Abstract
The second order rate constants for the thermal electron capture have been determined for a long time in many laboratories with a wide spectrum of different experimental techniques. However, there are not too many compounds investigated. Moreover, in most cases a large scattering of the results from different laboratories is observed. This could be caused either by not achieving the truly thermal distribution of electrons energy and/or not including the contribution from higher order electron attachment processes.
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References
I. Szamrej and M. Forys, The role of the van der Waals complexes in the thermal electron attachment processes in the gas phase, Progress in Reaction Kinetics, in press (1998).
M. Foryś and I. Szamrej, The dependence of electron capture rate constants on some molecular parameters, J. Radioanal. Nucl. Chem., 232 (1998).
I. Szamrej, H. Janicka, I. Chrząścik and M. Forys, Thermal electron attachment processes in gas mixtures containing H2S, HCl and HBr, Radiat. Phys. Chem., 33, 387 (1989).
L.G. Christophorou, D.L. McCorkle and A.A. Christodoulides, Electron attachment processes, in Electron-Molecule Interactions and their Applications, L.G. Christophorou, ed., Academic Press, London (1984).
S.R. Hunter and L.G. Christophorou, Electron attachment to the perfluoroalkanes n-CNF2N+2 (N=1-6) using high pressure swarm technique, J. Chem.Phys. 80, 6150 (1974).
I. Szamrej, H. Kość and M. Foryś, Thermal electron attachment to halomethanes-part 2. CH2F2, CHF3and CCIF3, Radiat.Phys.Chem., 48, 69 (1996).
D.L. McCorkle, I. Szamrej and L.G. Christophorou, Electron attachment to halocarbons, J. Chem.Phys., 77, 5542 (1982).
I. Szamrej, W. Tchórzewska, H. Kość and M. Foryś, Thermal electron attachment to halomethanes — part 1. CH2C12, CHFC12 and CF2C12, Radiat.Phys.Chem., 47, 269 (1996).
I. Szamrej, J. Jowko and M. Forys, Thermal electron attachment to CHF2C1 in mixtures with CO2 an N2, Radiat.Phys.Chem., 48, 65 (1996).
S.J. Burns, J.M. Matthews and D.L. McFadden, Rate coefficients for dissociative electron attachment by halomethane compounds between 300 and 800 K, J. Phys.Chem., 100, 19436 (1996).
E. Illenberger, Electron attachment reactions in molecular clusters, Chem.Rev., 92, 1589 (1992).
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Szamrej, I. (1998). The Dependence of Electron Capture Rate Constants on Electronic Polarizability. In: Christophorou, L.G., Olthoff, J.K. (eds) Gaseous Dielectrics VIII. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-4899-7_9
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DOI: https://doi.org/10.1007/978-1-4615-4899-7_9
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