Abstract
The growth of crystals from molten salt solutions or “fluxes” has historically been an empirical art which developed principally as a tool for mineral synthesis. The use of fluxes to grow crystals of technological interest began with the work of Remeika who grew barium titanate, BaTiO3, from molten potassium fluoride, KF [1], and ferrimagnetic spinels, MFe2O4, from molten lead oxide, PbO [2]. A major impetus to flux growth was the discovery that magnetic garnets, Ln3Fe5O12, could be grown from PbO [3], Bi2O3 [3], and PbO-PbF2 mixtures [4]. That work and Remeika’s discovery of the addition of boric oxide to PbO and Bi2O3 to improve their solvent power for the growth of many oxides set the stage for wide application of the flux method.
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Literature Cited
J. P. Remeika, J. Amer. Chem. Soc., 76: 940 (1954).
J. P. Remeika, U. S. Patent 2,848, 310 (1958).
J. W. Nielsen, J. App. Phys., 29: 390 (1958).
J. W. Nielsen, J. App. Phys. Suppl., 31: 515 (1960).
L. G. Van Uitert, W. H. Grodkiewicz, and E. F. Dearborn, J. Amer. Ceram. Soc., 48: 105 (1965).
R. A. Laudise, “Molten Salt Solvents,” in: The Art and Science of Growing Crystals, J. J. Gilman, ed., Wiley, New York (1963), p. 252.
E. A. D. White, Tech. Inorg. Chem., 4: 31 (1965).
Y. Laurent, Rev. Chim. Mineral., 6: 1145 (1969).
L. G. Van Uitert and R. C. Sherwood, J. Phys. Chem. Solids, 25: 1447 (1964).
Barbara M. Wanklyn, to be published in J. Mater. Sci.
L. G. Van Uitert, Private communication.
S. Abrahams and J. L. Bernstein, J. Chem. Phys., 46:3776 (1967); I. Novik, H. J. Williams, L. G. Van Uitert, and H. J. Levinstein, J. App. Phys., 37: 970 (1966).
D. B. McWhan and J. P. Remeika, Phys. Rev., B2:3734 (1970)•
M. Foguel and R. Grajower, J. Cryst. Growth, 11: 280 (1971).
Barbara M. Wanklyn, to be published.
L. G. Van Uitert, L. Pictroski, and W. H. Grodkiewicz, Mater. Res. Bull., 4: 777 (1969).
H. J. Scheel, to be published.
M. Nevriva, Krist. Tech., 6: 517 (1971).
J. P. Remeika and M. Marezio, App. Phys. Lett., 8: 87 (1966).
D. F. Nelson and J. P. Remeika, J. App. Phys., 35:522 (1964); J. W. Nielsen, Electronics, 37: 44 (1964).
W. H. Grodkiewicz, E. F. Dearborn, and L. G. Van Uitert, in: Crystal Growth, H. S. Peiser, ed., Pergamon, Oxford (1967), p. 441.
H. J. Scheel and E. O. Schulz-DuBois, J. Cryst. Growth, 8:304 (1971); H. J. Scheel, J. Cryst. Growth, 13 /14: 560 (1972).
E. O. Schulz-DuBois, J. Cryst. Growth, 12: 81 (1972).
W. Tolksdorf and F. Welz, to be published.
W. Tolksdorf, J. Cryst. Growth, 3/4:463 (1968); G. A. Bennett, ibid., p. 458.
Unpublished work.
Private communication.
C. E. Miller, J. Appl. Phys., 29: 233 (1958).
V. Belruss, J. Kalnajs, and A. Linz, Mater. Res. Bull., 6: 899 (1971).
P. W. Whipps, J. Cryst. Growth, 12: 120 (1972).
W. A. Bonner, E. F. Dearborn, and L. G. Van Uitert, in: Crystal Growth, H. S. Peiser, ed., Pergamon, Oxford (1967), p. 437.
R. A. Laudise, R. C. Linares, and E. F. Dearborn, J. Appl. Phys., 338: 1362 (1962).
H. J. Levinstein, S. Licht, R. W. Landorf, and S. L. Blank, App. Phys. Lett., 19: 486 (1971).
E. A. Giess, B. E. Argyle, D. C. Cronemeyer, E. Klokholm, D. F. O’Kane, T. S. Plaskett, and V. Sadagopan, Magnetism and Magnetic Materials - 1971, AIP Conference Proceedings No. 5, Part 1, C. D. Graham and J. J. Rhyne, eds., American Institute of Physics, New York (1972), p. 110.
S. L. Blank and J. W. Nielsen, Presented at the Second International Conference on Vapor Growth and Epitaxy, May 21–26, 1972, Jerusalem, Israel.
J. W. Nielsen and E. F. Dearborn, J. Phys. Chem. Solids, 5: 202 (1958).
V. A. Timofeeva, in: Crystal Growth, H. S. Peiser, ed., Pergamon, Oxford (1967), p. 445.
V. A. Timofeeva, J. Cryst. Growth, 3 /4: 496 (1968).
J. W. Nielsen, D. A. Lepore, and D. C. Leo, in: Crystal Growth, H. S. Peiser, ed., Pergamon, Oxford (1967), p. 457.
E. V. Rybal’skaya, T. G. Petrov, and A. G. Titova, Kristallografiya, 15:1094 (1970). [Sov. Phys. - Crystallography, 15:958 (1971)].
D. Elwell and W. W. Neate, J. Mater. Sci., 6: 1499 (1971).
D. Elwell and R. D. Dawson, Presented at the Third International Conference on Crystal Growth, July 5–9, 1971, Marseille, France.
H. J. Scheel and D. Elwell, J. Cryst. Growth, 12: 153 (1972).
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Nielsen, J.W. (1984). Recent Development in Crystal Growth from High-Temperature Solutions. In: Chernov, A.A. (eds) Рост Кристаллоь / Rost Kristallov / Growth of Crystals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7116-2_23
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