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Characteristics of Rodlike Micelles of Alkyltrimethylammonium Halides in Aqueous Sodium Halide Solutions: Their Flexibility and Entanglement

  • Chapter
Surfactants in Solution

Abstract

Static light scattering has been measured for aqueous NaCl solutions of tetradecyl-and hexadecyl-trimethylammonium chlorides (C14TAC and C15TAC) and for aqueous NaBr solutions of their homologous bromide derivatives (C14TAB and C16TAB) at 25 or 35°C. The threshold salt concentration of sphere-rod transition depends on the alkyl chain length and the counterion species. The persistence length of a long rodlike micelle has been evaluated as 37 – 60 nm for C14TAB, C16TAC and C16TAB. Solution properties of long rodllike micelles in semidilute regime are investigated on the basis of the blob model and the scaling laws. Electron micrographs prove the existence of spherical micelles and semiflexible rodlike micelles.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Nagoya University, Chikusa, Nagoya 464, Japan

    Toyoko Imae & Shoichi Ikeda

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  1. Toyoko Imae
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  2. Shoichi Ikeda
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Editor information

Editors and Affiliations

  1. IBM US Technical Education, 500 Columbus Ave., Thornwood, NY, 10594, USA

    K. L. Mittal

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© 1989 Plenum Press, New York

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Imae, T., Ikeda, S. (1989). Characteristics of Rodlike Micelles of Alkyltrimethylammonium Halides in Aqueous Sodium Halide Solutions: Their Flexibility and Entanglement. In: Mittal, K.L. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7984-7_31

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  • DOI: https://doi.org/10.1007/978-1-4615-7984-7_31

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-7986-1

  • Online ISBN: 978-1-4615-7984-7

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