Abstract
The mean aggregation number n of different alkylsulphate (sodium octyl-, decyl-, dodecylsulphate) micelles has been systematically studied versus surfactant concentration (c = 0.03-0.8 mol/dm3) and solution temperature (T = 20-60 °C), by using the small angle neutron scattering (SANS) and positron annihilation (PA) techniques. In the first case, the mean aggregation number has been determined from the least squares fitting of the product P(q)S(q) to the scattering intensity patterns. The single particle scattering function P(q) is assumed to arise from ellipsoidal-shaped monodisperse micelles; in contrast, the interparticle structure factor S(q) is determined by assuming monodisperse“mean” spherical scatterers interacting with a screened Coulomb potential.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A. Guinier and G. Fournet,“Small-Angle Scattering of X-rays”, John Wiley, New York, 1955.
G. Kostorz, in“Neutron Scattering in Materials Science”, G. Kostorz, Editor, Academic Press, New York, 1978.
G.S. Hartley,“Aqueous Solutions of Paraffin Chain Salts”, Hermann, Paris, 1936.
C. Tanford,“The Hydrophobic Effect”, John Wiley, New York, 1973.
I.N. Israelachvili, D.J. Mitchell and B.W. Ninham, J. Chem. Soc. Faraday Trans II 72 1525 (1976).
K.A. Dill and P.J. Flory, Proc. Nat. Acad. Sci. USA 78, 676 (1981).
A. Ben-Shaul, I. Szleifer and W.M. Gelbart, Proc. Nat. Acad. Sci. USA 81, 4601 (1984).
P. Fromherz, Chem. Phys. Lett. 77 460 (1981).
D.W.R. Gruen, J. Phys. Chem. 89, 146 (1985).
B.V. Deryagin, Usp. Chim. 48, 675 (1979), in Russian.
J.B. Hayter and J. Penfold, J. Chem. Soc Faraday Tans. I 77, 1851 (1981).
J.B. Hayter and J. Penfold, Colloid Polym. Sci. 261, 1022 (1983).
J.B. Hayter and J. Penfold, Mol. Phys. 42, 109 (1981).
J.P. Hansen and J.B. Hayter, Mol. Phys. 46, 651 (1982).
Sz. Vass, J. Phys. Chem. 90, 1099 (1986).
V.A. Vagov, A.B. Kunchenko, Yu.M. Ostanievich and I.M. Salamatin, JINR Communications P14-83-898, Dubna, 1983, in Russian.
I.A. Gladkikh, A.B. Kunchenko, Yu.M. Ostanievich and L. Cser, JINR Communications P3-11487, Dubna, 1978, in Russian.
C. Tanford, Proc. Nat. Acad. Sci. USA 71, 1811 (1974).
A. Ben-Shaul and W.H. Gelbart, J. Phys. Chem. 86, 316 (1982).
D. Blankschtein, G.M. Thurston and G.B. Benedek, Phys. Rev. Lett. 54., 955 (1985).
M. Corti and V. Degiorgio, Chem. Phys. Lett. 53, 237 (1978).
M. Kotlarchyk and S.H. Chen, J. Chem. Phys 79, 2461 (1983).
J.B. Hayter, in“Physics of Amphiphiles: Micelles, Vesicles and Microemulsions”, V. Degiorgio and M. Corti, Editors, p. 59, North Holland, Amsterdam, 1985.
B. Cabane, R. Duplessix and T. Zemb, J. Phys., Paris 46, 2161 (1985).
V. Luzzati and A. Tardieu, Ann. Rev. Biophys. Bioeng. 9, 1 (1980).
I. Dèzsi, Zs. Kajcsos and B. Molnòr, Nucl. Instr. Meth. 141, 401 (1977).
A. Hoessler,“Annihilation des Positrons dans les Liquides”, Thesis, Université Louis Pasteur, Strasbourg, 1982.
Sz. Vass, Zs. Kajcsos and B. Molnòr, Chem. Phys. Lett. 118, 105 (1985).
Sz. Vass, Zs. Kajcsos and B. Molnòr, in“Surfactants in Solutions,” K.L. Mittal, Editor, Vol 4, pp. 179–188, Plenum Press, New York, (1986).
E.A.G. Aniansson, S.N. Wall, H. Almgren, H. Hoffmann, I. Kielmann, W. Ulbricht, R. Zana, J. Lang and C. Tondre, J. Phys. Chem. 80, 905 (1976).
M. Kahlweit, J. Colloid Interface Sci. 90, 92 (1980).
T.R. Waite, Phys. Rev. 107, 463 (1957).
H.S. Carlsaw and J.C. Jaeger,“Conduction of Heat in Solids”, p. 382, Clarendon Press, Oxford, 1959.
Sz. Vass and Zs. Kajcsos, Radiat. Phys. Chem. 32., 403 (1988).
F. James and M. Roos, Comp. Phys. Comm. 10, 343 (1979).
P.J. Missel, N.A. Mazer, G.B. Benedek and M.C. Carey, J. Phys. Chem. 87, 1264 (1983).
H.V. Tartar and A.CM. Lelong, J. Phys. Chem. 59, 1185 (1955).
J.M. Phillips and J.K. Mysels, J. Phys. Chem. 59, 325 (1955).
K.J. Mysels and L.H. Princen, J. Phys. Chem. 63, 1696 (1959).
H.F. Huisman, Proc. Kon. Ned. Akad. Ser.B67, 405 (1964).
E.Y. Sheu, C.F. Wu, H.S. Chen and L. Blum, Phys. Rev. A32, 3807 (1983).
H.S. Chen, Ann. Rev. Phys. Chem. 37. 351 (1986).
R. Triolo, E. Caponetti and V. Graziani, J. Phys. Chem. 85, 5743 (1985).
S.S. Berr, M.J. Coleman, R.R. Marriott Jones and J.S. Johnson, Jr., J. Phys. Chem. 90, 6492 (1986).
N.J. Turro and A. Yekta, J. Am. Chem. Soc. 100, 5951 (1978).
P. Lianos and R. Zana, J. Phys. Chem. 84, 3339 (1980).
P. Lianos and R. Zana, J. Colloid Interface Sci. 84, 100 (1981).
L. Belloni, J. Chem. Phys. 85, 519 (1986).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1989 Plenum Press, New York
About this chapter
Cite this chapter
Cser, L. et al. (1989). Systematic Investigation of Sodium Alkylsulphate Micelles Using Small Angle Neutron Scattering and Positron Annihilation Techniques. In: Mittal, K.L. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7984-7_11
Download citation
DOI: https://doi.org/10.1007/978-1-4615-7984-7_11
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4615-7986-1
Online ISBN: 978-1-4615-7984-7
eBook Packages: Springer Book Archive