Abstract
An electron beam generated plasma reactor was used for the decomposition of carbon tetrachloride, 1,1,1-trichloroethane, trichloroethylene, 1,1-dichloroethane, toluene, and Freon 113. 99% decomposition of most compounds is achieved in the reactor. The energy requirements for decomposition of these compounds are given, and these results are discussed in terms of the electron capture rate coefficients and the plasma chemistry of the molecules.
This work supported by the Contaminant Plume Containment and Remediation Focus Area, Office of Environmental Management, U.S. Department of Energy.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
W. A. Apel, P.R. Dugan, M. R. Wiebe, E. G. Johnson, J. H. Wolfram and R. D. Rogers, Chapter 20in Emerging Technologies in Hazardous Waste Management 11Iedited by W. D. Tedder and F. G. Pohland, ACS, Washington D. C., (1993).
T. Aida, R. Higuchi and H. NiyamaChem. Lett.2247 (1990).
S. Okazaki and A. KurosakiChem. Lett.1901 (1989).
T. R. Krause and J. E. Helt, Chapter 19in Emerging Technologies in Hazardous Waste Management IIIedited by W. D. Tedder and F. G. Pohland, ACS, Washington D. C., (1993).
J. R. Bolton, A. Safarzadeh-Amiri, J. A. Buchley, R. Notarfonzo, S. Cater, “Homogeneous Photodegredation of Pollutants in Air” presented at 87th Annual Meeting and Exhibition, Air and Waste Management Association, Cincinnati, OH, June 1994.
M.C. Hsiao, B. T. Merritt, B. M. Penetrante, G. E. Vogtlin and P. H. Waltmanaccepted by J. App. Phys.(1995).
H. Shaw, Y. Wang, T. Yu and A. E. Cerkanowicz, Chapter 17 inEmerging Technologies in Hazardous Waste Management IIIedited by W. D. Tedder and F. G. Pohland, ACS, Washington D. C., (1993).
J. W. Bozzelli and R. B. BaratPlasma Chem. and Plasma Proc.8, 293 (1988).
L. A. Rosocha, J. J. Coogan, “ Processing of Pollutants in Dielectric-Barrier Plasma Reactors,”Proceedings of the 12th International Symposium on Plasma ChemistryMinneapolis, MN, 1995, p. 665–676.
M. Penetrante, M. C. Hsiao, J. N. Bardsley, B. T. Merritt, G. E. Vogtlin, P. H. Waltman, A. Kuthi, C. P. Burkhart, J. R. Bayless, “Electron Beam and Pulsed Corona Processing of Volatile Organic Compounds in Gas Streams,” To Be Publishedin Pure and Applied Chemistry1995.
R. C. Slater and D. H. Douglas-HamiltonJ. Appl. Phys.52 5820, (1981).
Td = 1 * 10-18V cm2
M. Koch, D.R. Cohn, R. M. Patrick, M. P. Scheutze, L. Bromberg, D. Reilly, K. Hadidi, P. Thomas, P. Falkos, “Electron Beam Atmospheric Pressure Cold Plasma Decomposition of Carbontetrachloride and Trichloroethylene,”Environmental Science and Technology29:2946 (1994).
M. Koch, “Decomposition of Chlorinated Organic Compounds in Gaseous Hazardous Waste Using a Tunable Plasma Reactor”, Ph.D. Thesis, M.I.T. Department of Nuclear Engineering, 1994.
S. A. Vitale, K. Hadidi, D. R. Cohn, P. Falkos, L. Bromberg, “1,1,1-Trichloroethane Decomposition in an Electron Beam Generated Plasma Reactor,”Plasma Chemistry and Plasma Processing16:651 (1996).
S. A. Vitale, K. Hadidi, D. R. Cohn, P. Falkos, L. Bromberg, `Effect of a Carbon-Carbon Double Bond on 1,1,1-Trichloroethane and Trichloroethylene Decomposition in an Electron Beam Generated Plasma Reactor,“ accepted by Plasma Chemistry and Plasma Processing, May1996.
L. G. Christoporou, Electron-Molecule Interactions and Their Applications, Vol. 1, Academic Press, 1984.
L. G. ChristoporouAtomic and Molecular Radiation PhysicsWiley-Interscience, 1971.
R. C. WeastHandbook of Chemistry and Physics 57th EditionCRC Press, 1976.
Freon 113 data estimated from similar compounds given in reference 19.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1997 Springer Science+Business Media New York
About this chapter
Cite this chapter
Vitale, S.A., Hadidi, K., Cohn, D.R., Bromberg, L., Falkos, a.P. (1997). An Electron Beam Generated Plasma Reactor for Decomposition of Halogenated VOCs. In: Tedder, D.W., Pohland, F.G. (eds) Emerging Technologies in Hazardous Waste Management 7. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-5387-8_3
Download citation
DOI: https://doi.org/10.1007/978-1-4615-5387-8_3
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-7459-6
Online ISBN: 978-1-4615-5387-8
eBook Packages: Springer Book Archive