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Methods and Mechanisms in Electroorganic Chemistry

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Modern Aspects of Electrochemistry
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Abstract

Electroorganic chemistry, or the effecting of chemical changes in organic systems through the agency of an electric current, dates from about the time of Faraday’s discovery of hydrocarbon formation during the electrolysis of aqueous acetate solutions.1 This anodic decarboxylation reaction was later investigated for its synthetic possibilities by Kolbe2 and others3; it is interesting to note that, after one and one-third centuries, it is still being actively investigated, both for the original (synthetic) purpose,4 and with a view to obtaining information about the mechanism of this reaction, and of electrochemical reactions in general.5 From this initial decarboxylation and radical dimerization reaction, the bounds of electroorganic chemistry have spread to include a wide range of different reaction types, ranging from complete oxidation to CO2 of organic substrates like alkanes,6 alcohols,7 acids,8–10 or even cellulose,11 to anodic or cathodic substitution reactions, e.g., acetoxylation12 or halide reduction,13 to anodic or cathodic addition, e.g., methoxylation,14 or reduction of unsaturated linkages,15 to hydrodimerization,16 and to formation of organometallic compounds,17 etc.

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Humffray, A.A. (1972). Methods and Mechanisms in Electroorganic Chemistry. In: Bockris, J.O., Conway, B.E. (eds) Modern Aspects of Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7440-8_3

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