Abstract
Large numbers of polynuclear transition-metal complexes have now been characterized by X-ray crystallography.1 Many of them, particularly the larger aggregates,1d have structures resembling those of metals. On the basis of this and other similarities, a number of workers2 have suggested that useful analogies may be drawn between clusters and metal surfaces.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
For some recent reviews see B. R. Penfold, Perspectives in Structural Chmeistry, 2, 71 (1968);
R. B. King, Progress in Inorganic Chemistry, 15, 287 (1972);
J. Lewis and B. F. G. Johnson, Pure Appl. Chem., 44, 43 (1975);
P. Chini, G. Longoni and V. G. Albano, Adv. Organomet. Chem., 14, 285 (1976).
E. L. Muetterties, Bull. Soc. Chim. Belg., 84, 959 (1975);
R. Ugo, Catal. Rev., 11, 225 (1975);
E. L. Muetterties, Bull. Soc. Chim. Belg., 85, 451 (1976);
J. M. Basset and R. Ugo, in Aspects of Homogeneous Catalysis, Vol. III, R. Ugo, ed., Reidel (Holland) (1976).
P. Bellon, M. Manassero and M. Sansoni, J. C. S. Dalton, 1481 (1972).
V. G. Alhano, A. Ceriotti, P. Chini, G. Ciani, S. Martinengo and W. M. Anker, Chem. Commun., 859 (1975).
F. A. Cotton and G. Wilkinson, “Advanced Inorganic Chemistry,” Third Edition, Interscience, 1972, p. 65.
N. Kutepow and H. Kindler, Angew. Chem., 72, 802 (1960).
T. F. Wada and T. Masuda, Chem. Lett., 197 (1974).
F. L’Epplattenier, P. Matthys and F. Calderazzo, Inorg. Chem., 9, 342 (1970).
P. Chini, S. Martinengo and G. Garlaschelli, Chem. Commun., 709 (1972), and references therein.
G. D. Mercer, J. S. Shu, T. B. Rauchfuss and D. M. Roundhill, J. Amer. Chem. Soc., 97, 1967 (1975).
R. L. Pruett and W. E. Walker, U. S. Patent Application 210, 538; German Offen. 2,262,318, June 28, 1973; Chem. Abs., 79, 78088k (1973).
W. E. Walker, J. B. Cropley and R. E. Pruett, Netherlands patents 7,407,383 and 7,407,412.
P. Chini, S. Martinengo and G. Ciordano, Gazz. Chim. Ital., 102, 330 (1972).
M. G. Thomas, B. F. Beier and E. L. Muetterties, J. Amer. Chem. Soc., 98, 1296 (1976).
G. N. Schrauzer, B. N. Bastian and G. A. Fosselius, J. Amer. Chem. Soc., 88, 4890 (1966).
R. R. Schrock and J. A. Osborn, J. Amer. Chem. Soc., 93, 3089 (1971).
G. N. Schrauzer, R. K. Y. Ho and G. Schlesinger, Tetrahedron Lett., 543 (1970).
J. B. Keister and J. R. Shapley, J. Amer. Chem. Soc., 98, 1056 (1976), and references therein.
A. J. Deeming and S. Hasso, J. Organomet. Chem., 114. 313 (1976), and references therein.
V. W. Day, R. O. Day, J. S. Kristoff, F. J. Hirsekorn and E. L. Muetterties, J. Amer. Chem. Soc., 97, 2571 (1975).
M. G. Thomas, E. L. Muetterties, R. O. Day and V. W. Day, J. Amer. Chem. Soc., 98, 4645 (1976).
J. B. Keister and J. R. Shapley, J. Organomet. Chem., 85, C29 (1975).
A. J. Canty, B. F. G. Johnson, J. Levis and J. R. Norton, Chem. Commun., 1331 (1972).
J. Evans, S. J. Okrasinski, A. J. Pribula and J. R. Norton, J. Amer. Chem. Soc., 98, 4000 (1976).
P. Woodward, private communication.
J. Evans, B. F. G. Johnson, J. Lewis and J. R. Norton, Chem. Commun., 79 (1973).
F. A. Cotton, L. Kracznski, B. L. Shapiro and L. F. Johnson, J. Amer. Chem. Soc., 94, 6191 (1972);
J. Evans, B. F. G. Johnson, J. Lewis, J. R. Norton and F. A. Cotton, Chem. Commun., 807 (1973).
P. Chini, S. Martinengo, D. J. A. McCaffrey and B. T. Heaton, Chem. Commun., 310 (1974).
J. W. Koepke, J. R. Johnson, S. A. R. Knox, and H. D. Kaesz, J. Amer. Chem. Soc., 97, 3947 (1975).
K. J. Karel and J. R. Norton, J. Amer. Chem. Soc., 96, 6812 (1974).
J. R. Norton and J. P. Collman, Inorg. Chem., 12, 476 (1973).
a) R. J. Haines, R. Mason, J. A. Zubieta, and C. R. Nolte, Chem. Commun., 990 (1972);
R. Mason and J. A. Zubieta, J. Organomet. Chem., 66, 279 (1974).
A. Agapiou, S. E. Pedersen, L. A. Zyzyck, and J. R. Norton, manuscript submitted for publication.
R. J. Haines, J. C. Burkett-St. Laurent, and C. R. Nolte, J. Organomet. Chem., 104, C27 (1976).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1977 Plenum Press, New York
About this chapter
Cite this chapter
Norton, J.R. (1977). Metal Clusters in Catalysis. In: Tsutsui, M., Ugo, R. (eds) Fundamental Research in Homogeneous Catalysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7038-7_4
Download citation
DOI: https://doi.org/10.1007/978-1-4615-7038-7_4
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4615-7040-0
Online ISBN: 978-1-4615-7038-7
eBook Packages: Springer Book Archive