Abstract
An introduction to surfactant and micellar systems is presented. The unique properties exhibited by micellar systems that are ideally suited and very useful in the field of analytical chemistry are outlined (ie. their solubilization power; their utilization as a novel reaction medium in which the rates, equilibrium position, products, and, in a few instances, stereochemistry can be affected; and their ability to greatly alter the microscopic properties and change the effective microenvironment about solubilized solutes). A summary of published work is presented in which micellar systems have been successfully utilized to either improve existing analytical methods or help overcome problems associated with the development of new analytical procedures. Specific examples of such practical and useful applications of micellar systems are given for spectral methods of analysis such as ultraviolet-visible absorption, fluorescence, and atomic absorption; for electroanalytical methods involving potentiometry and polarography; and for chemical separations including chromatographic and extraction techniques. In each case, the micellar chemistry and/or properties involved in the particular analytical application are elucidated. The advantages of these micellar-improved analytical methods are discussed. Several other miscellaneous applications as well as potential areas for future research involving micellar systems in analytical chemistry are pointed out in the overview.
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Hinze, W.L. (1979). Use of Surfactant and Micellar Systems in Analytical Chemistry. In: Mittal, K.L. (eds) Solution Chemistry of Surfactants. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7880-2_4
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