Abstract
Sols and gels are two forms of matter that have been known to exist naturally for a long time. They include various materials such as ink, clays, and a number of other substances such as the eye vitrea, blood, serum, and milk [1]. Sols and gels have arose scientific interests for a long time. The oldest sols prepared in a laboratory were synthesized with gold by Faraday in 1853. They are still stable nowadays[2]. It was not until 1861 that Graham founded colloidal science. Since then the study of ceramic colloidal sols has been slowly progressing so that the manner in which the sols forms and their sensibility to a number of different factors are now starting to be understood. It is only since recently that we can control the size of particles with inorganic salts [2,3]. Similarly, it has been necessary to achieve a good understanding of the nature of sols and of the laws explaining their behaviors before synthesizing well-defined particle dispersions. A major contribution in the understanding of sols chemistry came from the DLVO or electrostatic theory. This theory was particularly the first one to distinguish a precipitate from a stable colloidal suspension.
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References
Livage J., Lemerle J., Ann. Rev. Mater. Sci. 12 (1982) 103–122.
Matijevic E., “Monodisperse colloids (Preparation, Properties and Applications), and interactions in mixed colloidal systems (heterocoagulation, adhesion and microflotation)”. Conference presented at the Université de Bordeaux I, France, 9-10 June 1987.
Roy R., J. Amer. Ceram. Soc. 39 (1956) 145.
Iler R.K., “The Chemistry of Silica”, Wiley, New-York (1979).
Ebelmen M., Ann. Chim. Phys, 15 (1845) 319
Ebelmen M., Ann. Chim. Phys, 16 (1846) 129
Ebelmen M., Compte Rendus de l’Acd. des Sciences 25 (1947) 854.
Cossa A., Il Nuovo Cimento 3 (1870) 228–230.
Kistler S.S., Nature, 127 (1931) 741.
Stock A., Somieski K., Ber. dt. Chem. Ges. 54 (1921) 740–758.
Corma A., Chem. Rev. 97 (1997) 2373–2419.
Sanchez C., Ribot F., New J. Chem., 18 (1994) 1007–1047.
Tohge N., Moore G.S., Mackenzie J.D., J. Non-Cryst. Solids 63 (1984) 95–103.
Gitzen W.H., “Alumina as a Ceramic Material”, the American Ceramic Society, Columbus, Ohio (1970).
Flory P.J., J. Am. Chem. Soc. 63 (1941) 3083–3100.
Hammersley J.M., Proc. Cambridge Phil. Soc. 53 (1957) 642–645.
Mandelbrot B.B., “Fractals: Form, Chances and Dimensions”, Freeman, San Francisco (1977).
Ford R.W., “Drying”, Institute of ceramics, Textbook series; MacLaren and Sons, London, England (1964).
Matijevic E., Acc. Chem. Res. 14 (1981) 22–29.
Mazdiyasni K.S., Lynch C.T., Smith II J.S., J. Am. Ceram. Soc. 48 (1965) 372–375.
Wheat T.A., J. Canad. Ceram. Soc. 46 (1977) 11–18.
Hiemenz P.C., “Principles of Colloid and Surface Chemsitry”, Marcel Dekker, New-York (1977).
Flory J.P., Disc. Faraday soc., 57 (1974) 7–8.
Flory J.P., “Principles of Polymer Chemistry”, Cornell University Press, Ithaca, New-York (1953).
Seyferth D., Wiseman G.H., in “Ultrastructure Processing of ceramics, Glasses and Composites”, Edited by Hench L.L. and Ulrich D.R., Wiley, New-York (1984) 265–271.
Dislich H., J. of Non-Crystalline Solids 57 (1983) 371–388.
Segal D.L., J. Non-Crystalline Solids 63 (1984) 183–191.
Mazdiyasni K.S., Ceramics International 8 (1982) 42–56.
Zelinski B.J.J., Uhlmann D.R., J. Phys. Chem. Solids 45 (1984) 1069–1090.
Haertling G.H., Land C.E., Ferroelectrics 3 (1972) 269–280.
Sapieszko R.S., Matijevic E., Corrosion 36 (1980) 522–530.
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Pierre, A.C. (1998). General Introduction. In: Introduction to Sol-Gel Processing. The Kluwer International Series in Sol-Gel Processing: Technology and Applications, vol 1. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-5659-6_1
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DOI: https://doi.org/10.1007/978-1-4615-5659-6_1
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