Abstract
Thermodynamic models for the microphase separation of block copolymers have evolved much further in the past decade than have rheological models for interpreting mechanical property data on these materials. Early thermodynamic theories were designed as two-phase models (1–6), so that diblock AB or triblock ABA was represented as having microphases of pure A and pure B with a sharp interface between. A major advance was the recognition (7) that a third region, an interphase of intermediate composition, must contribute importantly in a system having such small phase dimensions (Fig. 1). Incorporation of this concept in thermodynamic models (7–10) has been quite successful, in terms of predicting microstructural geometries and microphase separation temperatures Ts which have been verified by experiment (e.g., 11).
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Diamant, J., Soong, D.S., Williams, M.C. (1984). Modeling the Viscoelastic Behavior of SBS Block Copolymer Solids. In: Bailey, W.J., Tsuruta, T. (eds) Contemporary Topics in Polymer Science. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-6743-1_41
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DOI: https://doi.org/10.1007/978-1-4615-6743-1_41
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