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Electrocatalysis

  • Chapter
Modern Aspects of Electrochemistry

Abstract

This article will attempt to discuss those factors which influence the overall rates of electrochemical reactions, a subject that has been treated several times elsewhere.1–4,83 It is hoped that the question will be approached from somewhat different points of view from those expressed previously. In particular, concentration will be on the fundamental aspects of the rate equation for electron transfer as a function of the substrate, together with their experimental consequences, which will involve a discussion and review of the mechanism of the elementary act of electron transfer. Particular emphasis will be placed on the electrocatalytic case, i.e., that involving adsorbed reaction intermediates. This has been the subject of much dispute in the recent literature.5 The reasoning will be applied to a discussion of those reactions that have been most studied with respect to the dependence of rate on the nature of the substrate: namely hydrogen evolution, oxygen reduction and evolution, and, to a lesser extent, hydrocarbon oxidation. Emphasis will be particularly on the oxygen electrode reaction, which has been reviewed elsewhere.83,163,189

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  1. A. J. Appleby

    Present address: Laboratoires de Marcoussis (C.G.E.), 91-Marcoussis, France

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    A. J. Appleby

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  1. Department of Chemistry, University of Ottawa, Ottawa, Canada

    B. E. Conway

  2. School of Physical Sciences, The Flinders University, Adelaide, South Australia, Australia

    J. O’M. Bockris

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Appleby, A.J. (1974). Electrocatalysis. In: Conway, B.E., Bockris, J.O. (eds) Modern Aspects of Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7443-9_5

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