Abstract
A recently developed discrete shell model1,2 for cross-relaxation and energy-transfer processes in hexachloroelpasolites Cs2NaLn x Gd1-x Cl6 (Ln = rare-earth ion, x = 0.001,…,1) is introduced. After deciding the energy-transfer mechanism, luminescent decay curves can be calculated for all concentrations and compared with experimental data. The radial and angular dependencies of the energy-transfer Hamiltonian have been considered with respect to the fcc lattice.
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References
S.O. Vasquez, C. D. Flint, Chem. Phys. Letts. (1995), in press
T. Luxbacher, H. P. Fritzer, C. D. Flint, Chem. Phys. Letts. (1995), in press
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Luxbacher, T. (1997). Structural Aspects of Energy Transfer in Cubic Crystals. In: Di Bartolo, B., Kyrkos, S. (eds) Spectroscopy and Dynamics of Collective Excitations in Solids. NATO ASI Series, vol 356. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-5835-4_41
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DOI: https://doi.org/10.1007/978-1-4615-5835-4_41
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