Abstract
A study was made to ascertain whether the nuclear quadrupole coupling constants of Cu and Na in more or less ionic crystals could be correlated with chemical properties such as net charge or electronegativity. A number of isostructural compounds were examined and such correlations appear to exist. The long-term aim is to collect sufficient data on isostructural compounds of varying degrees of ionicity, so that adequate tests can be made of some of the current theories of nuclear quadrupole coupling constants. The business of this paper is primarily to present new and rather extensive experimental results and, at this time, to attempt only the simplest of theoretical interpretations.
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Peterson, G.E. (1970). Charge Distributions in Ionic Crystals from the N.M.R. and N.Q.R. of Na and Cu. In: Coogan, C.K., Ham, N.S., Stuart, S.N., Pilbrow, J.R., Wilson, G.V.H. (eds) Magnetic Resonance. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7373-9_3
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DOI: https://doi.org/10.1007/978-1-4615-7373-9_3
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