Abstract
The fluorescence quenching method, as applied to the study of molecular organizates, particularly aqueous micelles and microemulsions, is presented. The importance of fluorescence probing, for the determination of static as well as dynamic micellar parameters, is emphasized. The fluorescence decay of a micelle-bound hydrophobic fluorophor in the presence of “immobile”,“hydrophobic mobile” and“hydrophilic mobile“ quenchers is discussed in detail. The reliability of the parameters obtained from the time-resolved fluorescence quenching method is evaluated, while on the other hand, systems in which this method must be applied with extreme caution are described. The main conclusions concerning fluorescence probing techniques and their application to micellar solutions are summarized.
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References
A. Malliaris, J. Lang and R. Zana, J. Colloid Interface Sci., 110, 237 (1986).
P. Lianos, J. Lang, J. Sturm and R. Zana, J. Phys. Chem., 88., 819 (1984).
S.S. Atik and J.K. Thomas, J. Am. Chem. Soc, 103, 4367 (1981).
E. Gelade and F.C. De Schryver, in“Reverse Micelles” P.L. Luisi and B.E. Straub, editors, p.143, Plenum Press, New York, 1984.
K.P. Ghiggino, A.J. Roberts and D. Phillips, Adv. in Polym. Sci., 40, 69 (1981).
A. Malliaris, W. Binana-Limbele and R. Zana, J. Colloid Interface Sci., 110., 114 (1986).
M. Van der Auweraer, C. Dederen, C. Palmans-Windels and F.C. De Schryver, J. Am. Chem. Soc, 104, 1800 (1982).
A. Malliaris, J. Lang and R. Zana, J. Chem. Soc., Faraday Trans. 1 82, 109 (1986).
A.M. Tachiya, Chem. Phys. Lett., 33., 289 (1975).
P.P. Infelta, M. Gratzel and J.K. Thomas, J. Phys. Chem., 78., 190 (1974).
J.C. Dederen, M. Van der Auweraer and F.C. De Schryver, Chem. Phys. Lett., 68, 451 (1979).
S. Ozeki and S. Ikeda, J. Colloid Interface Sci., 87, 424 (1982).
G. Porte and J. Appell, in“Surfactants in Solution”, K.L. Mittal and B. Lindman, editors, vol.2, pp.805-823, Plenum Press, New York, 1984.
J. Corkill, J. Goodman, T. Walker and J. Wyer, Proc. Roy. Soc. London, Ser. A 312, 243 (1969).
P. Mukerjee, J. Phys. Chem., 76, 565 (1972).
J. Israelachvili, J. Mitchell and B. Ninham, J. Chem. Soc, Faraday Trans. 2, 72, 1525 (1976).
N. Mazer, G. Benedek and M. Carey, J. Phys. Chem., 80, 1075 (1976).
S. Atik and J.K. Thomas, Chem. Phys. Lett., 79., 351(l981).
A. Malliaris, J Le Moigne, J. Sturm and R. Zana, J. Phys. Chem., 89., 2709 (1985).
R. Zana, S. Yiv, C. Strazielle and P. Lianos, J. Colloid Interface Sci., 80, 208 (1981).
E. Vikingstadt, J. Colloid Interface Sci., 73, 260 (1980).
A. Hyde and D. Stevenson, Kolloid Z.Z. Polym. 232, 797 (1969).
M.A. Chaiko, R. Nagarajan and E. Ruckenstein, J. Colloid Interface Sci., 99., 168 (1984).
H. Hoffmann, R. Nagel, G. Platz and W. Ulbricht, Colloid Polym. Sci., 102, 152 (1984).
G.E.A. Aniansson, S. Wall, M. Almgren, H. Hoffmann, I. Kielman, W. Ulbricht, R. Zana, J. Lang and C. Rendre, J. Phys.Chem., 80 905 (1981).
E. Lessner, M. Teubner and M. Kahlweit, J. Phys. Chem., 85, 3167 (1981).
M. Kahlweit, Pure Appl. Chem., 53, 2069 (1981); M. Kahlweit, J. Colloid Interface Sci., 90, 92 (1982).
J. Lang and R. Zana, J. Phys. Chem., 90., 5258 (1986).
A. Malliaris, J. Lang and R. Zana, J. Phys. Chem., 90, 655 (1986).
W. Baumuller, H. Hoffmann, W. Ulbricht, C. Tondre and R. Zana, J. Colloid Interface Sci., 64, 418 (1978).
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© 1989 Plenum Press, New York
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Malliaris, A., Lang, J., Zana, R. (1989). Fluorescence Quenching and the Study of Micellar Systems: Possibilities and Limitations of the Method. In: Mittal, K.L. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7984-7_7
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DOI: https://doi.org/10.1007/978-1-4615-7984-7_7
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