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Morphology and Microstructure of A1N Single Crystals on Si (111): A Combination of Surface Electron Spectroscopies and Transmission Electron Microscopies

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Ceramic Microstructures

Abstract

In the last 10 years, the III-nitride semiconductors (A1N, GaN, InN and ternary compounds) have revealed promising physical and optical properties. Potential applications include blue light emitting diodes and ultraviolet (UV) detectors, as well as high power and high temperature electronic devices. Aluminum nitride has a wide band gap (6.2 eV). Because of its piezoelectric properties, it can also be used in field effect transistors as a gate dielectric film and in thin film microwave acoustic resonators.1 A high thermal conductivity (320 W/mK for ideally pure single crystals) and a thermal expansion coefficient close to that of Si (4–5 × 10−6/K for A1N and 3 × 10−6/K for Si) make the A1N/Si system a good candidate for microelectronics and for use in metal-insulator-semiconductor (MIS) devices. These applications require high quality crystals and low contamination in order to obtain near-ideal material characteristics.

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References

  1. K. S. Stevens, M. Kinniburgh, A. F. Schwartzman, A. Ohtani and R. Beresford, Demonstration of a silicon field-effect transistor using A1N as a gate dielectric, Appl. Phys. Lett. 66:3179 (1995).

    Article  CAS  Google Scholar 

  2. A. Saxler, P. Kung, C. J. Sun, E. Bigan and M. Razeghi, High quality aluminum nitride epitaxial layers grown on sapphire substrates, Appl. Phys. Lett. 64:339 (1994).

    Article  CAS  Google Scholar 

  3. L. B. Rowland, R. S. Kern, S. Tanaka and R. F. Davis, Epitaxial growth of A1N by plasma-assisted, gas-source molecular beam epitax, J. Mater. Res., 8:2310 (1993).

    Article  CAS  Google Scholar 

  4. W. J. Meng, J. Heremans and Y. T. Cheng, Epitaxial growth of aluminium nitride on Si(111) by reactive sputtering, Appl. Phys. Lett., 59:2097 (1991).

    Article  CAS  Google Scholar 

  5. W. J. Meng, J. A. Sell, T. A. Perry, L. E. Rehn and P. M. Baldo, Growth of aluminum nitride thin films on Si(111) and Si(001): structural characteristics and development of intrinsic stresses, J. Appl. Phys., 75:3446 (1994).

    Article  CAS  Google Scholar 

  6. F. Malengreau, M. Vermeersch, S. Hagège, R. Sporken, M. D. Lange and R. Caudano, Epitaxial growth of aluminum nitride layers on Si(111) at high temperature and for different thicknesses, in Journal of Materials Research, in press.

    Google Scholar 

  7. T. Warren Weeks, Jr., M. D. Bremser, K. Shawn Ailey, E. Carlson, W. G. Perry and R. F. Davis, GaN thin films deposited via organometallic vapor phase epitaxy on a (6H)-SiC(0001) using high-temperature monocrystalline A1N buffer layer, Appl. Phys. Lett., 67:401 (1995).

    Article  Google Scholar 

  8. J. N. Kuznia, M. Asif Khan, D. T. Olson, R. Kaplan and J. Freitas, Influence of buffer layers on the deposition of high quality single crystal GaN over sapphire substrates, J. Appl. Phys., 73:4700 (1993).

    Article  CAS  Google Scholar 

  9. see also: C. Colliex, R. Brydson, V. Serin et S. Matar, to be published.

    Google Scholar 

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© 1998 Springer Science+Business Media New York

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Malengreau, F., Hagège, S., Sporken, R., Vermeersch, M., Caudano, R., Imhoff, D. (1998). Morphology and Microstructure of A1N Single Crystals on Si (111): A Combination of Surface Electron Spectroscopies and Transmission Electron Microscopies. In: Tomsia, A.P., Glaeser, A.M. (eds) Ceramic Microstructures. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-5393-9_16

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  • DOI: https://doi.org/10.1007/978-1-4615-5393-9_16

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-7462-6

  • Online ISBN: 978-1-4615-5393-9

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