Abstract
Core and valence levels of poly-p-phenylene sulfide have been examined by X-ray photoelectron spectroscopy. Atomic charges distribution and characteristics of the C-S bond are obtained by comparison with related molecules such as (di)phenyl sulfide and (di)benzyl sulfide. The degree of the π electron delocalization in the polymeric chain and the amplitude of the energy gap are compared with previous results on poly-p-phenylene.
Holder of a fellowship of I.R.S.I.A. (Belgium)
Chercheur qualifié of the “Fonds National de la Recherche Scientifique”.
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References
V.V. Walatka Jr., M.M. Labes and J.H. Perlstein, Phys. Rev. Lett. 31, 1139 (1973).
G.B. Street and T.C. Clarke, IBM J. Res. Develop. 25, 51 (1981)
C.B. Duke in “Extended Linear Chain Compounds”, J.S. Miller, Editor, Plenum Press, New York,1980.
A.G. Mac Diarmid and A.J. Heeger, Synthetic Metals, 1, 101 (1979/80).
D.M. Ivory, G.G. Miller, J.M. Sowa, L.W. Shacklette, R.R. Chance and R.H. Baughman, J. Chem. Phys. 71, 1506 (1979)
L.W. Shacklette, R.R. Chance, D.M. Ivory, G.G. Miller and R.H. Baughman, Synthetic Metals 1, 307 (1979).
J.L. Brédas, R.R. Chance, R.H. Baughman and R. Silbey, Int. J. Quantum Chemistry, S15, 231 (1981).
L.W. Schacklette, R.L. Elsenbaumer, R.R. Chance, H. Eckhardt, J.R. Frommer and R.H. Baughman, submitted for publication.
J.F. Rabolt, T.C. Clarke, K.K. Kanazawa, J.R. Reynolds and G.B. Street, J.C.S. Chem. Comm., p. 347 (1980)
R.R. Chance, L.W. Schacklette, G.G. Miller, D.M. Ivory, J.M. Sowa, R.L. Elsenbaumer and R.H. Baughman, J.C.S. Chem. Comm., p. 348 (1980).
B.J. Tabor, E.P. Magre and J. Boon, European Polymer J. 7, 1127 (1971).
J. Riga, J.J. Pireaux, J.P. Boutique, R. Caudano, J. Verbist and Y. Gobillon, Synthetic Metals, 4, 99 (1981).
J. Riga, J.J. Pireaux, R. Caudano and J. Verbist, Physica Scripta 16, 346 (1977).
J.P. Boutique, J. Riga, J.J. Verbist (1982), unpublished data.
K. Siegbahn, C. Nordling, A. Fahlman, R. Nordberg, K. Hamrin, J. Hedman, G. Johansson, T. Bergmark, S.-E. Karlson, I. Lindgren, B. Lindberg, “ESCA, Atomic Molecular and Solid State Structure Studied by Means of Electron Spectroscopy”, Almqvist and Wiksells, Uppsala, Sweden, 1967.
J. Riga, Ph. D. Thesis, University of Namur, Namur, Belgium, 1978, available from University Microfilms, Publ. N° 7970007.
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© 1983 Plenum Press, New York
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Riga, J., Boutique, J.P., Pireaux, J.J., Verbist, J.J. (1983). X-Ray Photoelectron Spectroscopic Study of the Electronic Structure of Poly-P-Phenylene Sulfide. In: Mittal, K.L. (eds) Physicochemical Aspects of Polymer Surfaces. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7584-9_3
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DOI: https://doi.org/10.1007/978-1-4615-7584-9_3
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