym. Sci., 264, 167 (1986).
A.T. Florence, F. Madsen, and F. Puisieux, J.Pharm. Pharmacol., 27, 385 (1975).
D. Exerowa, M. Zachsarieva, R. Cohen, and D. Platikanov, Colloid and Polym.Sci., 257, 1089 (1979).
J.M. Corkill, J.F. Goodman, D.R. Haisman and S.P. Harrold, Trans. Faraday Soc., 57, 821 (1961).
J.S. Clunie, J.F. Goodman and B.T. Ingram in “Surface and Colloid Science”, ed. Matijevic, E., Vol. 3, Wiley-Interscience, New York, 1971, P. 167.
J. Lyklema and K.J. Mysels, J. Am.Chem.Soc., 87, 2539 (1965).
J. Lyklema, P.C. Scholten and K. Mysels, J.Phys.Chem., 69, 116 (1965).
J.M. Corkhill, J.F. Goodman and C.P. Ogden, Trans.Faraday Soc., 61, 583 (1965).
S.P. Frankel and K.J. Mysels, J.Appl.Phys., 37, 3725 (1966).
A. Scheludko, Adv. Colloid Interface Sci., 1, 391 (1967).
A. Vrij, J.E.M. Joosten and M.M. Fijnaut, Adv.Chem.Phys., 48, 329 (1981).
T.K. Law, T.L. Whateley and A.T. Florence, Int.J.Pharm., 21, 277 (1984).
idem J. Pharm. Pharmacol., 37, 6P (1985).
idem Brit. Polymer J., 18, 34 (1986).
T.K. Law, A.T. Florence, and T.L. Whateley, J.Pharm. Pharmacol., 36, 50P (1984).
J.A. Omotosho, T.K. Law, T.L. Whateley and A.T. Florence, Colloids and Surfaces 20, 133 (1986).
T.K. Law, A. T. Florence, and T.L. whateley, J.Contr.Rel., 3, 279 (1986).
M.N. Jones, K.J. Mysels, and P.C. Scholten, Trans.Faraday Soc., 62, 1336 (1966).
M.J. Schick, editor, “Nonionic Surfactants” Marcel Dekker, New York, p. 753 (1967).
A.A. Al-Saden, T.L. Whateley, and A.T. Florence, J. Colloid Interface Sci., 90, 303 (1982).
J.B. Kayes and B. Rawlins, Colloid and Polym.Sci., 257m 622 (1979).
K.N. Prasad, T.T. Luong, A.T. Florence, J. Paris, C. Vaution, M. Seiller and F. Puisieux, J.Colloid Interface Sci., 69, 225 (1979).
H.G. Bruil, and J. Lyklema, Nature, 233, 19 (1971).
S. Friberg, S.E. Linden and H. Saito, Nature, 251, 494 (1974).
J.W. Keuskamp and J. Lyklema in “Adsorption at Interfaces”, K.L. Mittal, Editor, ACS Symposium Series, No. 8, p. 191, American Chemical Society, Washington, D.C., 1975.
D.T, Wasan and A.D. Nikolov, paper presented at 6th Int. Symp. Surfactants in Solution, New Delhi, Aug. 1986.
M.A. Cohen Stuart, J.T.F. Keurentjes, B.C. Bonekamp and J.G.E.M. Fraaye, Colloids and Surfaces, 17, 91 (1986)
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© 1989 Plenum Press, New York
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Florence, A.T., Law, T.K., Whateley, T.L. (1989). Thin Films of Non-Ionic Poloxamer Surfactants: Thinning and Polymerisation of Poloxamer 407. In: Mittal, K.L. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7990-8_23
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DOI: https://doi.org/10.1007/978-1-4615-7990-8_23
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